|
|
Material Sciences 2026
稀土元素含量对铸造高稀土镁合金组织与性能的影响
|
Abstract:
为探究稀土总含量对镁合金显微组织及室温拉伸力学性能的影响,本研究采用低压铸造工艺制备WE43、Mg-14Gd及Mg-20Gd三种不同稀土含量的镁合金,并对其进行热处理。通过光学显微镜(OM)、配备能谱仪(EDS)的扫描电子显微镜(SEM)及室温拉伸试验,系统分析合金在铸态与热处理后的显微组织特征及力学性能规律。结果表明:随着稀土含量增加,合金组织中第二相体积分数呈递增趋势;铸态下,Mg-14Gd合金综合力学性能最优,其屈服强度、抗拉强度及延伸率分别达165 MPa、220 MPa和2.8%;固溶处理后,Mg-20Gd合金表现出最高的屈服强度(183 MPa)与抗拉强度(265 MPa),而Mg-14Gd合金延伸率显著提升至15.3%,为三种合金中最高。本研究可为稀土镁合金的成分优化及工程化应用提供理论参考。
To investigate the influence of total rare earth content on the microstructure and room-temperature tensile mechanical properties of magnesium alloys, this study prepared three magnesium alloys with different rare earth contents, namely WE43, Mg-14Gd and Mg-20Gd, by low-pressure casting and subjected them to heat treatment. The microstructure characteristics and mechanical properties of the alloys in as-cast and heat-treated states were systematically analyzed by optical microscopy (OM), scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS), and room-temperature tensile tests. The results show that with the increase of rare earth content, the volume fraction of the second phase in the alloys increases. In the as-cast state, the Mg-14Gd alloy shows the best comprehensive mechanical properties, with yield strength of 165 MPa, ultimate tensile strength of 220 MPa and elongation of 2.8%. After solution treatment, the Mg-20Gd alloy exhibits the highest yield strength (183 MPa) and ultimate tensile strength (265 MPa), while the elongation of the Mg-14Gd alloy significantly increases to 15.3%, which is the highest among the three alloys. This study can provide theoretical references for the composition optimization and engineering application of rare earth magnesium alloys.
| [1] | 左铁镛. 21世纪的轻质结构材料——镁及镁合金发展[J]. 新材料产业, 2007(12): 22-26. |
| [2] | Li, R., Wang, L., Yang, B., Xu, B., Liang, D., Wang, F., et al. (2023) Magnesium Alloy Scrap Vacuum Gasification—Directional Condensation to Purify Magnesium. Metals, 13, Article 675. https://doi.org/10.3390/met13040675 |
| [3] | Pan, F., Yang, M. and Chen, X. (2016) A Review on Casting Magnesium Alloys: Modification of Commercial Alloys and Development of New Alloys. Journal of Materials Science & Technology, 32, 1211-1221. https://doi.org/10.1016/j.jmst.2016.07.001 |
| [4] | 赵天豪, 康晶杰, 王若兰, 等. 铸造高强Mg-Gd系合金研究进展[J]. 铸造设备与工艺, 2023(5): 66-72. |
| [5] | Kong, F., Xie, W., Wei, G., Ma, Z., Chen, H. and Fan, C. (2023) Microstructure Evaluation and Thermal Deformation Behaviours of Wrought Magnesium Alloys. Materials Science and Technology, 39, 283-299. https://doi.org/10.1080/02670836.2022.2110374 |
| [6] | 潘复生. 铸造镁合金及制备技术新进展[C]//2018中国铸造活动周. 2018中国铸造活动周论文集. 苏州: 中国机械工程学会, 铸造行业生产力促进中心, 2018: 14. |
| [7] | 谢飞, 胡静, 林栋梁, 等. 稀土Y含量对铸造镁合金组织和性能的影响[J]. 材料热处理学报, 2008(3): 90-93. |
| [8] | 孙庆冀, 高景龙, 郑兆博, 等. 高应变率下Mg-9Gd-4Y-0.5Zr镁合金的力学行为研究[J]. 沈阳理工大学学报, 2022, 41(3): 41-45. |
| [9] | Jafari Nodooshan, H.R., Wu, G., Liu, W., Wei, G., Li, Y. and Zhang, S. (2016) Effect of Gd Content on High Temperature Mechanical Properties of Mg-Gd-Y-Zr Alloy. Materials Science and Engineering: A, 651, 840-847. https://doi.org/10.1016/j.msea.2015.11.047 |
| [10] | He, S.M., Zeng, X.Q., Peng, L.M., Gao, X., Nie, J.F. and Ding, W.J. (2006) Precipitation in a Mg-10Gd-3Y-0.4Zr (wt.%) Alloy during Isothermal Ageing at 250˚C. Journal of Alloys and Compounds, 421, 309-313. https://doi.org/10.1016/j.jallcom.2005.11.046 |
| [11] | Bu, D., Li, T., Han, X., Du, Z., Yuan, J., Zhang, K., et al. (2023) Enhancing Strength and Ductility in Back Extruded WE71 Magnesium Alloy Cylindrical Parts by Introduction of Multi-Direction Forging Process. Journal of Rare Earths, 41, 462-470. https://doi.org/10.1016/j.jre.2022.03.001 |
| [12] | Li, C., Wei, J., Jin, J., Yan, H., Shan, Z., Mao, Y., et al. (2024) The Effect of Precipitates on the Fracture Behavior and Tensile Properties of Mg-14Gd-0.5Zr (wt.%) Alloy. Journal of Materials Science & Technology, 180, 226-242. https://doi.org/10.1016/j.jmst.2023.08.062 |
| [13] | Shigeki, S., Shu, I., Kyouei, D., et al. (1992) The Time-Hardening Characteristics and High-Temperature Strength of Mg-Gd and Mg-Tb Alloy Systems. Light Metals, 42, 727-733. |
| [14] | 田晓莹, 魏健雄, 闫宏, 等. 热等静压对低压铸造WE43镁合金组织和室温及高温力学性能的影响[J]. 材料热处理学报, 2023, 44(10): 87-95. |