%0 Journal Article
%T 硅基催化结构合成的策略
%A Harold H. KUNG
%A Mayfair C. KUNG
%J 催化学报
%P 1187-1192
%D 2008
%X ？Twoapproachestosynthesizesilicon-basedcatalyticstructuresthataimatcapturingthepropertiesandfunctionalitiesofnaturalenzymesaredescribedinthisbriefreview:unit-by-unitsynthesisofmacromolecularunitsandtemplating/imprintingsynthesisofnanocages.Theunit-by-unitapproachmimicsthepeptidesynthesismethod,offersatomiccontrolofthestructure,butisinefficientinsynthesizinglargestructuressuchasnanocages.Thetemplating/imprintingmethodismoresuitablefornanocagesatthesacrificeofatomiccontrol,andthenanocagesobtainedareshowntopossesspropertiesexhibitedbyenzymecavities.
%K enzymeanalogs
%K templating
%K imprinting
%K dendrimer
%K nanocage
%K catalystsynthesis
%K confinementeffect
%U http://www.chxb.cn/CN/abstract/abstract17339.shtml