%0 Journal Article
%T STUDY ON ELECTROCHEMICAL CORROSION  OF COPPER BY IR SPECTROELECTROCHEMISTRY  AND QUANTUM CHEMISTRY METHODS<br>铜的电化学腐蚀过程的红外光谱电化学及量子化学方法研究
%A ZHU Yong-chun
%A WANG Lin
%A XU Yan
%A HE Yi
%A ZHAO Le
%A YANG Cui
%A ZHANG Yuan-yuanUniversity Laboratory of Liaoning Province on Separations
%A Analysis in Complex Systems
%A Chemistry
%A <br>朱永春
%A 王琳
%A 徐雁
%A 何怡
%A 赵乐
%A 杨翠
%A 张园园
%J 腐蚀科学与防护技术
%D 2009
%I 
%X An ultra-thin layer IR spectroelectrochemical cell was designed for in-situ monitoring the electrochemical corrosion of copper.The cell shows a very good electrochemical properties and response of IR spectroelectrochemical behavior.In 1.0 mol/LKCl aqueous solution,copper corrosion was companied with the formation of a series copper(I)chlorides.By means of quantum chemistry calculation(ab initio and arguslab),it has provided that among several copper chlorides,the one with three chlorides is the stable one.T...
%K IR spectroelectrochemistry
%K ultra-thin layer spectroelectrochemical cell
%K corrosion of copper
%K quantum chemical calculations<br>红外光谱电化学
%K 超薄层电解池
%K 铜腐蚀
%K 量子化学计算
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=AB188D3B70B071C57EB64E395D864ECE&jid=9F6E6EC8BA5BB62698F6640073DDD6E1&aid=FE9F5D21920570327C346F38418FFC6C&yid=DE12191FBD62783C&vid=659D3B06EBF534A7&iid=38B194292C032A66&sid=FD7C952458BFB5D8&eid=6CCE24D86D03D083&journal_id=1002-6495&journal_name=腐蚀科学与防护技术&referenced_num=0&reference_num=7