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物理学报 2012
Key issues for high-efficiency silicon thin film solar cells prepared by RF-PECVD under high-pressure-depletion conditions
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Abstract:
Our recent work on deposition and characterization of hydrogenated microcrystalline silicon(μc-Si:H) thin films and silicon thin film solar cells prepared by RF-PECVD under high-pressure-depletion conditions is summarized in this paper.Several key issues are studied in detail:1) process windows for device-qualityμc-Si:H thin films,2) formation mechanism of amorphous silicon incubation layer and the effective methods to reduce the incubation layer thickness,3) modification of crystalUne fraction volume of intrinsicμc-Si:H layers and its influence on the device performance ofμc-Si:H solar cells,4) deposition of high conductive p-typeμc-Si:H window layers with high crystalline fraction volume,and the influence of p-layer on the device performance.After solving the above key issues,a high efficiency of 8.16%is obtained forμc-Si:H sing-junction solar cell with intrinsic layer prepared by RF-PECVD under high-pressure-depletion conditions.When it is used as bottom cell in a-Si:H/μc-Si:H tandem solar cell,the efficiency of tandem cell reaches 11.61%.