Assessment of Surface Water Quality Using the Water Quality Index (WQI) and Multivariate Statistical Analysis (MSA) in Nyanga River, Republic of the Congo
The aim of this study was to assess the physico-chemical and mineralogical quality of surface waters used by populations for their domestic and agro-pastoral activities in the Nyanga district in the south-west of the Republic of the Congo. Descriptive statistics, hydrochemistry (Piper diagram), Principal Component Analysis (PCA) and hierarchical ascending classification (HAC) were used to determine the quality, chemical facies and mineralization phenomena of surface waters. Physico-chemical analyses were carried out on 6 samples taken in May 2023. The results showed that the waters studied are acidic, with a pH between 4.99 and 5.76. They are poorly mineralized, with an average electrical conductivity of 12.37 μS/cm. In the study area, the water is chloride-calcium-magnesium and bicarbonate-calcium-magnesium. Analysis of heavy metals shows that all values, with the exception of iron and nitrate, comply with WHO guidelines on water potability, with the exception of the point sampled at the confluence of the Nyanga, where values were slightly higher than normal, i.e. 0.06 μg/L for manganese and 0.03 μg/L for nitrate. Other heavy metals such as Lead (Pb) and Copper (Cu) were analyzed and confirmed that their concentration was within the authorized detection limits. Water mineralization is controlled by phenomena such as soil rainwashing, acid hydrolysis of rocks and input from high rainfall. This study shows that water resources in the Nyanga watershed are not subject to anthropogenic pressure, but to a totally natural phenomenon. Given its acidity, untreated consumption of this water could present health risks for the population.
References
[1]
Talhaoui, A., El Hmaidi, A., Jaddi, H., Ousmana, H. and Manssouri, I. (2020) Calcul de l’indice de qualité de l’eau (IQE) pour l’évaluation de la qualité physico-chimique des eaux superficielles de l’oued moulouya (NE, Maroc). European Scientific Journal ESJ, 16, Article No. 3. https://doi.org/10.19044/esj.2020.v16n2p64
[2]
Rabearisoa, A.H., Narindrarisoa, V.H., Razanamparany, B., Manjolongo, B. and Fidiarilanto, S.T. (2023) Caractérisation physico-chimique et bactériologique de l’eau de puits du Fokontany Ambohibory Soatsihadino, région Haute Matsiatra, Madagascar. Journal of Applied Biosciences, 191, 20277-20284. https://doi.org/10.35759/jabs.191.8
[3]
Worl Health Organization (2017) Progress on Drinking Water, Sanitaire and Hygiene: 2017 Update and SDG Baselines. Worl Health Organization.
[4]
Ahoussi, K., Koffi, Y., Kouassi, A., Soro, G. and Biemi, J. (2013) Étude hydrochimique et microbiologique des eaux de source de l’ouest montagneux de la Côte d’Ivoire: Cas du village de Mangouin-Yrongouin (souspréfecture de Biankouman). Journal of Applied Biosciences, 63, Article 4703. https://doi.org/10.4314/jab.v63i1.87245
[5]
INS (2023) Cinquieme recensement général de la population et de l’habitation (RGPH-5).
[6]
Mbilou Gampio, U., Ngouala Mabonzo, M., Koua Bita, B. and Samba-Kimbata, M.J. (2016) Régimes des écoulements de surface dans un bassin versant hydrologique côtier: cas du bassin hydrologique de la Nyanga en République du Congo. Afrique Science, 12, 271-281.
[7]
Bouquet, A. (1967) Inventaire des plantes médicinales et toxiques du Congo-Brazzaville. Office de la Recherche Scientifique et Technique Outre-Mer (ORSTOM), 34.
[8]
American Public Health Association (1998) Standard Methods for the Examination of Water and Wastewater. American Public Health Association, American Water Works Association and Water Environmental Federation.
[9]
Rodier, J., Legube, B., Merlet, N. and Brunet, R. (2009) L’analyse de l’eau: Eaux naturelles, eaux résiduaires, eaux de mer. Dunod Editions.
[10]
Ngouala Mabonzo, M., Mbilou, U.G. and Koussoubé, Y. (2020) Hydrochimie des eaux sou-terraine du bassin versant de la Loua au sud de Brazzaville. American Journal of Innovative Research and Applied Sciences, No. 1, 4.
[11]
Assemien François Yao, K., Ernest Ahoussi, K., Blaise Koffi, Y., Moin Sandrine Tivoli, L., Salze, D. and Lopez-Ferber, M. (2023) Caractérisation Hydro-Chimique et Évaluation de la Qualité des Eaux Souterraines de l’Environnement Minier du Canton Afema (Sud-Est de la Côte d’Ivoire). European Scientific Journal, ESJ, 19, Article 248. https://doi.org/10.19044/esj.2023.v19n6p248
[12]
Bassakouahou, G., Mbilou Gampio, U. and Ngouala Mabonzo, M. (2022) Caractérisation hy-drochimique des eaux de surface du bassin versant de la Loutété (sud de la Ré-publique du Congo). Journal of Animal & Plant Sciences, 54, 5.
[13]
Traore, A., Soro, T.D., Dibi, B. and Yao, L.J.A. (2022) Caractérisation hydrogéochimique des eaux souterraines du département de Man (Ouest de la Côte d’Ivoire). International Journal of Biological and Chemical Sciences, 16, 498-514. https://doi.org/10.4314/ijbcs.v16i1.40
[14]
Guillén, M.T., Delgado, J., Albanese, S., Nieto, J.M., Lima, A. and De Vivo, B. (2012) Heavy Metals Fractionation and Multivariate Statistical Techniques to Evaluate the Environmental Risk in Soils of Huelva Township (SW Iberian Peninsula). Journal of Geochemical Exploration, 119, 32-43. https://doi.org/10.1016/j.gexplo.2012.06.009
[15]
OMS (2011) Directives de qualité pour l’eau de Boisson. OMS.
[16]
Brown, R.M., Mc Clelland, N.I., Deininger, R.A. and Tozer, R.G. (1970) A Water Quality Index: Do We Dare? Water and Sewerage, 117, 339-343.
[17]
Steduto, P., Faurès, J.-M., Hoogeveen, J., Winpenny, J. and Burke, J. (2021) Coping with Water: Scarcity: An Action Framework for Agriculture and Food Security. FAO Water Report, 16, 78.
[18]
Usman, M., Liedl, R. and Awan, U.K. (2015) Spatiotemporal Estimation of Consumptive Water Use for Assessment of Irrigation System Performance and Management of Water Resources in Irrigated Indus Basin, Pakistan. Journal of Hydrology, 525, 26-41. https://doi.org/10.1016/j.jhydrol.2015.03.031
[19]
Tohouri, P., Anongba, B.V.R.B., Adja, G.M., Djemin, J.E. and Biemi, J. (2022) Aptitude à l’irrigation des eaux de la nappe du continental terminal de bonoua (Sud-est de la Côte d’Ivoire. International Journal of Progressive Sciences and Technologies, 35, 8.
[20]
Samtio, M.S., Hakro, A.A.a.D., Jahangir, T.M., Mastoi, A.S., Lanjwani, M.F., Rajper, R.H., et al. (2023) Impact of Rock-Water Interaction on Hydrogeochemical Characteristics of Groundwater: Using Multivariate Statistical, Water Quality Index and Irrigation Indices of Chachro Sub-District, Thar Desert, Sindh, Pakistan. Groundwater for Sustainable Development, 20, Article 100878. https://doi.org/10.1016/j.gsd.2022.100878
[21]
Kelley, W.P. (1963) Use of Saline Irrigation Water. Soil Science, 95, 385-391. https://doi.org/10.1097/00010694-196306000-00003
[22]
Kuang, H., Bai, H., Peng, N., Qi, K., Wang, Y., Chen, X., et al. (2022) Temporal and Spatial Distribution of Precambrian Red Beds and Their Formation Mechanisms. Geosystems and Geoenvironment, 1, Article 100098. https://doi.org/10.1016/j.geogeo.2022.100098
[23]
Abdelghani, G., Jaouad, G. and Carmelo Conesa, G. (2001) Hydrochimie des eaux, dissolution spécifique et salinité des cours d’eau dans le bassin de l’oued Lebène (Prérif Central, Maroc septentrional). Papeles de Geografia, 34, 6.
[24]
Grimaldi, C. (1988) Origine de la composition chimique des eaux superficielles en milieu tropical humide: Exempte de deux petits bassins versants sous forêt en Guyane française. Sciences Géologiques. Bulletin, 41, 247-262. https://doi.org/10.3406/sgeol.1988.1797
[25]
Moukolo, N. (2000) Le bassin du fleuve Congo: modalités des écoulements de surface et souterrains. Approche des échanges hydriques surface/Souterrain en milieu continu (hydrologie-hydrogéologie-hydrochimie). Thèse de Doctorat, Université Cheikh Anta Diop.
[26]
Matini, L., Moutou, J.M. and Kongo-Mantono, M.S. (2009) Hydrogeochemical Evaluation of Underground Water in an Urban Environment in the Southwest of Brazzaville, Congo Afrique Science: Revue Internationale des Sciences et Technologie, 5, 82-98. https://doi.org/10.4314/afsci.v5i1.61709
[27]
Mbilou, U.G., Tchoumou, M., Ngouala, M.M. and Balounguidi, J. (2016) Hydrogeochemical and Microbiological Characterization of Groundwater in the Multilayer Aquifer System of Pointe-Noire Region in the Republic of Congo. Larhyss, Journal of Hydraulic Sciences, 28, 257-273.
[28]
Moukandi-Nkaya, G.D. (2012) Hydrogeological and Hydrochemical Study in Situ and Hydrodynamic Modeling of the Aquifer System of Sedimentary Basin of the Pointe-Noire Region. Doctoral Thesis, Marien Ngouabi University.
[29]
Kozisek, F. (2005) Health Risks from Drinking Demineralised Water. In: National Institute of Public Health Czech Republic, Ed., Nutrients in Drinking Water, Word Health Organization, 148-163.
[30]
Mukwita Ntwabwa, J., Kamb, J.-C.T., Mutambel’Hity, D.S.N., Mbungu Sisa, E. and Kipimbye, J.L. (2023) Détermination de la qualité physique et chimique et analyse des mi-cropolluants des eaux de la rivière Lunkunga a Kinshasa. International Journal of Progressive Sciences and Technologies, 36, 8.
[31]
Abboudi, A., Tabyaoui, H. and El Hamichi, F. (2014) Etude de la qualité physi-co-chimique et contamination métallique des eaux de sur-face du bassin versant de. European Scientific Journal, 10, 85-92.
[32]
Soro, N. (2002) Hydrochimie et géochimie isotopique des eaux souterraines du degré carré de Grand-Laou et ses environs (sud-ouest de la Côte d’Ivoire). Implication hy-drologique et hydrogéologique. Thèse d’Etat, Université de Cocody, 272.
[33]
Lions, J., Pinson, S. and Parizot, M. (2009) Identification des zones à risque de fond géochimique élevé dans les cours d’eau et les eaux souterraines de la Guyane. Rapport BRGM.