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无催化剂光化学中电子给体–受体(EDA)络合物的作用机制与研究进展
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Abstract:
电子给体–受体(EDA)复合物介导的无催化剂光化学反应，凭借无需过渡金属与外加光催化剂、条件温和、绿色高效等优势，近年在合成方法学领域发展迅速，其中由EDA复合物介导的自由基反应备受关注，且在有机合成领域取得了一系列研究进展。本综述以下从核心机理、前沿反应类型、创新策略及应用拓展等方面阐述其研究进展。
The catalyst free photochemical reactions mediated by electron donor acceptor (EDA) complexes have developed rapidly in the field of synthetic methodology in recent years, thanks to their advantages of not requiring transition metals and external photocatalysts, mild conditions, and being green and efficient. Among them, the free radical reactions mediated by EDA complexes have attracted much attention and have made a series of research progress in the field of organic synthesis. This review elaborates on the latest developments in core mechanisms, cutting-edge reaction types, innovative strategies, and application expansion.
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