%0 Journal Article %T Cobalt-Catalyzed Asymmetric Synthesis of gem-Bis(silyl)alkanes by Double Hydrosilylation of Aliphatic Terminal Alkynes %J - %D 2019 %R https://doi.org/10.1016/j.chempr.2019.02.001 %X £¿ Precise synthesis of chiral gem-bis(silyl)alkanes with dihydro- and trihydrosilane £¿ Dual cobalt catalysis for sequential double hydrosilylation of alkynes £¿ Readily available starting materials under mild reaction conditions £¿ The proposed mechanism is supported by kinetic studies and DFT calculation %U https://www.cell.com/chem/fulltext/S2451-9294(19)30036-1