In response to the climate challenge, the cement industry is seeking to reduce CO2 emissions associated with clinker production. This study investigates the formulation of low-carbon LC3 cements using a binary clay blending strategy that combines a highly reactive clay (70% kaolinite) with a local clay containing only 2.6% kaolinite. A mixture design methodology was applied to develop and optimize formulations with 40% and 50% clinker, incorporating calcined clays, limestone, and phosphogypsum. The results demonstrate the technical feasibility of producing LC3 cements that meet standard strength classes. In 50% clinker formulations, incorporating up to 13.2% of the low-kaolinite clay yields a 42.5 N cement, with profit margins between 23330.9 and 23528.9 CFA francs per ton. Similarly, incorporating up to 27.2% of low-kaolinite clay results in a 32.5 R cement, with profit margins ranging from 23330.9 to 23738.9 CFA francs per ton for 50% clinker formulations, and from 29844.8 to 29945.3 CFA francs per ton for 40% clinker formulations. Overall, this binary clay blending approach offers a sustainable, economically attractive, and innovative pathway for decarbonizing the African cement industry.
References
[1]
Chong, R., Zhang, W., Yin, B. and Liew, K.M. (2025) Evaluating Next-Gen Sustainable Cementitious Materials: Unleashing the Potential of LC3-Based Composites under High-Temperature Environments. JournalofCleanerProduction, 503, Article 145421. https://doi.org/10.1016/j.jclepro.2025.145421
[2]
Tovias, H.R., Martinez, J.C., Gonzalez, N.L.G. and Gonzalez, K.S. (2013) Procédé de fabrication d’un clinker pour ciment hydraulique a basse émission de CO2 et haute résistance. EP2582641A1. https://patents.google.com/patent/EP2582641A1/fr
[3]
Devi, K.S., Lakshmi, V.V. and Alakanandana, A. (2017) Impacts of Cement Industry on Environment—An Overview. Asia Pacific Journal of Research, 1, 156-161.
[4]
Kaddah, F., Amiri, O., Turcry, P., Ranaivomanana, H. and Roziere, E. (2024) Coupled Thermo-Hydro-Chemical Modeling of Accelerated Carbonation of Cement-Based Materials: Application to CO2 Uptake. JournalofBuildingEngineering, 93, Article 109819. https://doi.org/10.1016/j.jobe.2024.109819
[5]
NF EN 197-1 (2012) Cement—Part 1: Composition, Specifications and Conformity Criteria for Common Cements. AFNOR.
[6]
Scrivener, K., Martirena, F., Bishnoi, S. and Maity, S. (2018) Calcined Clay Limestone Cements (LC3). Cement and Concrete Research, 114, 49-56. https://doi.org/10.1016/j.cemconres.2017.08.017
[7]
Ma?osa, J., Calderón, A., Salgado-Pizarro, R., Maldonado-Alameda, A. and Chimenos, J.M. (2024) Research Evolution of Limestone Calcined Clay Cement (LC3), a Promising Low-Carbon Binder—A Comprehensive Overview. Heliyon, 10, e25117. https://doi.org/10.1016/j.heliyon.2024.e25117
[8]
Ijaz, N., Ye, W.M., Rehman, Z.U., et al. (2024) Global Insights into Micro-Macro Mechanisms and Environmental Implications of Limestone Calcined Clay Cement (LC3) for Sustainable Construction Applications. ScienceoftheTotalEnvironment, 907, Article 167794. https://doi.org/10.1016/j.scitotenv.2023.167794
Ghazy, M.F., Maaty, E.S.A., Elaty, M.A. and Alrwashdeh, A.A. (2025) A Comprehensive Review of Limestone Calcined Clay Cement (LC3): Environmental and Properties Benefits, Challenges, Opportunities, and Future Directions. ResultsinEngineering, 28, Article 108319. https://doi.org/10.1016/j.rineng.2025.108319
[11]
European Committee for Standardization (2016) EN 196?1, Methods of Testing Cement—Part 1: Determination of Strength.
[12]
Avet, F. and Scrivener, K. (2018) Ciments calcaire argiles calcinées—Limestone Calcined Clay Cements (LC3). Actes dela Conférence Internationale Francophone NoMaD 2018, Liège, 7-8 November 2018.
[13]
Ababneh, A.N., Al-Thiab, E.H. and Al-Shorman, B.H. (2025) Early Strength Development in Cement Mortars Containing High Proportions of Jordanian Natural Pozzolan. Results in Engineering, 27, Article 105868. https://doi.org/10.1016/j.rineng.2025.105868
[14]
Zunino, F. and Scrivener, K. (2021) The Reaction between Metakaolin and Limestone and Its Effect in Porosity Refinement and Mechanical Properties. Cement and Concrete Research, 140, Article 106307. https://doi.org/10.1016/j.cemconres.2020.106307
[15]
Dhandapani, Y., Sakthivel, T., Santhanam, M., Gettu, R. and Pillai, R.G. (2018) Mechanical Properties and Durability Performance of Concretes with Limestone Calcined Clay Cement (LC3). Cement and Concrete Research, 107, 136-151. https://doi.org/10.1016/j.cemconres.2018.02.005
[16]
Myers, R.H., Montgomery, D.C. and Anderson-Cook, C.M. (2009) Response Surface Methodology: Process and Product Optimization Using Designed Experiments. 3rd Edition, Wiley.
[17]
Ortiz, M.C., Sánchez, M.S. and Sarabia, L.A. (2009) Quality of Analytical Measurements: Univariate Regression. In: ComprehensiveChemometrics: Chemical and Biochemical Data Analysis, Elsevier, 127-169. https://doi.org/10.1016/b978-044452701-1.00091-0
[18]
Coleman, K. and Vanatta, L. (2006) Statistics in Analytical Chemistry: Part 22—Lack-of-Fit Details. American Laboratory. https://www.americanlaboratory.com/913-Technical-Articles/1238-Part-22-Lack-of-Fit-Details/