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Removal of Lead (II) Metal Ions from Aqueous Solutions Using Modified Kennan’s Sugarcane Bagasse Activated Carbon Combined with Natural Zeolite

DOI: 10.4236/oalib.1115597, PP. 1-17

Subject Areas: Physical Chemistry

Keywords: Kennan’s Sugarcane Baggase (KSB), Activated Carbon, Natural Zeolite, Lead Adsorption, Isotherm Modeling, Water Treatment

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Abstract

This work presents a systematic comparative evaluation of sugarcane bagasse-derived activated carbons from Kennana Sugar Company—Sudan, chemically activated using KOH and H3PO4 and composited with natural zeolite, for the adsorption of Pb(II) ions from aqueous media. The adsorption process exhibited optimal performance under mildly acidic conditions (pH 5.0 - 6.0). Equilibrium data were analyzed using Langmuir and Freundlich isotherm models, with both models showing strong agreement with experimental results; however, the Langmuir model provided the most accurate representation, indicating predominantly monolayer adsorption. Freundlich analysis further suggested that Pb(II) uptake on both composites is governed mainly by a physisorption mechanism. The adsorbents demonstrated high affinity toward Pb(II) ions, with maximum monolayer adsorption capacities of 588.24 mg g1 for AC (KSCB)KOH-zeolite and 161.29 mg g1 for AC (KSCB)H3PO4-zeolite, as determined from Langmuir isotherms. Corresponding Langmuir affinity constants (KL) were 138.77 and 92.39, respectively, confirming stronger Pb(II) -adsorbent interactions for the KOH-activated composite. Overall, the carbonized AC (KSCB)KOH-natural zeolite composite exhibited markedly enhanced adsorption performance compared to its H3PO4-activated counterpart, underscoring its potential as a cost-effective and sustainable material for efficient lead remediation in water treatment applications.

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Elhussien, M. , Hassan, M. and Sulieman, S. (2026). Removal of Lead (II) Metal Ions from Aqueous Solutions Using Modified Kennan’s Sugarcane Bagasse Activated Carbon Combined with Natural Zeolite. Open Access Library Journal, 13, e15597. doi: http://dx.doi.org/10.4236/oalib.1115597.

References

[1]  WHO (World Health Organization) (2011) Guidelines for Drinking-Water Quality. 4th Edition, World Health Organization.
[2]  USEPA (US Environmental Protection Agency) (2015) Regulated Drinking Water Contaminants. Online Database.
[3]  Bryan, G.W. and Langston, W.J. (1992) Bioavailability, Accumulation and Effects of Heavy Metals in Sediments with Special Reference to United Kingdom Estuaries: A Review. <i>Environmental Pollution</i>, 76, 89-131. <br>https://doi.org/10.1016/0269-7491(92)90099-v
[4]  Alabdula&#8217;aly, A.I. and Khan, M.A. (2009) Heavy Metals in Cooler Waters in Riyadh, Saudi Arabia. <i>Environmental Monitoring and Assessment</i>, 157, 23-28. <br>https://doi.org/10.1007/s10661-008-0511-3
[5]  Agency for Toxic Substances and Disease Registry (2015) Toxicological Profiles, Toxic Substances Portal.
[6]  Das, N., Vimala, R. and Kartika, P. (2007) Biosorption of Heavy Metals: An Overview. <i>Indian Journal of Biotechnology</i>, 7, 159-169.
[7]  Grevatt, P.C. (1998) Toxicological Review of Hexavalent Chromium. Support of Summary Information on the Integrated Risk Information System (IRIS), US Environmental Protection Agency, Washington DC.
[8]  Dehghani, M.H., Taher, M.M., Bajpai, A.K., Heibati, B., Tyagi, I., Asif, M., <i>et al</i>. (2015) Removal of Noxious Cr (VI) Ions Using Single-Walled Carbon Nanotubes and Multi-Walled Carbon Nanotubes. <i>Chemical Engineering Journal</i>, 279, 344-352. <br>https://doi.org/10.1016/j.cej.2015.04.151
[9]  Aksu, Z. (2009) Application of Biosorption for the Removal of Organic Pollutants: A Review. <i>Process Biochemistry</i>, 40, 997-1026. <br>https://doi.org/10.1016/j.procbio.2004.04.008
[10]  Kozlowski, C.A. and Walkowiak, W. (2002) Removal of Chromium(VI) from Aqueous Solutions by Polymer Inclusion Membranes. <i>Water Research</i>, 36, 4870-4876. <br>https://doi.org/10.1016/s0043-1354(02)00216-6
[11]  Akbal, F. and Camc&#305;, S. (2011) Copper, Chromium and Nickel Removal from Metal Plating Wastewater by Electrocoagulation. <i>Desalination</i>, 269, 214-222. <br>https://doi.org/10.1016/j.desal.2010.11.001
[12]  Assadi, A., Dehghani, M.H., Nasseri, N.R. and Mahvi, A.H. (2012) Photocatalytic Reduction of Hexavalent Chromium in Aqueous Solutions with Zinc Oxide Nanoparticles and Hydrogen Peroxide. <i>Environment Protection Engineering</i>, 38, 1-12. <br>https://doi.org/10.37190/epe120401
[13]  Mohammadi, T., Moheb, A., Sadrzadeh, M. and Razmi, A. (2005) Modeling of Metal Ion Removal from Wastewater by Electrodialysis. <i>Separation and Purification Technology</i>, 41, 73-82. <br>https://doi.org/10.1016/j.seppur.2004.04.007
[14]  Gupta, S. and Babua, B.V. (2006) Adsorption of Cr (VI) by a Low-Cost Adsorbent Prepared from Neem Leaves. 2006 <i>Proceeding of National Conference on Environ</i><i>mental Conservation</i>, Pilani, 1-3 September 2006, 170-185.
[15]  Anzeze, D.A., Onyari, J.M., Shiundu, P.M. and Gichuki, J.W. (2014) Equilibrium and Kinetics Studies for the Biosorption of Aqueous Cd (II) Ions onto Eichhornia Crasippes Biomass. <i>IOSR</i> <i>Journal</i> <i>of</i> <i>Applied</i> <i>Chemistry</i>, 7, 29-37. <br>https://doi.org/10.9790/5736-07122937
[16]  Thakur, L.S. and Parmar, M. (2013) Adsorption of Heavy Metal (Cu<sup>2+</sup>, Ni<sup>2+</sup> and Zn<sup>2+</sup>) from Synthetic Waste Water by Tea Waste Adsorbent. <i>International Journal o</i><i>f Chemical and Physical Sciences</i>, 2, 6-19.
[17]  Ania, M.C. (2003) Purification of Industrial Effluents with Activated Carbon, Adsorption of Pollutants and Adsorbent Regeneration Austrias. Universidad de Oviedo.
[18]  Garg, V. (2004) Basic Dye (Methylene Blue) Removal from Simulated Wastewater by Adsorption Using Indian Rosewood Sawdust: A Timber Industry Waste. <i>Dyes and Pigments</i>, 63, 243-250. <br>https://doi.org/10.1016/j.dyepig.2004.03.005
[19]  Onal, Y., Akmilbasar, C., Eren, D., Sariciozdemir, C. and Depci, T. (2006) Adsorption Kinetics of Malachite Green onto Activated Carbon Prepared from Tun&#231;bilek Lignite. <i>Journal of Hazardous Materials</i>, 128, 150-157. <br>https://doi.org/10.1016/j.jhazmat.2005.07.055
[20]  Ahmadpour, A. and Do, D.D. (1997) The Preparation of Activated Carbon from Macadamia Nutshell by Chemical Activation. <i>Carbon</i>, 35, 1723-1732. <br>https://doi.org/10.1016/s0008-6223(97)00127-9
[21]  Youssef, A.M., Radwan, N.R.E., Abdel-Gawad, I. and Singer, G.A.A. (2005) Textural Properties of Activated Carbons from Apricot Stones. <i>Colloids</i> <i>and</i> <i>Surfaces</i> <i>A</i>: <i>Physicochemical</i> <i>and</i> <i>Engineering</i> <i>Aspects</i>, 252, 143-151. <br>https://doi.org/10.1016/j.colsurfa.2004.09.008
[22]  AI-Duri, B. (1996) Introduction to Adsorption. In: McKay, G., <i>Use of Adsorbents for </i><i>Theremoval</i><i> of Pollutants from Wastewaters</i>, CRC Press, 1-6.
[23]  Xiao, B., Sun, X.F. and Sun, R. (2001) The Chemical Modification of Lignins with Succinic Anhydride in Aqueous Systems. <i>Polymer Degradation and Stability</i>, 71, 223-231. <br>https://doi.org/10.1016/s0141-3910(00)00133-6
[24]  Ho, Y.S. and McKay, G. (1998) A Two-Stage Batch Sorption Optimized Design for Dye Removal to Minimize Contact Time. <i>Process Safety and Environmental Protection</i>, 76, 313-318. <br>https://doi.org/10.1205/095758298529678
[25]  Orlando, U.S., Baes, A.U., Nishijima, W. and Okada, M. (2002) A New Procedure to Produce Lignocellulosic Anion Exchangers from Agricultural Waste Materials. <i>Bioresource</i> <i>Technology</i>, 83, 195-198. <br>https://doi.org/10.1016/s0960-8524(01)00220-6
[26]  Arami-Niya, A., Daud, W.M.A.W. and Mjalli, F.S. (2011) Comparative Study of the Textural Characteristics of Oil Palm Shell Activated Carbon Produced by Chemical and Physical Activation for Methane Adsorption. <i>Chemical Engineering Research and Design</i>, 89, 657-664. <br>https://doi.org/10.1016/j.cherd.2010.10.003
[27]  Ariyadejwanich, P., Tanthapanichakoon, W., Nakagawa, K., Mukai, S.R. and Tamon, H. (2003) Preparation and Characterization of Mesoporous Activated Carbon from Waste Tires. <i>Carbon</i>, 41, 157-164. <br>https://doi.org/10.1016/s0008-6223(02)00267-1
[28]  Arriagada, R., Garc&#237;a, R., Molina-Sabio, M. and Rodriguez-Reinoso, F. (1997) Effect of Steam Activation on the Porosity and Chemical Nature of Activated Carbons from Eucalyptus Globulus and Peach Stones. <i>Microporous Materials</i>, 8, 123-130. <br>https://doi.org/10.1016/s0927-6513(96)00078-8

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