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-  2019 

Cobalt-Catalyzed Asymmetric Synthesis of gem-Bis(silyl)alkanes by Double Hydrosilylation of Aliphatic Terminal Alkynes

DOI: https://doi.org/10.1016/j.chempr.2019.02.001

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Abstract:

? Precise synthesis of chiral gem-bis(silyl)alkanes with dihydro- and trihydrosilane ? Dual cobalt catalysis for sequential double hydrosilylation of alkynes ? Readily available starting materials under mild reaction conditions ? The proposed mechanism is supported by kinetic studies and DFT calculation

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