全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Experimental Process of Coagulation-Floculation by Aluminum Sulfate of Surface Waters of the Djiri River (Brazzaville, Congo)

DOI: 10.4236/wjet.2026.144049, PP. 792-806

Keywords: Water Organique Mater, Coagulation-Floculation, Aluminum Sulfate, Mechanisms, Adsorption

Full-Text   Cite this paper   Add to My Lib

Abstract:

This article investigates the coagulation-flocculation of surface water from the Djiri River using aluminum sulfate via jar tests, considering pH and coagulant dosage as the primary operating variables. The study reports improved TOC removal rates of 67% and 92%, respectively, at a moderately acid pH (5.5 to 6.5) and with increasing coagulant dosages (1 to 4 mL), for initial TOC concentrations in the 6 to 21 mg/L range. The manuscript also interprets the removal mechanisms using correlation analysis and a Freundlich adsorption-type approach. Analysis of the Freundlich isotherm reveals very good R2 correlation coefficients, ranging from 0.88 to 0.99, for various TOC concentrations and varying coagulant dosages. The experimental TOC removal process could be the result of a phenomenon favoring adsorption onto aluminum hydroxide flocs.

References

[1]  Jayaprakash, M., Giridharan, L., Venugopal, T., Krishna Kumar, S.P. and Periakali, P. (2008) Characterization and Evaluation of the Factors Affecting the Geochemistry of Groundwater in Neyveli, Tamil Nadu, India. Environmental Geology, 54, 855-867.
https://doi.org/10.1007/s00254-007-0868-6
[2]  Tiwari, K.K., Prasad, R.N., Chandra,. R., et al. (2012) Geochem Parameters for Assessment of Groundwater Quality around Urban and Suburban Areas of Dausa City in Rajasthan, India. Applied Geochemistry, 14, 184-193.
[3]  Saab, H.B., Nassif, N., El Samrani, A.G., Daoud, R., Medawar, S. and Oua?ni, N. (2007) Suivi de la qualité bactériologique des eaux de surface (rivière Nahr Ibrahim, Liban). Revue des sciences de l’eau, 20, 341-352.
https://doi.org/10.7202/016909ar
[4]  Ozturk, D., Sahan, T., Bayram, T. and Erkus, A. (2017) Application of Response Surface Methodology (RSM) to Optimize the Adsorption Conditions of Cationic Basic Yellow 2 onto Pumice Samples as a New Adsorbent. Fresenius Environmental Bulletin, 26, 3285-3292.
[5]  Ngoubou, R.C., Dinga, J.B. and Nganga, D. (2021) Diagnosis of Lead Pollution of Surface Waters of a River: Case of the Djiri River in the Republic of Congo. Journal of Water Resource and Protection, 13, 173-189.
https://doi.org/10.4236/jwarp.2021.133010
[6]  Bliefert, C. and Perraud, R. (2008) Chimie de l’environnement: Air, eau, sols, dechets. 2nd Edition, Glen De Boeck.
[7]  Wei, Y., Ji, Q., Chen, L., Hao, J., Yao, C. and Dong, X. (2017) Preparation of an Inorganic Coagulant-Polysilicate—Magnesium for Dyeing Wastewater Treatment: Effect of Acid Medium on the Characterization and Coagulation Performance.
https://www.sciencedirect.com/science/article/abs/pii/S1876107017300330?via%3Dihub
[8]  Balik, ?.Y. and Aydin, S. (2016) Coagulation/Flocculation Optimization and Sludge Production for Pre-Treatment of Paint Industry Wastewater. Desalination and Water Treatment, 57, 12692-12699.
https://doi.org/10.1080/19443994.2015.1051125
[9]  Aldemir, A., Hakk?tan?r, E. and ?zgüven, A. (2021) Determination of Optimum Treatment Conditions for Paint Industry Wastewater with the Coagulation/Flocculation Method. Desalination and Water Treatment, 211, 165-176.
https://doi.org/10.5004/dwt.2021.26624
[10]  Erkus, A., Oygun, E., Türkmenoglu, M. and Aldemir, A. (2018) Characterization of Paint Industry Wastewater. Journal of the Institute of Natural & Applied Sciences, 23, 308-319.
[11]  Hecini, L. and Achour, S. (2017) Phenylalanine and Catechol Flocculation Tests and Mechanisms in the Presence of Aluminium Sulphate. Larhyss Journal, 29, 341-354.
[12]  Wood, S.N. (2003) Thin Plate Regression Splines. Journal of the Royal Statistical Society Series B: Statistical Methodology, 65, 95-114.
https://doi.org/10.1111/1467-9868.00374
[13]  Achour, S. and Guesbaya, N. (2005) Coagulation-Floculation par le sulfate d’aluminium de composes organiques phenoliques et de substances humiques. Larhyss Journal, 4, 153-168.
[14]  APHA, AWWA and WPCF (1994) Standard Methods for the Examination of Water and Wastewater. 15th Edition, American Public Health Association.
[15]  OMS (2000) Directives de qualité pour l’eau de boisson. Critères d’hygiène et documentation à l’appui. 2nd Edition, 1050 p.
[16]  Atteia, O. (2005) Chimie et pollution des eaux souterraines. Lavoisier, TEC & DOC, 398p.
[17]  Mannino, A., Novak, M.G., Hooker, S.B., Hyde, K. and Aurin, D. (2014) Algorithm Development and Validation of CDOM Properties for Estuarine and Continental Shelf Waters along the Northeastern U.S. Coast. Remote Sensing of Environment, 152, 576-602.
https://doi.org/10.1016/j.rse.2014.06.027
[18]  Myklestad, S.M. (2000) Dissolved Organic Carbon from Phytoplankton. In: The Handbook of Environmental Chemistry, Springer-Verlag, 111-148.
https://doi.org/10.1007/10683826_5
[19]  Birgand, F., Novince, E., Gruau, G. and Bioteau, T. (2004) Facteurs expliquant la presence de matieres organiques dans les eaux superficielles en bretagne: Analyse des donnees existantes. Rapport drass et region bretagne. 78p.
[20]  Chantigny, M.H. (2003) Dissolved and Water-Extractable Organic Matter in Soils: A Review on the Influence of Land Use and Management Practices. Geoderma, 113, 357-380.
https://doi.org/10.1016/s0016-7061(02)00370-1
[21]  Jekel, M. (1986) Interactions of Humic Acids and Aluminum Salts in the Flocculation Process. Water Research, 20, 1535-1542.
https://doi.org/10.1016/0043-1354(86)90118-1
[22]  Semmens, M.J. and Ayers, K. (1985) Removal by Coagulation of Trace Organics from Mississippi River Water. Journal AWWA, 77, 79-84.
https://doi.org/10.1002/j.1551-8833.1985.tb05543.x
[23]  Barabasz, W., Albińska, D., Ja?kowska, M. and Lipiec, J. (2002) Ecotoxicology of Aluminum. Polish Journal of Environmental Studies, 11, 199-203.
[24]  Van Benschoten, J.E. and Edzwald, J.K. (1990) Chemical Aspects of Coagulation Using Aluminum Salts—I. Hydrolytic Reactions of Alum and Polyaluminum Chloride. Water Research, 24, 1519-1526.
https://doi.org/10.1016/0043-1354(90)90086-l
[25]  Chadwick, O.A. and Chorover, J. (2001) The Chemistry of Pedogenic Thresholds. Geoderma, 100, 321-353.
https://doi.org/10.1016/s0016-7061(01)00027-1
[26]  von Fromm, S.F., Jungkunst, H.F., Amenkhienan, B., Hall, S.J., Georgiou, K., Pries, C.H., et al. (2025) Moisture and Soil Depth Govern Relationships between Soil Organic Carbon and Oxalate-Extractable Metals at the Global Scale. Biogeochemistry, 168, Article No. 20.
https://doi.org/10.1007/s10533-025-01208-9
[27]  Rasmussen, C., Heckman, K., Wieder, W.R., Keiluweit, M., Lawrence, C.R., Berhe, A.A., et al. (2018) Beyond Clay: Towards an Improved Set of Variables for Predicting Soil Organic Matter Content. Biogeochemistry, 137, 297-306.
https://doi.org/10.1007/s10533-018-0424-3
[28]  Lefebvre, E. and Legube, B. (1990) Coagulation par Fe (III) de substances humiques extraites d’eaux de surface: Effet du pH et de la concentration en substances humiques. Water Research, 24, 591-606.
https://doi.org/10.1016/0043-1354(90)90192-9
[29]  Al-Malack, M.H., Abuzaid, N.S. and El-Mubarak, A.H. (1999) Coagulation of Polymeric Wastewater Discharged by a Chemical Factory. Water Research, 33, 521-529.
https://doi.org/10.1016/s0043-1354(98)00219-x
[30]  Tipping, E., Backes, C.A. and Hurley, M.A. (1988) The Complexation of Protons, Aluminium and Calcium by Aquatic Humic Substances: A Model Incorporating Binding-Site Heterogeneity and Macroionic Effects. Water Research, 22, 597-611.
https://doi.org/10.1016/0043-1354(88)90061-9
[31]  Cathalifaud, G., Ayele, J. and Mazet, M. (1997) Etude de la complexation des ions aluminium par des molécules organiques: Constantes et stoechiométrie des complexes. Application au traitement de potabilisation des eaux. Water Research, 31, 689-698.
https://doi.org/10.1016/s0043-1354(96)00295-3
[32]  Kida, M., Nagano, H., Shimada, H., Fukumasu, J. and Wagai, R. (2026) Organo-Aluminum Complexation as a Dominant Metal Control on Soil Carbon Storage in Andisols: Global Evidence across Pedogenic and pH Gradients. Geoderma, 467, Article 117740.
https://doi.org/10.1016/j.geoderma.2026.117740
[33]  Wang, G.S., Kang, S.F., Yang, H.J., Pai, S.Y. and Chen, H.W. (2002) Removal of Dissolved Natural Organic Matter from Source Water with Alum Coagulation. Environmental Technology, 23, 1415-1423.
https://doi.org/10.1080/09593332508618446

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133