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OALib Journal期刊
ISSN: 2333-9721
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Silvernanoparticledecoratedpoly(2-aminodiphenylamine)modifiedcarbonpasteelectrodeasasimpleandefficientelectrocatalystforoxidationofformaldehyde
DOI: 10.1016/S1872-2067(14)60115-7, PP. 1565-1570
Keywords: Electrocatalyst,Silvernanoparticle,Formaldehyde,2-Aminodiphenylamine,Carbonpasteelectrode
Abstract:
？Thisworkdescribesthepromisingactivityofsilvernanoparticlesonthesurfaceofapoly(2-aminodiphenylamine)modifiedcarbonpasteelectrode(CPE)towardsformaldehydeoxidation.ElectrodepositionoftheconductingpolymerfilmontheCPEwascarriedoutusingconsecutivecyclicvoltammetryinanaqueoussolutionof2-aminodiphenylamineandHCl.NitrogengroupsinthepolymerbackbonehadaAgionaccumulatingeffect,allowingAgnanoparticlestobeelectrochemicallydepositedonthesurfaceoftheelectrode.Theelectrochemicalandmorphologicalcharacteristicsofthemodifiedelectrodewereinvestigated.Theelectro-oxidationofformaldehydeonthesurfaceofelectrodewasstudiedusingcyclicvoltammetryandchronoamperometryinaqueoussolutionof0.1mol/LNaOH.Theelectro-oxidationonsetpotentialwasfoundtobearound-0.4V,whichisuniqueintheliterature.Theeffectofdifferentconcentrationsofformaldehydeontheelectrocatalyticactivityofthemodifiedelectrodewasinvestigated.Finally,thediffusioncoefficientofformaldehydeinalkalinemediawascalculatedtobe0.47×10-6cm2/susingchronoamperometry.
| [1] | Hosseini M G, Abdolmaleki M, Ashrafpoor S. Chin J Catal (催化学报), 2013, 34: 1712
|
| [2] | Parsons R, Vandernoot T. J Electroanal Chem Int Electrochem, 1988, 257: 9
|
| [3] | Va？kelis A, Norkus E, Stalnioniene I, Stalnionis G. Electrochim Acta, 2004, 49: 1613
|
| [4] | Song C J, Khanfar M, Pickup P G. J Appl Electrochem, 2006, 36: 339
|
| [5] | Safavi A, Maleki N, Farjami F, Farjami E. J Electroanal Chem, 2009, 626: 75
|
| [6] | Raoof J B, Ojani R, Abdi S, Hosseini S R. Int J Hydrogen Energy, 2012, 37: 2137
|
| [7] | Raoof J B, Omrani A, Ojani R, Monfared F. J Electroan Chem, 2009, 633: 153
|
| [8] | Villullas H M, Mattos-Costa F I, Nascente P A P, Bulh？es L O S. Electrochim Acta, 2004, 49: 3909
|
| [9] | Wang L, Sun Y J, Che G B, Li Z. Appl Surf Sci, 2011, 257: 7150
|
| [10] | Sato N, Shimizu Y. Electrochim Acta, 1973, 18: 567
|
| [11] | Droog J M M, Huisman F. J Electroanal Chem Int Electrochem, 1980, 115: 211
|
| [12] | Casella I G, Ritorti M. Electrochim Acta, 2010, 55: 6462
|
| [13] | Abd El Rehim S S, Hassan H H, Ibrahim M A M, Amin M A. Monatsh Chem, 1998, 129: 1103
|
| [14] | Stonehart P. Electrochim Acta, 1968, 13: 1789
|
| [15] | Selvaraj V, Nirmala Grace A, Alagar M. J Colloid Interface Sci, 2009, 333: 254
|
| [16] | Strbac S, Avramov Ivic M. Electrochim Acta, 2009, 54: 5408
|
| [17] | Gao G Y, Guo D J, Li H L. J Power Sources, 2006, 162: 1094
|
| [18] | Kim J, Jung C, Rhee C K, Lim T H. Langmuir, 2007, 23: 10831
|
| [19] | Shen Y N, Yang X Z, Wang Y Z, Zhang Y B, Zhu H Y, Gao L, Jia M L. Appl Catal B, 2008, 79: 142
|
| [20] | IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. Volume 88. Formaldehyde, 2-Butoxyethanol and 1-tert- Butoxypropan-2-ol. 2006
|
| [21] | Ojani R, Raoof J B, Safshekan S. J Appl Electrochem, 2012, 42: 81
|
| [22] | Zhu Z Z, Wang Z, Li H L. J Power Sources, 2009, 186: 339
|
| [23] | Selvaraj V, Alagar M, Sathish Kumar K. Appl Catal B, 2007, 75: 129
|
| [24] | Geng J L, Bi Y P, Lu G X. Electrochem Commun, 2009, 11: 1255
|
| [25] | Ojani R, Raoof J B, Ahmady-Khanghah Y, Safshekan S. Int J Hydrogen Energy, 2013, 38: 5457
|
| [26] | Majari Kasmaee L, Gobal F. J Power Sources, 2010, 195: 165
|
| [27] | Assaf F H, Zaky A M, Abd El Rehim S S. Appl Surf Sci, 2002,187: 18
|
| [28] | Ambrose J, Barradas R G. Electrochim acta, 1974, 19: 781
|
| [29] | Bard A J, Faulkner L R. Electrochemical Methods. New York: John Wiley and Sons, 2001
|
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