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OALib Journal期刊

ISSN: 2333-9721

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Rubber recovery from centrifuged natural rubber latex residue using sulfuric acid
Wirach Taweepreda
Songklanakarin Journal of Science and Technology , 2013,
Abstract: Waste latex sludge from centrifuged residue, which is a null by-product of concentrated latex manufacturing, wasdigested to retrieve the rubber by using sulfuric acid. It was found that the acid concentration and digestion time have aneffect on the amount and purity of the retrieved rubber. Sulfuric acid at concentrations of more than 10% by weight with adigestion time of 48 hours completely digested waste latex sludge and gave rubber 10% by weight. The quality of the retrievedrubber was examined for Mooney viscosity (MV), plasticity retention index, nitrogen content, and ash content. The averagemolecular weight of the retrieved rubber, using gel permeation chromatography, was lower than that of normal natural rubber(NR) which corresponds with the MV and initial plasticity (Po). The molecular structure from Fourier transform infraredspectroscopy (FT-IR) indicated that the retrieved rubber surface is wet composed with hydroxyl functional ended group.The residue solution was evaporated and crystallized. The structure of crystals was determined using power X-ray diffractometer.
Effects of nitrile rubber and multi
Guirong Peng,Wenpei Liu,Xiaojia Zhao,Yang Yang
- , 2018, DOI: 10.1177/0954008317733527
Abstract: Carbon fiber–reinforced epoxy resin composites (CF/EP) modified with nitrile rubber (NBR) and multi-walled carbon nanotube (CNT) were prepared, and their shape memory behavior and physical mechanical properties were studied. NBR/CF/EP composite showed a relative lower bending strength than pure CF/EP composite, and a remarkable increase of bending strength was achieved for CNT/CF/EP composite. The bending strength of all samples increased after postcure process. All samples showed a similar glass transition temperature, but CNT/CF/EP composite could recover at lower temperature and faster speed, while NBR/CF/EP composite was just the opposite. During folding-recovery cycles, internal damage increased with folding times, which led to a general decrease in bending strength, storage modulus, and shape recovery ratio. The anomaly of slight increase in bending strength resulted from the further curing at high temperature during the folding-recovery cycles. Among the three kinds of samples, NBR/CF/EP composite showed the best folding-recovery precision, recovery repeatability, and recovery capability of bending strength, which was considered resulting from the various damage mechanisms. Compared with the cracks in the CNT/CF/EP composite, the rubber deformation and plastic deformation of the matrix of NBR/CF/EP composite prior to the occurrence of cracks were easier to recover during the inadvertent or intentional postcure process
Study the Effect of Recycled Tire Rubber on the Mechanical and Rheological Properties of TPV (HDPE/Recycled Tire Rubber)  [PDF]
Ziyad T. Al-Malki, Einas A. Al-Nasir, Moayad N. Khalaf, Raed K. Zidan
Open Journal of Polymer Chemistry (OJPChem) , 2013, DOI: 10.4236/ojpchem.2013.34017
Abstract:

Thermoplastic elastomeric blends prepared from blending of (10%, 20%, 30%, 40% and 50 wt%) high density polyethylene(HDPE) and (10%, 20%, 30%, 40% and 50 wt%) ground rubber tire (TPV-R). The blends prepared contain (HDPE)/polybutadiene (TPV-V). The two blends were successfully prepared through a dynamic vulcanization process, involving dicumyl peroxide (3%) as vulcanizing agent. The data of the mechanical (tensile strength at yield, %elongation and young modulus) and rheological properties (shear stress, shear rate, viscosity, flow behavior index and activation energy of melt flow) of the TPV-V and TPV-R showed that there was comparable results between the two blends.

Investigation of the Potential of Using Liquid Rubbers in Rubber Industry  [PDF]
Emine Demir, Gasim Altundal, Husnu Gerengi, Canan Yüksel
Journal of Materials Science and Chemical Engineering (MSCE) , 2023, DOI: 10.4236/msce.2023.119002
Abstract: Along with the developing technology in the rubber industry, the use of natural and synthetic rubbers as well as liquid rubbers has increased significantly in recent years. The formulation of the tread compound, which directly affects the performance of a tire, is generally produced from natural and synthetic rubbers. Intensive scientific studies have been carried out on liquid rubbers because they reduce the consumption of process oils used in the tire production phase and increase dispersion. In this study, the rheological and physico-mechanical properties of rubbers developed using only liquid rubber (liquid isoprene and liquid SBR) with four different viscosities and without using process oil (Styrene Butadiene Rubber—SBR) were investigated. It has been observed that the rubber blends produced by adding four different liquid rubbers to the same recipe caused changes in rheological and physico-mechanical properties compared to the reference sample. It was observed that the minimum torque/viscosity (ML), maximum torque/viscosity (MH) and curing time (t90) in some of the formulas tested decreased significantly due to the use of liquid rubber.
Genocide and Ethnocide in the Amazon Basin during the Rubber Boom (1880 to 1920)  [PDF]
Carlos Junquera Rubio
Open Journal of Political Science (OJPS) , 2024, DOI: 10.4236/ojps.2024.143027
Abstract: The rubber boom was established between 1880 and 1920. Between those years, latex generated a true economic fever worldwide and the Amazon entered fully into international trade. The reason was that Carlos Goodyear managed to vulcanize this material in 1839 and from that moment on it found application for bicycle wheels, which meant a social revolution, especially in the United States of America and Europe. In a brief time, it was also applied to automobiles. It was a triumph that could satisfy the need of several industries that had been waiting for some time for some lucky inventor to discover the secrets of this material and guide its industrial and commercial application. On the other hand, the raw material, in its two species, was found in the Amazon, but the extraction of latex in its two versions was required: Hevea brasiliensis, and Castilloa elastica. Achieving this meant uncontrolled deforestation in Brazil, because the separation technique was to cut down each tree; but not so in Peru where each specimen was bled, leaving it where it was (Flores Marín, 1987). Likewise, the boom meant enslaving, deporting and murdering people from Amazonian societies. These last aspects are what will be evaluated here along with some proper names of rubber tappers, who were accused of murders, deportations, exterminations, etc.
Processing and Material Characteristics of a reclaimed Ground Rubber Tire Reinforced Styrene Butadiene Rubber  [PDF]
Debapriya De, Debasish De
Materials Sciences and Applications (MSA) , 2011, DOI: 10.4236/msa.2011.25066
Abstract: Mechanochemically partially devulcanized ground rubber tire (GRT) was revulcanized in composition with virgin styrene butadiene rubber (SBR). Reclaiming of GRT was carried out by tetra methyl thiuram disulfide (TMTD) in presence of spindle oil. The cure characteristics and tensile properties of SBR compounds were investigated. Results indicate that the minimum torque and Mooney viscosity of the SBR compounds increase with increasing reclaim rubber (RR) loading whereas the scorch time remain unaltered but optimum cure time exhibit a decreasing trend. Increasing RR loading also gives SBR compounds better resistance towards swelling but the 100% modulus, 200% modulus tensile strength, and the elongation at break increases. Thermogravimetric analysis of SBR/RR vulcanizates was carried out in order to get thermal stability of the vulcanizates. Scanning electron microscopy (SEM) studies further indicate the coherency and homogeneity in the SBR/RR vulcanizates.
Influence of Poly(vinyl chloride) on Natural Rubber/Chlorosulfonated Polyethylene Blends  [PDF]
Manisara Phiriyawirut, Sawanya Luamlam
Open Journal of Organic Polymer Materials (OJOPM) , 2013, DOI: 10.4236/ojopm.2013.34013
Abstract:

Blend of natural rubber (NR) and chlorosulfonated polyethylene (CSM) was so interesting due to binding of the good oil resistance of CSM, the good mechanical properties and low cost of NR. However, due to the different polarities of two rubbers, phase separation and inferior properties of NR/CSM blend were obtained. The practical way to improve its properties is the addition of the third component to bind both phases of the blend. Effects of poly(vinyl chloride), PVC as compatibilizer on cure characteristics, morphology, mechanical properties and automotive fuel resistance of NR/ CSM blend were investigated. In this contribution, NR/CSM blend with blend ratio of 50/50 was prepared using a two-roll mill, and then vulcanized in a compression mold at 160°C. The PVC content was varied from 1 to 7 phr. It was found that the usage of 7 phr PVC led to improve interaction between NR and CSM phases. Therefore, increase in cure characteristics, mechanical strength and automotive fuel resistance of the blend was observed.

Natural Rubber/Fluoro Elastomer Blends: Effect of Third Component on Cure Characteristics, Morphology,Mechanical Properties, and Automotive Fuel Swelling  [PDF]
Manisara Phiriyawirut, Thalatchanan Limwongwatthananan, Surawut Kaemram, Sirithada Wiengkaew
Open Journal of Polymer Chemistry (OJPChem) , 2013, DOI: 10.4236/ojpchem.2013.34014
Abstract:

The natural rubber (NR) was mixed with fluoro elastomer (FKM), due to the difference of polarity in NR and FKM made this blend incompatible so the third component was used. NR/FKM blended with the blend ratio of 70/30 was prepared by using a two-roll mill and vulcanization in a compression mold at 180℃ using peroxide as a curative agent. Epoxidized natural rubber (ENR) or polyisoprene-graft-maleic acid monomethyl ester (PI-ME) was used as a third component. The curing characteristics, morphology, mechanical properties, and automotive fuel swelling were investigated. The results indicated that the scorch time and cure time of the blend rubbers were longer as adding ENR or PI-ME. Both mechanical properties and automotive fuel resistance of the blend rubbers were found to increase with adding ENR in rubber blend. Conversely for adding PI-ME, automotive fuel resistance of the blend rubbers was found to decrease progressively with increasing PI-ME content.

A 5-Year Review of Gynaecological Oncology Patients Managed by a Fast Track Surgery Program  [PDF]
Jonathan Carter, Shannon Philp, Rachel O’Connell
International Journal of Clinical Medicine (IJCM) , 2014, DOI: 10.4236/ijcm.2014.51008
Abstract:

Introduction: The aim of this study is to provide a comprehensive 5-year audit of patients undergoing laparotomy for suspected or confirmed gynaecological malignancy to document the frequency and incidence of adverse events and to investigate factors associated with shorter length of stay and readmission to hospital. Methods: A 5-year surgical audit of the period commencing 2008 and concluding 2012. All patients undergoing laparotomy were included in the audit without exclusions. Approval was granted by the local Ethics Review Committee. Results: Four hundred and twenty-seven patients underwent laparotomy for suspected or confirmed gynaecological malignancy and were managed by Fast Track Surgery (FTS) principles. Average age was 54.8 years and average weight and BMI were 73.4 kg and 28.1 respectively. Ultimately 254 (59%) patients had confirmed malignancy. Average surgery duration was 2.36 hours and average estimated blood loss (EBL) at surgery was 262 mL. Median and mean LOS was 3.0 and 3.5 days respectively with 125 (29%) patients discharged on day 2. Overall transfusion rate was 5%. Other adverse events in decreasing frequency were hospital readmission (3.7%), significant wound infection (3%) and unplanned High Dependency Unit (HDU) admission (1.4%). All other adverse events were uncommon with rates <0.5%. Factors associated with a short LOS included year of surgery, age, performance status, malignant vs benign pathology, the use of COX-2 inhibitors, operation time, incision type, transfusion, and radical hysterectomy, at least 1 complication, if patients tolerated early oral feeding (EOF). In multivariable analysis, year, age, performance status, the use of COX-2 inhibitors, operation time and incision type were significant. Factors associated with readmission included the use of COX-2 inhibitors, operation time, performance of a lymph node dissection, return to operating theatre, operation category at least 1 complication, and in multivariable analysis lymph node dissection and the occurrence of at least 1 complication were significant. Conclusions: This 5-year audit is important in establishing a contemporary incidence and the prevalence rate of serious adverse events for patients with suspected or confirmed gynaecological cancer undergoing laparotomy and managed by FTS principles. The community can be reassured that the incidence of serious adverse events is low when managed by FTS principles.

Lessons Learned from Aquifer Storage and Recovery (ASR) Systems in the United States  [PDF]
Frederick Bloetscher, Chi Ho Sham, Joseph J. Danko III, Samuel Ratick
Journal of Water Resource and Protection (JWARP) , 2014, DOI: 10.4236/jwarp.2014.617146
Abstract: This paper is the result of a survey and analyses of available data from 204 Aquifer Storage and Recovery (ASR) sites in the United States. This ASR site survey included all active and inactive sites and collected both operational and construction details. The inactive sites are of particular interest here because these are the projects from which valuable lessons can often be learned. The intent of this paper is to examine the reasons for those projects that are terminated. Statistical analyses indicated that there were factors associated with terminated ASR projects: general geographic location (e.g., region), operational issue, storage cycle, casing material, and injection formation. The injection formation involves local geology and aquifer characteristics (i.e., whether the aquifer is leaky and/or unconfined, and if water can be displaced to surface water bodies or adjacent aquifers). Operational problems associated with inactive projects include well clogging, metals mobilization, a low percentage of recovery for injected water, and disinfection byproducts in the recovered water.
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