%0 Journal Article
%T [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
%A Fu-Ming Wang
%J Acta Crystallographica Section E
%D 2011
%I International Union of Crystallography
%R 10.1107/s1600536811008774
%X The VV atom in the title complex, [V(C14H8BrClN2O2)(CH3O)O(CH3OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octahedral geometry. The dihedral angle between the two benzene rings of the hydrazone ligand is 13.2 (3)¡ã. The deviation of the V atom towards the oxide O atom from the plane defined by the three donor atoms of the hydrazone ligand and the methoxy O atom is 0.318 (2)  . Bond lengths are comparable with those observed in similar oxidovanadium(V) complexes with hydrazone ligands. In the crystal, pairs of molecules are linked through intermolecular O¡ªH...N hydrogen bonds, forming dimers.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536811008774