STUDY ON ELECTROCHEMICAL CORROSION OF COPPER BY IR SPECTROELECTROCHEMISTRY AND QUANTUM CHEMISTRY METHODS
铜的电化学腐蚀过程的红外光谱电化学及量子化学方法研究

An ultra-thin layer IR spectroelectrochemical cell was designed for in-situ monitoring the electrochemical corrosion of copper.The cell shows a very good electrochemical properties and response of IR spectroelectrochemical behavior.In 1.0 mol/LKCl aqueous solution,copper corrosion was companied with the formation of a series copper(I)chlorides.By means of quantum chemistry calculation(ab initio and arguslab),it has provided that among several copper chlorides,the one with three chlorides is the stable one.T...