The study of the rheological properties of aqueous solutions of corn starch (CS) blends with sodium alginate (SA) and agar-agar (AA) as well as the physical and mechanical properties of bicomponent films on their basis has been carried out. The data show that adding of both polymers to starch solution causes an increase in viscosity which is higher in the case of SA. Activation energy for viscosity flow of solutions of CS blended with SA has minimum value at CS:SA ratio = 98:2. The above mentioned dependence is not typical for AA, as flow activation energy in this case raises steadily with the growth of AA content in the solution, like viscosity of the CS:AA. The extreme behavior of polymer blends with low content of one of the polymers is described in terms of mutual solubility or thermodynamic compatibility. There is a tendency that mechanical properties and water solubility increase with the increasing of SA and AA polymers in corn starch matrix. Obtained data evidence the benefits of bicomponent films production instead of starch-based films.
Jimknez, A., Fabra, M., Taw, P. and Chiralt, A. (2012) Edible and Biodegradable Starch Films. Food and Bioprocess Technology, 5, 2058-2076. http://dx.doi.org/10.1007/s11947-012-0835-4
[3]
Huo, P., Savitskaya, T., Gotina, L., Reznikov, I. and Grinshpan, D. (2015) Rheological Properties of Casting Solutions for Starch Edible Films Production. Open Journal of Fluid Dynamics, 5, 58-67.
http://dx.doi.org/10.4236/ojfd.2015.51008
[4]
Harnsilawat, T., Pongsawatmanit, R. and McClements, D.J. (2006) Characterization of β-Lactoglobulin–Sodium Alginate Interactions in Aqueous Solutions: A Calorimetry, Light Scattering, Electrophoretic Mobility and Solubility Study. Food Hydrocolloids, 20, 577-585. http://dx.doi.org/10.1016/j.foodhyd.2005.05.005
[5]
Lahrech, K., Safouane, A. and Peytellasse, J. (2005) Sol State Formation and Melting of Agar Gels Rheological Study. Physica A: Statistical Mechanics and Its Application, 358, 205-211.
http://dx.doi.org/10.1016/j.physa.2005.06.022
[6]
Lii, C.-Y., Tsai, M.-L. and Tseng, K.-H. (1996) Effect of Amylose Content on the Rheological Property of Rice Starch. Cereal Chemistry, 73, 415-420.
[7]
Singh, N., Singh, J., Kaur, L., Sodhi, N.-S. and Gill, B.-S. (2003) Morphological, Thermal, and Rheological Properties of Starches from Different Botanical Sources. Food Chemistry, 81, 219-231.
http://dx.doi.org/10.1016/S0308-8146(02)00416-8
[8]
Odeniyi, M.A. and Ayorinde, J.O. (2012) Material and Rheological Properties of Yam Starch/Polymer Blend Hydrogel. International Journal of Pharmacology and Pharmaceutical Technology, 1, 23-28.
[9]
Bertolini, A.C., Creamer, L.K., Eppink, M. and Boland, M.J. (2003) Some Rheological Properties of Sodium Caseinate—Starch Gels. Journal of Agricultural and Food Chemistry, 81, 219-231.
[10]
Ma, N.S., Png, j., Xu, N., Li, M.G. and Lin, Q. (2008) Rheological Properties of Sodium Alginate-Agar-Montmorillonite. Journal of Applied Polymer Science, 109, 4075-4081.
[11]
Drozdz, W. and Tomaszewska-Ciosk, E. (2007) Rheological Properties of Potato Starch Pastes with the Addition of Kaolin. Polish Journal of Food and Nutrition Sciences, 57, 113-117.
[12]
Wu, Y., Geng, F., Chang, P.R., Yu, J. and Ma, X. (2009) Effect of Agar on the Microstructure and Performance of Potato Starch Films. Carbohydrate Polymers, 76, 299-304. http://dx.doi.org/10.1016/j.carbpol.2008.10.031
[13]
The, D.P., Debeaufort, F., Voilley, A. and Luu, D. (2009 Biopolymers Interactions Affect the Functional Properties of Edible Films Based on Agar, Cassava Starch and Arabinoxylan Blends. Journal of Food Engineering, 90, 548-558.
http://dx.doi.org/10.1016/j.jfoodeng.2008.07.023
[14]
Gedde, U.W. (1999) Polymer Physics. Springer, 298 p.
[15]
Lipatov, I.S. (1988) Colloid Chemistry of Polymers. Elsevier.