|
|
苎麻增强回收聚丙烯复合材料的制备及其性能的研究
|
Abstract:
本文分别使用碱法改性和柠檬酸改性两种方法对苎麻纤维进行改性,制备了苎麻/回收聚丙烯复合材料,对材料的冲击性能、硬度、拉伸性能、耐热性能等进行了研究。结果表明,两种方法均能有效清除苎麻表面杂质,用苎麻纤维增强回收聚丙烯复合材料,可以提高废旧聚丙烯的力学性能。在苎麻纤维长度为1.5 cm,苎麻含量为6%柠檬酸改性方法下,冲击强度提升至8.222 kJ/m2,拉伸强度提升至38.2 MPa,断裂伸长率降低136%,硬度提升13.3%。在苎麻纤维长度为1.5 cm,苎麻含量为6%碱法改性方法下,冲击强度提升至6.854 kJ/m2,拉伸强度提升至为29.5 MPa,断裂伸长率降低139%,硬度提升5%。
In this paper, Ramie fibers were modified using two methods, namely alkali modification and citric acid modification. Ramie/recycled polypropylene composites were prepared, and the impact properties, hardness, tensile properties, and heat resistance of the materials were investigated. The results showed that both methods were effective in removing the surface impurities of ramie, and the mechanical properties of used polypropylene could be improved by reinforcing the recycled polypropylene composites with ramie fibers. Under the method of ramie fiber length of 1.5 cm and ramie content of 6% citric acid modification, the impact strength was increased to 8.222 KJ/m2, the tensile strength was increased to 38.2 MPa, the elongation at break was reduced by 136%, and the hardness was increased by 13.3%. Under the ramie fiber length of 1.5 cm, ramie content of 6% alkali modification method, the impact strength was increased to 6.854 KJ/m2, the tensile strength was increased to 29.5 MPa, the elongation at break was reduced by 139%, and the hardness was increased by 5%.
| [1] | Yuan, Q.H., Yang, W., Ma, Z.W., et al. (2022) Tobacco Stalk Flour/Magnesium Oxysulfate Whiskers Reinforced Hybrid Composites of Recycled Polypropylene: Mechanical and Thermal and Antibacterial Properties. Polymers, 52, 52-61. |
| [2] | 皮超雄. 车用苎麻纤维增强聚丙烯复合材料力学与阻尼性能研究[D]: [硕士学位论文]. 长沙: 湖南大学, 2018. |
| [3] | Maurya, K.L., Kumar, M., Sonwani, R.K., Jaiswal, V.K., Verma, A. and Singh, R.S. (2023) Enhancement of Azo Dye Bioremediation Using Chemically Modified Polypropylene Biocarrier: Comparative Analysis and Kinetic Modeling. Bioresource Technology Reports, 21, Article ID: 101375. https://doi.org/10.1016/j.biteb.2023.101375 |
| [4] | Yu, M., He, C., Huang, R., Liu, J. and Lu, D. (2016) Accelerated Weathering of Recycled Polypropylene Packaging Bag Composites Reinforced with Wheat Straw Fibers. Forest Products Journal, 66, 485-494. https://doi.org/10.13073/fpj-d-14-00107 |
| [5] | 张勇, 鄢勇气. 苎麻纤维化学改性研究进展[J]. 化学研究, 2021(3): 277-282. |
| [6] | 孟承翰, 罗皓文, 刘昊, 等. 柠檬酸改性苎麻纤维增强聚丁二酸丁二醇酯的性能研究[J]. 中国塑料, 2024, 38(12): 54-59. |
| [7] | 张扬, 温变英, 李晓媛, 等. 苎麻纤维表面修饰对聚丙烯/苎麻纤维复合材料性能的影响[J]. 中国塑料, 2014, 28(8): 47-51. |
| [8] | Kumar, S.K., Siva, I., Jeyaraj, P., Winowlin Jappes, J.T., Amico, S.C. and Rajini, N. (2014) Synergy of Fiber Length and Content on Free Vibration and Damping Behavior of Natural Fiber Reinforced Polyester Composite Beams. Materials & Design (1980-2015), 56, 379-386. https://doi.org/10.1016/j.matdes.2013.11.039 |
| [9] | 吕泽瑞, 黎征帆, 江惠林, 等. 苎麻纤维制备研究进展[J]. 棉纺织技术, 2020, 48(11): 68-72. |
| [10] | 王勋林. 废旧聚乙烯膜回收料的改性应用[J]. 青岛科技大学学报(自然科学版), 2010, 31(6): 608-612. |
| [11] | 洪钧, 毕松梅, 朱钦钦. 苎麻纤维增强聚丙烯复合材料的性能研究[J]. 塑料科技, 2012, 40(2): 45-47. |
| [12] | 吕陈. 苎麻纤维的柔软处理研究[D]: [硕士学位论文]. 上海: 东华大学, 2017. |
| [13] | Pratiwi, H., Kusmono, K. and Wildan, M.W. (2025) The Effect of Sodium Hydroxide and Oxalic Acid Treatments on Water Absorption, Thickness Swelling, and Hardness of Polyester/Ramie Fiber Composites. Solid State Phenomena, 372, 33-39. https://doi.org/10.4028/p-cj3xil |
| [14] | 陈林. 柠檬酸改性的苎麻纤维掺杂PBS复合材料制备及性能研究[D]: [硕士学位论文]. 合肥: 合肥工业大学, 2023. |
| [15] | 展江湖, 王迎宵, 杨志浩, 等. 苎麻纤维增强聚乳酸复合材料性能研究[J]. 工程科学学报, 2021, 43(7): 952-959. |
| [16] | 段炼. 苎麻纤维材料热处理后的性能研究[D]: [硕士学位论文]. 武汉: 武汉纺织大学, 2022. |
| [17] | 王倩. 苎麻纤维改性环氧树脂复合材料及应用性能[J]. 化学与粘合, 2024, 46(3): 240-243. |
| [18] | 李文军. 苎麻纤维/聚丙烯车用复合材料的制备及改性机理研究[D]: [博士学位论文]. 长沙: 湖南大学, 2017. |
| [19] | 齐杭杭. 酶法探究苎麻纤维的超微结构及织物改性研究[D]: [硕士学位论文]. 武汉: 武汉纺织大学, 2020. |
| [20] | 房晓萌. 三维正交苎麻机织物增强聚丙烯复合材料的制备与性能研究[D]: [硕士学位论文]. 上海: 东华大学, 2011. |