CATALYTIC OXIDATIVE POLYMERIZATION OF (N,N-DIMETHYLAMINO)ETHYL METHACRYLATE WITH CuX/PMDETA
甲基丙烯酸N,N-二甲氨基乙酯的CuX/PMDETA催化氧化聚合

It was observed that upon addition a certain amount of CuX(X = Cl/Br)/pentamethyldiethylenetriamire(PMDETA) in the presence of air,(N,N-dimethylamino)ethyl methacrylate(DMAEMA) can steadily undergo catalytic oxidative polymerization at ambient temperature.The results from gas chromatography(GC),nuclear magnetic resonnance spectroscopy(()~1H-NMR) and gel-permeation chromatography(GPC) showed that both the monomer conversion and the number-average molecular weight increased gradually with the reaction time;th...