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Application of Chemically Modified and Unmodified Waste Biological Sorbents in Treatment of Wastewater

DOI: 10.1155/2012/751240

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Abstract:

Protein wastes (feathers, goat hair) and cellulosic wastes (corn cob, coconut husks) were collected and washed with detergent solution, thoroughly rinsed and sun dried for 2 days before drying in an oven, and then ground. One-half of ground material was carbonized at a maximum temperature of 500°C after mixing with H2SO4. The carbonized parts were pulverized; both carbonized and uncarbonized sorbents were sieved into two particle sizes of 325 and 625?μm using mechanical sieve. Sorbents of a given particle size were packed into glass column.Then, textile wastewater that had its physicochemical parameters previously determined was eluted into each glass column and a contact time of 60 and 120 mins was allowed before analysis. Results showed 48.15–99.98 percentage reduction of , EC, Cl?, BOD, COD, DO, TSS, and TDS, 34.67–99.93 percentage reduction of , EC, Cl?, BOD, COD, DO, TSS, and TDS, 52.83–97.95 percentage reduction of Pb2+, Ni2+, Cr3+ and Mn2+ and 34.59–94.87 percentage reduction of Pb2+, Ni2+, Cr3+ and Mn2+. Carbonization, small particle, size and longer contact time enhanced the sorption capabilities of the sorbents. These show that protein and cellulosic wastes can be used to detoxify wastewater. 1. Introduction Wastewater may be purely domestic or may contain some industrial wastewater as well [1]. Residential wastewater is a combination of excreta, flush water, and all types of wastewater generated from household. It is more commonly known as sewage and much diluted. There are two types of domestic sewage: black water or wastewater from toilets and gray water, which is wastewater from all sources except toilets [2]. Industrial wastewater comes from commercial activities (shops, restaurants, fast food shops, hospitals, etc.), industries (e.g., chemical industries, pharmaceutical companies, textile manufacturing, etc.), agriculture (e.g., Slurry), and so forth. Wastewaters from dyeing operations are characterized by color caused by both organic and inorganic compounds [3]. The organic compounds are more problematic in industrial effluent than inorganic materials [4, 5] because, apart from the color, it imparts on the wastewater, biodegradation of organic material in the dye depleting the dissolved oxygen of the water thereby stressing aquatic microbes [6]. Traditional wastewater treatment technologies have shown to be ineffective for handling synthetic dyes because of the chemical stability of these pollutants [7]. There is no single or economically attractive method of treatment of textile wastewater [8], although notable achievements were made

References

[1]  M. F. Gordon, J. C. Geten, and A. D. Okun, Water and Wastewater Engineering, John Wiley and Son, New York, NY, USA, 1986.
[2]  A. Ofoefule, E. Uzodimma, and C. Ibeto, “Wastewater: treatment options and its associated benefits,” in Wastewater Evaluation and Management, Fernando Sebastian Garcia Einschlag, Ed., Intech-Publishers Croatia, 2011.
[3]  R. Crites and G. Techobanoglous, Small Decentralized Wastewaters Management Systems, McGraw- Hill, Singapore, 1998.
[4]  J. W. Moore and E. A. Moore, Environmental Small Decentralized Wastewater Management Systems, McGraw Chemistry, Academic Press, London, UK, 1976.
[5]  J. Passivirta, Chemical Ecotoxicology, Lewis Publishers, Chelsea, Mich, USA, 1991.
[6]  M. Calf and C. Eddy, Wastewater Engineering, Tata McGraw-Hill, New Delhi, India, 3rd edition, 1991.
[7]  E. Forgacs, T. Cserháti, and G. Oros, “Removal of synthetic dyes from wastewaters: a review,” Environment International, vol. 30, no. 7, pp. 953–971, 2004.
[8]  Y. M. Slokar and A. M. Marechal, “Methods of decoloration of textile wastewaters,” Dyes and Pigments, vol. 37, no. 4, pp. 335–356, 1998.
[9]  A. B. dos Santos, F. J. Cervantes, and J. B. Vanlier, “Review paper on current technologies for decoloration of textile wastewaters: perspective for anaerobic biotechnology,” Bioresource Technology, vol. 918, pp. 2169–2385, 2007.
[10]  P. Janos, “Non-conventional sorbents for the Dye Removal from waters: mechanisms and selected applications,” in Sorbents Properties, Materials and Applications, T. P. Wills, Ed., pp. 357–381, Nova Science, New York, NY, USA, 2009.
[11]  J. QU, “Research progress of novel adsorption processes in water purification: a review,” Journal of Environmental Sciences, vol. 20, no. 1, pp. 1–13, 2008.
[12]  L. Wojnarovites and E. Takacs, “Irradiation treatment of azodye containing wastewater. An overview,” Radiation Physics and Chemistry, vol. 77, no. 3, pp. 225–244, 2008.
[13]  T. A. Kurniawan, G. Y. S. Chan, W. H. Lo, and S. Babel, “Comparisons of low-cost adsorbents for treating wastewaters laden with heavy metals,” Science of the Total Environment, vol. 366, no. 2-3, pp. 409–426, 2006.
[14]  G. Crini, “Non-conventional low-cost adsorbents for dye removal: a review,” Bioresource Technology, vol. 97, no. 9, pp. 1061–1085, 2006.
[15]  S. Babel and T. A. Kurniawan, “Low-cost adsorbents for heavy metals uptake from contaminated water: a review,” Journal of Hazardous Materials, vol. 97, no. 1–3, pp. 219–243, 2003.
[16]  S. E. Bailey, T. J. Olin, R. M. Bricka, and D. D. Adrian, “A review of potentially low-cost sorbents for heavy metals,” Water Research, vol. 33, no. 11, pp. 2469–2479, 1999.
[17]  American Public Health Association, Standard Methods for the Examination of Water and Wastewater, APHA, AWWA, WEF, Washington, DC, USA, 20th edition, 1998.
[18]  F. R. Theroux, Laboratory Manual for Chemical and Bacterial Analysis of Water and Sewage, McGraw-Hill, New York, NY, USA, 3rd edition, 1943.
[19]  J. Bertram and R. Balance, A Practical Guide to the Design and Implementation of Fresh Water Quality and Monitoring Programmes, United Nations Environmental Programme (UNEP) and World Health Organization (WHO). E & FN Spon, 1996.
[20]  F. N. Emengo, J. K. Nduka, C. N. Anodebe, and P. A. C. Okoye, “Dye wastewaters, alternative physiochemical treatment reagent,” in Sorbents: Properties, Materials and Applications, T. P. Willis, Ed., Nova Science, New York, NY, USA, 2009.
[21]  A. Shukla, Y. H. Zhang, P. Dubey, J. L. Margrave, and S. S. Shukla, “The role of sawdust in the removal of unwanted materials from water,” Journal of Hazardous Materials, vol. 95, no. 1-2, pp. 137–152, 2002.
[22]  G. Annadurai, S. Juang, and D. J. Lee, “Use of cellulose-based wastes for adsorption of dyes from aqueous solutions,” Journal of Hazardous Materials, vol. 92, no. 3, pp. 263–274, 2002.
[23]  F. Banat, S. Al-Asheh, R. Al-Ahmad, and F. Bni-Khalid, “Bench-scale and packed bed sorption of methylene blue using treated olive pomace and charcoal,” Bioresource Technology, vol. 98, no. 16, pp. 3017–3025, 2007.
[24]  A. E. Ofomaja, “Kinetics and mechanism of methylene blue sorption onto palm kernel fibre,” Process Biochemistry, vol. 42, no. 1, pp. 16–24, 2007.
[25]  M. Saleem, T. Pirzada, and R. Qadeer, “Sorption of acid violet 17 and direct red 80 dyes on cotton fiber from aqueous solutions,” Colloids and Surfaces A, vol. 292, no. 2-3, pp. 246–250, 2007.
[26]  J. C. Igwe and A. A. Abia, “Studies on the effects of pH and modification of adsorbent on AS (V) removal from aqueous solution using sawdust and coconut fibre,” Chemical Society of Nigeria, vol. 32, no. 2, pp. 24–28, 2007.
[27]  M. Musah, U. A. Birnin-Yauri, and A. U. Itodo, “Detoxification of Pb2+ and Cr3+ ions using derived palm kernel shell adsorbent,” in Proceedings of the 34th International Conference Chemical Society of Nigeria, September 2011.
[28]  Y. Kato, K. Umehara, and M. Aoyama, “An oil sorbent from wood fiber by mild pyrolysis,” Holz als Roh- und Werkstoff, vol. 55, no. 6, pp. 399–401, 1997.
[29]  S. Karaca, A. Gürses, and R. Bayrak, “Investigation of applicability of the various adsorption models of methylene blue adsorption onto lignite/water interface,” Energy Conversion and Management, vol. 46, no. 1, pp. 33–46, 2005.
[30]  E. Gallego, F. J. Roca, J. F. Perales, and X. Guardino, “Use of Sorbents in air quality control systems,” in Sorbents; Properties, Materials and Applications, T. P. Wills, Ed., Nova Science, New York, NY, USA, 2009.
[31]  J. K. C. Nduka, O. J. Ezeakor, and A. C. Okoye, “Characterization of wastewater and use of cellulosic waste as treatment option,” Journal of Engineering Science and Technology, vol. 14, no. 11, pp. 7226–7234, 2007.
[32]  G. F. Liptrot, Modern Inorganic Chemistry, Unwin Hyman, London, UK, 4th edition, 1986.
[33]  E. Matisova and S. Skrabakova, “Cabon sorbents and their utilization for preconcentration of organic pollutant in environmental samples,” Journal of Chromatography A, vol. 707, pp. 145–179, 1995.

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