[N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)

The VV atom in the title complex, [V(C14H8BrClN2O2)(CH3O)O(CH3OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octahedral geometry. The dihedral angle between the two benzene rings of the hydrazone ligand is 13.2 (3)°. The deviation of the V atom towards the oxide O atom from the plane defined by the three donor atoms of the hydrazone ligand and the methoxy O atom is 0.318 (2) . Bond lengths are comparable with those observed in similar oxidovanadium(V) complexes with hydrazone ligands. In the crystal, pairs of molecules are linked through intermolecular O—H...N hydrogen bonds, forming dimers.