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Crystals  2012 

Spin and Charge Transport in the X-ray Irradiated Quasi-2D Layered Compound: κ-(BEDT-TTF)2Cu[N(CN)2]Cl

DOI: 10.3390/cryst2020579

Keywords: organic, two dimensional, X-ray irradiation

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Abstract:

The interplane spin cross relaxation time Tx measured by high frequency ESR in X-ray irradiated κ-(BEDT-TTF) 2Cu[N(CN) 2]Cl is compared to the interplane resisitivity ρ⊥and the in-plane resistivity ρII between 50 K and 250 K. The irradiation transforms the semiconductor behavior of the non-irradiated crystal into metallic. Irradiation decreases Tx , ρ⊥ and ρII?but the ratio Tx/ ρ⊥?and ρ⊥/ ρII?remain unchanged between 50 and 250 K. Models describing the unusual defect concentration dependence in κ-(BEDT-TTF) 2Cu[N(CN) 2]Cl are discussed.

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