全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

化学浴沉积法制备Sb掺杂SnS薄膜

DOI: 10.14062/j.issn.0454-5648.2015.12.14

Full-Text   Cite this paper   Add to My Lib

Abstract:

以氯化亚锡、硫代乙酰胺、三氯化锑为反应物,采用化学浴沉积法在玻璃衬底上沉积不同锑掺杂量(摩尔分数)硫化锡(SnSSb)膜,研究了锑掺杂量对薄膜晶相结构、表面形貌和光电性能的影响。结果表明锑掺杂SnS薄膜是具有正交结构多晶薄膜,薄膜为纳米片组装成的花状球形颗粒。随着Sb掺杂量由1.8%增加到7.2%,其相应的禁带宽度从0.93eV增加到1.30eV。随着Sb掺杂量的增加,SnS薄膜的电阻率呈现先下降后增大趋势,当Sb掺杂量为3.6%时,其最小值为5.21×103?·cm。

References

[1]  SAJEESH T H, WARRIER A R, KARTA C S, et al. Optimization ofparameters of chemical spray pyrolosis technique to get n- and p-typelayers of SnS [J]. Thin Solid Films, 2010, 518: 4370–4374.
[2]  KOTEESWARA REDDY N, RAMAKRISHNA REDDY K T. Opticalbehaviour of sprayed tin sulphide thin films [J]. Mater Res Bull, 2006,41: 414–422.
[3]  RAY S C, KARANJAI M K, DASGUPTA D. Structure andphotoconductive properties of dip-deposited SnS and SnS2 thin filmsand their conversion to tin dioxide by annealing in air [J]. Thin SolidFilms, 1999, 350: 72–78.
[4]  RAMAKRISHNA R K T, KOTESWARA REDDY N, MILES R W.Photovoltaic properties of SnS based solar cells [J]. Solar EnergyMater Solar Cells, 2006, 90: 3041–3046.
[5]  MINNAM REDDY V R, GEDI S, PARK C, et al. Development ofsulphurized SnS thin film solar cells [J]. Curr Appl Phys, 2015, 15:588–598.
[6]  GE Y, GUO Y Y, SHI W M, et al. Influence of In-doping on resitivityof chemical bath deposited SnS films[J]. J Shanghai Univ(Eng Ed),2007, 11 (4): 403–406.
[7]  HSU Hsuantai, CHIANG Minghung, HUANG Chenhao, et al. Effectsof Ge- and Sb-doping and annealing on the tunable bandgaps of SnSfilms[J]. Thin Solid Films, 2015, 584: 37–40.
[8]  SANTHOSH KUMAR K, MANOHARAN C, DHANAPANDIAN S,et al. Effect of indium incorporation on properties of SnS thin filmsprepared by spray pyrolysis [J]. Optik, 2014, 125: 3996–4000.
[9]  SINSERMSUKSAKUL Prasert, CHAKRABORTY RupaSk, KIMSang Bok, et al. Antimony-doped tin (II) sulfide thin films [J]. ChemMater, 2012, 24 (23): 4556–4562.
[10]  PRICE L S, PARKIN I P, HARDY A M E, et al. Atmospheric pressurechemical vapor deposition of tin sulfides (SnS, Sn2S3, and SnS2) onglass[J]. Chem Mater, 1999, 11(7): 1792–1799.
[11]  SEAL Mark, SINGH Nirala, MCFARLAND Eric W, et al.Electrochemically deposited Sb and In doped tin sulfide (SnS)photoelectrodes [J]. J Phys Chem C, 2015, 119, 6471–6480.
[12]  JAYASREE Y, CHALAPATHI U, SUNDARA RAJA V. Growth andcharacterization of tin sulphide thin films by chemical bath depositionusing ethylenediamine tetra-acetic acid as the complexing agent [J].Thin Solid Films, 2013, 537: 149–155.
[13]  KOTESWARA R N, RAMAKRISHNA R K T. Growth ofpolycrystalline SnS films by spray pyrolysis[J]. Thin Solid Films, 1998,325: 4–6.
[14]  KAWANO Yu, CHANTANA Jakapan, MINEMOTO Takashi. Impactof growth temperature on the properties of SnS film prepared bythermal evaporation and its photovoltaic performance [J]. Curr ApplPhys, 2015, 15: 897–901.
[15]  PARK Hui Kyung, JO Jaeseung, HONG Hee Kyeung, et al. Structural,optical, and electrical properties of tin sulfide thin films grown withelectron-beam evaporation [J]. Curr Appl Phys, 2015, 15: 964–969.
[16]  HARTMAN K, JOHNSON J L, BERTONI M I, et al. SnS thin filmsby RF sputtering at room temperature[J]. Thin Solid Films, 2011,519(21) :7421-7424.
[17]  DU Ming, YIN Xuesong, GONG Hao. Effects of triethanolamine onthe morphology and phase of chemically deposited tin sulfide[J]. MaterLett, 2015, 152: 40–44.
[18]  GUNERI E, ULUTAS C, KIRMIZIGUL F, et al. Effect of depositiontime on structural, electrical, and optical properties of SnS thin filmsdeposited by chemical bath deposition [J]. Appl Surf Sci, 2010, 257:1189–1195.
[19]  SAJEESH T H, CHERIAN A S, SUDHA KARTHA C, et al.Engineering structural and opto-electronic properties of SnS filmsdeposited using chemical spray pyrolysis technique by controlling pHof the Precursor Solution[J]. Energy Procedia, 2012, 15: 325–332.
[20]  NAIR M S T, NAIR P K. Simplified chemical deposition technique forgood quality SnS thin films[J]. Semicond Sci Technol, 1991, 6:132–134.
[21]  PRAMANIK P, BASU P K, BISWAS S. Preparation andcharacterization of chemically deposited tin(II) sulphide thin films[J].Thin Solid Films, 1987, 150(2-3): 269–276.
[22]  SANTHOSH K K, GOWRI M A, DHANAPANDIAN S, et al. Physicalproperties of spray pyrolyzed Ag-doped SnS thin films foropto-electronic applications [J]. Mater Lett, 2014, 131: 167–170.
[23]  GOWRI M A, DHANAPANDIAN S, MANOHARAN C, et al. Effectof doping concentration on the properties of bismuth doped tin sulfidethin films prepared by spray pyrolysis[J]. Mater Sci Semicond Process,2014, 17: 138–142.
[24]  GAO Chao, SHEN Honglie, SUN Lei, et al. Chemical bath depositionof SnS films with different crystal structures [J]. Mater Lett, 2011, 65:1413–1415.
[25]  PEJOVA Biljana, GROZDANOV Ivan, TANU?EVSKI Atanas. Opticaland thermal band gap energy of chemically deposited bismuth (III)selenide thin films [J]. Mater Chem Phys, 2004, 83(2-3): 245–249.
[26]  NAIR M T S, PENA Y, CAMPOS J, et al. Semiconductor thin films bychemical bath deposition for solar energy related applications [J]. SolarEnergy Mater Solar Cells, 1998, 52(3): 313–344.
[27]  HICKEY S G, WAURISCH C, RELLINGHAUS B, et al. Size andshape control of colloidally synthesized IV-VI nanoparticulate tin(II)sulfide[J]. J Am Chem Soc, 2008, 130, 14978–14980.
[28]  GóMEZ-POZOS H, MALDONADO A, DE LA L M. Olvera. Effect ofthe [Al/Zn] ratio in the starting solution and deposition temperature onthe physical properties of sprayed ZnO:Al thin films[J]. Mater Lett,2007, 61(7): 1460–1464.
[29]  TANU?EVSKI A, POELMAN D. Optical and photoconductiveproperties of SnS thin films prepared by electron beam evaporation [J].Solar Energy Mater Solar Cells, 2003, 80: 297–303.
[30]  JOSEPH B, MANOJ P K, VAIDYAN V K. Studies on the structural,electrical and optical properties of Al-doped ZnO thin films preparedby chemical spray deposition[J]. Ceram Int, 2006, 32(5): 487–493.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133