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Modelo reológico para la transición de fase sol-gel de fracciones pesadas del petróleo termoenvejecidas

Keywords: rheology, rheological model, asphalt, aging.

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Abstract:

a power-law rheological model is proposed in this paper: g′′ (w) ~ wn and g′ (w) ~ wn. it represents the increased connectivity between thermo-aged asphalt molecules in a rheo-reactor as one of the applications of systematic rheology. the results confirmed a sol-gel phase transition tendency for aged asphalt in the experimental frequency window at temperatures below 40°c. such pattern could have been related to the structuring effect arising from the thermo-oxidative asphalt aging process during continuous agitation which has been suitably described by the micellar model of asphalt.

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