This paper presents a systematic numerical analysis of the Band Gap Narrowing (BGN) effect in indium gallium nitride (InGaN) solar cells for two indium molar fractions (x = 0.12 and x = 0.28) at T = 300 K. By sweeping the donor doping concentration N from 1016 to 3 × 1018 cm?3, we quantify the reduction of the effective band gap energy (Egeff) and the resulting red-shift of the optical cutoff wavelength (λcut). Results show that BGN intensifies non-linearly with doping and is systematically more pronounced for higher indium content. At the highest doping level (3 × 1018 cm?3), λcut shifts by +154 nm for x = 0.12 and by +378 nm for x = 0.28, extending absorption deep into the visible spectrum. These findings underline the necessity of a careful trade-off between spectral coverage and material quality degradation in the design of high-efficiency InGaN photovoltaic devices.
References
[1]
Wu, J., Walukiewicz, W., Yu, K.M., Shan, W. and Ager III, J.W. (2003) Superior Radiation Resistance of In1?xGaxN Alloys. JournalofAppliedPhysics, 94, 6477-6482. https://doi.org/10.1063/1.1618353
[2]
Bhuiyan, A.G., Sugita, K., Hashimoto, A. and Yamamoto, A. (2012) InGaN Solar Cells: Present State of the Art and Important Challenges. IEEEJournalofPhotovoltaics, 2, 276-293. https://doi.org/10.1109/jphotov.2012.2193384
[3]
Zhao, Y., Xu, M., Huang, X., Lebeau, J., Li, T., Wang, D., et al. (2023) Toward High Efficiency at High Temperatures: Recent Progress and Prospects on InGaN-Based Solar Cells. Materials Today Energy, 31, Article 101229. https://doi.org/10.1016/j.mtener.2022.101229
[4]
Marouf, Y., Dehimi, L., Bencherif, H., Pezzimenti, F., Younsi, Z., Albaqami, M.D., etal. (2025) Deep Insights on the Performance of Different Structures of InGaN-Based Tandem Photovoltaic Cells: Path Towards the Design of High Efficiency PV Modules. Journal of Optics, 54, 3326-3341. https://doi.org/10.1007/s12596-024-02045-z
[5]
Jain, S.C. and Roulston, D.J. (1991) A Simple Expression for Band Gap Narrowing in Heavily Doped Si, Ge, GaAs and GexSi1-x Strained Layers. Solid-StateElectronics, 34, 453-465. https://doi.org/10.1016/0038-1101(91)90149-s
[6]
Parajuli, D., Shah, D.K., KC, D., Kumar, S., Park, M. and Pant, B. (2023) Influence of Doping Concentration and Thickness of Regions on the Performance of InGaN Single Junction-Based Solar Cells: A Simulation Approach. Electrochem, 3, 407-415. https://doi.org/10.3390/electrochem3030028
[7]
El Ghazi, H., Eker, Y.R., En-nadir, R., Zaki, S.E. and Basyooni-M. Kabatas, M.A. (2024) Enhancing Performance of Polar InGaN-Based Thin Film Solar Cells through Intrinsic Layer Impact Optimization: Numerical Modeling. Results in Engineering, 21, Article 101909. https://doi.org/10.1016/j.rineng.2024.101909
[8]
Wei, Z., Al-Nuaimi, N. and Gemming, S. (2024) Optimization of InGaN-Based Solar Cells by Numerical Simulation: Enhanced Efficiency and Performance Analysis. Next Materials, 6, Article 100325. https://doi.org/10.1016/j.nxmate.2024.100325
[9]
Alhejji, M., Alavijeh, M., Kupernik, J., et al. (2025) Investigating the Efficiency of InGaN p-n-p-n Homojunction Solar Cells. MRSAdvances, 10, 2113-2118. https://doi.org/10.1557/s43580-025-01419-0
[10]
Vegard, L (1921) Die Konstitution der Mischkristalle und die Raumfüllung der Atome. Zeitschrift für Physik, 5, 17-26. https://doi.org/10.1007/bf01349680
[11]
Moses, P.G. and Van de Walle, C.G. (2010) Band Bowing and Band Alignment in InGaN Alloys. AppliedPhysicsLetters, 96, Article 021908. https://doi.org/10.1063/1.3291055
[12]
Levinshtein, M., Rumyantsev, S. and Shur, M. (2001) Properties of Advanced Semiconductor Materials: GaN, AlN, InN, BN, SiC, SiGe. Wiley.
[13]
Abboudi, H., En-Nadir, R. and Basyooni, M.A. (2024) Enhancing the Photovoltaic Efficiency of In0.2Ga0.8N/GaN Quantum Well Intermediate Band Solar Cells Using Combined Electric and Magnetic Fields. Materials, 17, Article 5219. https://doi.org/10.3390/ma17215219