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Molecules 2015
TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic AnionDOI: 10.3390/molecules20011262, PP. 1262-1276 Keywords: TDAE, benzoxazolone, benzoxazolinonic anion, benzylic alcohols, oxiranes Abstract: We describe an original pathway to produce new 5-substituted 3-methyl-6-nitro-benzoxazolones by the reaction of aromatic carbonyl and α-carbonyl ester derivatives with a benzoxazolinonic anion formed exclusively via the TDAE strategy.
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