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Interface Reaction of SiO2/Ta and Its Influence on Cu Diffusion
SiO_2/Ta界面反应及其对铜扩散的影响(英文)

Keywords: copper interconnection in ULSI,diffusion barrier,interface reaction,X-ray photoelectron spectroscopy
ULSI铜互连
,扩散阻挡层,界面反应,X射线光电子能谱

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Abstract:

Ta/NiFe film is deposited on Si substrate precoated with SiO_2 by magnetron sputtering.SiO_2/Ta interface and Ta_5Si_3 standard sample are investigated by using X-ray photoelectron spectroscopy (XPS) and peak decomposition technique.The results show that there is a thermodynamically favorable reaction at the SiO_2/Ta interface:37Ta+15SiO_2=5Ta_5Si_3+6Ta_2O_5.The more stable products Ta_5Si_3 and Ta_2O_5 may be beneficial to stop the diffusion of Cu into SiO_2.

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