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催化学报 2008
硅基催化结构合成的策略, PP. 1187-1192 Keywords: enzymeanalogs,templating,imprinting,dendrimer,nanocage,catalystsynthesis,confinementeffect Abstract: ？Twoapproachestosynthesizesilicon-basedcatalyticstructuresthataimatcapturingthepropertiesandfunctionalitiesofnaturalenzymesaredescribedinthisbriefreview:unit-by-unitsynthesisofmacromolecularunitsandtemplating/imprintingsynthesisofnanocages.Theunit-by-unitapproachmimicsthepeptidesynthesismethod,offersatomiccontrolofthestructure,butisinefficientinsynthesizinglargestructuressuchasnanocages.Thetemplating/imprintingmethodismoresuitablefornanocagesatthesacrificeofatomiccontrol,andthenanocagesobtainedareshowntopossesspropertiesexhibitedbyenzymecavities.
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