%0 Journal Article
%T SYNTHESIS AND CHIROPTICAL PROPERTY OF N-(o-OXAZOLINEPHENYL) METHACRYLAMIDE BASED OPTICACLLY ACTIVE POLYMERS<br>光学活性N-邻噁唑啉苯基甲基丙烯酰胺聚合物的合成及其手性光学性质
%A LIU Guangxuan
%A LU Wei
%A JIANG Liming
%A SUN Weilin
%A SHEN Zhiquan
%A WANG Yukang
%A <br>刘光烜
%A 路伟
%A 江黎明
%A 孙维林
%A 沈之荃
%A 王玉康
%J 高分子学报
%D 2009
%I 
%X Enantiopure methacrylamide derivative,N-o-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl] methacrylamide ((S)-MeOPMAM) was synthesized and radically polymerized in the presence of rare earth metal trifluoromethanesulfonates (Ln(OTf)3,Ln = La,Nd,Sm,and Y) to yield corresponding optically active polymers.Among these Lewis acids,Y(OTf)3 was found to be most effective for increasing the isotactic specificity during the radical polymerizations when using n-butanol as a solvent.The effect of the Lewis acids was si...
%K Radical polymerization
%K Rare-earth salts
%K Stereoregularity
%K Optically active polymer
%K Chiral recognition<br>自由基聚合
%K 稀土盐
%K 立构规整性
%K 光学活性聚合物
%K 手性识别
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=87EFB9E8DCFE48B6B262B6D7FC3EBB89&yid=DE12191FBD62783C&iid=5D311CA918CA9A03&sid=FA519F4FF622280A&eid=5E191A234CD3698F&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=28