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Applied Physics 2026
Au负载量对TiO2/Au光阳极光吸收能力的影响研究
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Abstract:
为了研究Au负载量对TiO2/Au光阳极的光吸收能力的影响,本文采用水热法和柠檬酸钠还原法制备了TiO2/Au材料,通过刮涂法制备光阳极。利用紫外–可见吸收、X射线衍射(XRD)、透射电子显微镜(TEM)等手段对不同Au负载量的TiO2/Au材料和TiO2/Au光阳极进行表征分析。结果表明,Au负载量在1.0 wt%时,TiO2/Au光阳极的光吸收能力最佳;低于1.0 wt%时,Au负载量提高,TiO2/Au光阳极的光吸收能力也随之提高;高于1.0 wt%时,Au负载量提高,TiO2/Au光阳极的光吸收能力随之降低。
In this paper, in order to investigate the effect of Au loading on the light absorption ability of TiO2/Au photoanode, TiO2/Au materials were prepared by hydrothermal method and sodium citrate reduction method, and photoanode was prepared by scratch coating method. Characterization and analysis of TiO2/Au materials and TiO2/Au photoanodes with different Au loadings were carried out using UV-visible absorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), and other methods. The results showed that the TiO2/Au photoanode had the best light absorption capacity when the Au loading was 1.0 wt%; when the Au loading was below 1.0 wt%, the light absorption capacity of TiO2/Au photoanode also increased with the increase of Au loading; when the Au loading exceeded 1.0 wt%, the light absorption capacity of TiO2/Au photoanode decreased as the Au loading increased.
| [1] | Domingues, R.P., Rodrigues, M.S., Proença, M., Costa, D., Alves, E., Barradas, N.P., et al. (2018) Thin Films Composed of Au Nanoparticles Embedded in AlN: Influence of Metal Concentration and Thermal Annealing on the LSPR Band. Vacuum, 157, 414-421. https://doi.org/10.1016/j.vacuum.2018.09.013 |
| [2] | Jain, P.K., Huang, X., El-Sayed, I.H. and El-Sayed, M.A. (2008) Noble Metals on the Nanoscale: Optical and Photothermal Properties and Some Applications in Imaging, Sensing, Biology, and Medicine. Accounts of Chemical Research, 41, 1578-1586. https://doi.org/10.1021/ar7002804 |
| [3] | Chen, J., Wu, J.C.S., Wu, P.C. and Tsai, D.P. (2012) Improved Photocatalytic Activity of Shell-Isolated Plasmonic Photocatalyst Au@SiO2/TiO2 by Promoted LSPR. The Journal of Physical Chemistry C, 116, 26535-26542. https://doi.org/10.1021/jp309901y |
| [4] | Hu, X., Liao, S., Song, Q., Zhang, X., Jin, G., Wang, X., et al. (2026) An Interfacial Modification Strategy of Gold Nanoparticles to Enhance the Performance of Kesterite Solar Cells. Solar Energy, 303, Article ID: 114157. https://doi.org/10.1016/j.solener.2025.114157 |
| [5] | Liu, S.L., Fei, G.T., Xu, S.H., Gao, X.D. and Li, H. (2021) All-Optical-Input Transistors with Light-Controlled Enhancement and Fast Stabilization of Hot-Electron Photocurrent. The Journal of Physical Chemistry C, 125, 18887-18895. https://doi.org/10.1021/acs.jpcc.1c03364 |
| [6] | Wang, M., Ye, M., Iocozzia, J., Lin, C. and Lin, Z. (2016) Plasmon‐Mediated Solar Energy Conversion via Photocatalysis in Noble Metal/Semiconductor Composites. Advanced Science, 3, Article ID: 1600024. https://doi.org/10.1002/advs.201600024 |
| [7] | Butt, M.T.Z., Ameen, S., Ali, M.H., Tahir, A., ul Haq, T., Hussain, S.Z., et al. (2025) A Facile One-Step, Additive-Free Method for In-Situ Deposition of Gold Nanoparticles for High-Efficiency Dye-Sensitized Solar Cells. Journal of Power Sources, 656, Article ID: 238027. https://doi.org/10.1016/j.jpowsour.2025.238027 |
| [8] | Muduli, S., Game, O., Dhas, V., Vijayamohanan, K., Bogle, K.A., Valanoor, N., et al. (2012) TiO2-Au Plasmonic Nanocomposite for Enhanced Dye-Sensitized Solar Cell (DSSC) Performance. Solar Energy, 86, 1428-1434. https://doi.org/10.1016/j.solener.2012.02.002 |
| [9] | Naphade, R.A., Tathavadekar, M., Jog, J.P., Agarkar, S. and Ogale, S. (2014) Plasmonic Light Harvesting of Dye Sensitized Solar Cells by Au-Nanoparticle Loaded TiO2 Nanofibers. Journal of Materials Chemistry A, 2, 975-984. https://doi.org/10.1039/c3ta13246c |
| [10] | Kimling, J., Maier, M., Okenve, B., Kotaidis, V., Ballot, H. and Plech, A. (2006) Turkevich Method for Gold Nanoparticle Synthesis Revisited. The Journal of Physical Chemistry B, 110, 15700-15707. https://doi.org/10.1021/jp061667w |
| [11] | Liu, T., Bai, X., Miao, C., Dai, Q., Xu, W., Yu, Y., et al. (2014) Yb2O3/Au Upconversion Nanocomposites with Broad-Band Excitation for Solar Cells. The Journal of Physical Chemistry C, 118, 3258-3265. https://doi.org/10.1021/jp408501k |
| [12] | Zhang, S., Huang, Y., Xiong, Y., Ågren, H., Zhang, J. and Guo, X. (2024) Multifunctional Composite Photoanode Containing a TiO2 Microarchitecture with Near-Infrared Upconversion Nanoparticles for Dye-Sensitized Solar Cells. ACS Applied Nano Materials, 7, 6851-6860. https://doi.org/10.1021/acsanm.3c05595 |
| [13] | Chou, H., Huang, W., Wu, T., Yu, Y. and Hsu, H. (2017) LSPR Effects of Au Nanoparticles/ZnO Nano-Composite Films. Sensing and Bio-Sensing Research, 14, 17-20. https://doi.org/10.1016/j.sbsr.2017.04.003 |