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物理化学学报 2009
聚合物分散液晶从液体桥的组装Keywords: liquidbridge,polymer-dispersedliquidcrystal,controlledevaporativeorganization,"stick-slip",motion Abstract: wereporttheorganizationofpolymer-dispersedliquidcrystals(pdlcs)intoorderedconcentricringsoverlargeareasbydryingadropofboundpdlctoluenesolution(i.e.,confinedbetweenasphericallensandanindiumtinoxide(ito)-coatedglasssubstrate;sphere-on-itogeometry).theformationofregularring-likedepositswasadirectconsequenceofcontrolled"stick-slip"cyclesofthree-phasecontactlineduringthecourseofsolventevaporation,whichwaseffectivelyregulatedthroughtheuseofthesphere-on-itogeometry.thissimpleapproachbasedoncontrolledevaporativeorganizationmayprovideanewmeansofprocessingpolymer/lcmixturetoproduceorderedsurfacepatternsinonestep,wheremicroscopiclcsaredispersedwithinthepolymermatrix.
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