%0 Journal Article %T CATALYTIC OXIDATIVE POLYMERIZATION OF (N,N-DIMETHYLAMINO)ETHYL METHACRYLATE WITH CuX/PMDETA
甲基丙烯酸N,N-二甲氨基乙酯的CuX/PMDETA催化氧化聚合 %A ZHAN Yan %A NI Canyan %A XIA Yougui %A CHEN Huafeng %A ZHAI Guangqun %A KONG Lizhi %A
展燕 %A 倪灿艳 %A 夏有贵 %A 陈华峰 %A 翟光群 %A 孔立智 %J 高分子学报 %D 2010 %I %X It was observed that upon addition a certain amount of CuX(X = Cl/Br)/pentamethyldiethylenetriamire(PMDETA) in the presence of air,(N,N-dimethylamino)ethyl methacrylate(DMAEMA) can steadily undergo catalytic oxidative polymerization at ambient temperature.The results from gas chromatography(GC),nuclear magnetic resonnance spectroscopy(()~1H-NMR) and gel-permeation chromatography(GPC) showed that both the monomer conversion and the number-average molecular weight increased gradually with the reaction time;th... %K (N %K N-Dimethylamino)ethyl methacrylate(DMAEMA) %K Catalytic oxidative polymerization %K Pentamethyldiethylenediamine
甲基丙烯酸N %K N-二甲氨基乙酯(DMAEMA) %K 催化氧化聚合 %K 五甲基二乙基三胺 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=C0F273470A19707084D42AA2409EEB57&yid=140ECF96957D60B2&iid=0B39A22176CE99FB&sid=D46BA3D3D4B3C585&eid=AC1578C6BB9EBDEF&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=32