SYNTHESIS AND CHIROPTICAL PROPERTY OF N-(o-OXAZOLINEPHENYL) METHACRYLAMIDE BASED OPTICACLLY ACTIVE POLYMERS
光学活性N-邻噁唑啉苯基甲基丙烯酰胺聚合物的合成及其手性光学性质

Enantiopure methacrylamide derivative,N-o-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl] methacrylamide ((S)-MeOPMAM) was synthesized and radically polymerized in the presence of rare earth metal trifluoromethanesulfonates (Ln(OTf)3,Ln = La,Nd,Sm,and Y) to yield corresponding optically active polymers.Among these Lewis acids,Y(OTf)3 was found to be most effective for increasing the isotactic specificity during the radical polymerizations when using n-butanol as a solvent.The effect of the Lewis acids was si...