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物理化学学报 2011
线型和非线型分子转动光谱强度的统计模型Keywords: statisticalproperty,powerlaw,organicandinorganicmolecules,spectrumintensity,boltzmannpowerlaw Abstract: inthisstudy,wefoundregularbehavior,fromastatisticalpointofview,intheintensitiesofrotationalspectraforseveralorganicandinorganicmoleculesatroomtemperature.non-linearmolecules,forwhichacommonintensitybehaviorwasderived,wereespeciallyinteresting.weprovidedtheoreticalsupportfortheobtainedresultsbasedontheboltzmanndistribution.boltzmannpowerlawswereusedtoreproducethestatisticalbehavioroftheintensitiesfromthespectraoflinearandnon-linearmolecules.weonlyusedstatisticalargumentsandnospecificdetailsofanymoleculewereused.therefore,theseresultsareapplicabletoalargeclassofatomsandmoleculesandthemodelisvalidwhenconsideringsimilarconditionstothoseusedinthisstudy.
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