%0 Journal Article
%T CATALYTIC OXIDATIVE POLYMERIZATION OF (N,N-DIMETHYLAMINO)ETHYL METHACRYLATE WITH CuX/PMDETA
甲基丙烯酸N,N-二甲氨基乙酯的CuX/PMDETA催化氧化聚合
%A ZHAN Yan
%A NI Canyan
%A XIA Yougui
%A CHEN Huafeng
%A ZHAI Guangqun
%A KONG Lizhi
%A
展燕
%A 倪灿艳
%A 夏有贵
%A 陈华峰
%A 翟光群
%A 孔立智
%J 高分子学报
%D 2010
%I
%X It was observed that upon addition a certain amount of CuX(X = Cl/Br)/pentamethyldiethylenetriamire(PMDETA) in the presence of air,(N,N-dimethylamino)ethyl methacrylate(DMAEMA) can steadily undergo catalytic oxidative polymerization at ambient temperature.The results from gas chromatography(GC),nuclear magnetic resonnance spectroscopy(()~1H-NMR) and gel-permeation chromatography(GPC) showed that both the monomer conversion and the number-average molecular weight increased gradually with the reaction time;th...
%K (N
%K N-Dimethylamino)ethyl methacrylate(DMAEMA)
%K Catalytic oxidative polymerization
%K Pentamethyldiethylenediamine
甲基丙烯酸N
%K N-二甲氨基乙酯(DMAEMA)
%K 催化氧化聚合
%K 五甲基二乙基三胺
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=C0F273470A19707084D42AA2409EEB57&yid=140ECF96957D60B2&iid=0B39A22176CE99FB&sid=D46BA3D3D4B3C585&eid=AC1578C6BB9EBDEF&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=32