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Fabrication of a new porous glass-ceramic monolith using vanadium(III) calcium phosphate glass as precursor

DOI: 10.1590/S0103-50532004000400003

Keywords: porous materials, vanadium metaphosphate, calcium orthovanadate, vanadium glass, devitrification.

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Abstract:

preliminary xrd, ir, raman and sem data indicate that porous glass-ceramic monoliths (pgc-lvcp) with skeleton of v(po3)3 and ca3(vo4)2 with three-dimensional network structure using an original li2o-v2o3-cao-p 2o5 glass as precursor was obtained. the pgc-lvcp is a promising porous host for integrated chemical systems because the ca3(vo4)2 has ferroelectric and luminophor properties while v(po3)3 exhibits magnetic properties associated with high degree of mechanical, chemical and thermal stability.

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