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二氧化碳与环氧化物环加成反应研究进展
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Abstract:
随着全球气候变化问题日益严峻，二氧化碳(CO2)的资源化利用已成为绿色化学与可持续发展领域的研究热点。在众多转化路径中，CO2与环氧化物的环加成反应因具有100%原子经济性而备受关注，其产物环状碳酸酯在锂离子电池电解质、绿色溶剂等领域应用广泛。本文系统总结了近年来，二氧化碳与环氧化合物通过环加成反应生产环碳酸酯方面取得的较大进展。
As the issue of global climate change becomes increasingly pressing, the resource utilization of carbon dioxide (CO2) has emerged as a research hotspot in the fields of green chemistry and sustainable development. Among the numerous conversion pathways, the cycloaddition reaction between CO2 and epoxides has attracted significant attention due to its 100% atom economy; the resulting cyclic carbonates find widespread applications in areas such as lithium-ion battery electrolytes and green solvents. This paper systematically summarizes the significant progress made in recent years in the production of cyclic carbonates via the cycloaddition reaction between carbon dioxide and epoxides.
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