全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Synthesis and Production Technology of Horse Dea Surfactant by Amidation of Horse Fatty Acids with Diethanolamine

DOI: 10.4236/msce.2026.141006, PP. 90-105

Keywords: Amide, Amine, Long Chain Fatty Acids, HLB Number, Foam Stability, Surfactant Model, Coconut DEA

Full-Text   Cite this paper   Add to My Lib

Abstract:

One of the most significant classes of nonionic surfactants containing nitrogen is ethanolamides of horse fatty acids. The conditions for the formation of nanoscale and submicron emulsions and the factors influencing the phase inversion temperature (SIT) and phase inversion composition (SIS) are examined. These products are widely used as components of detergents, foaming agents, and stabilizers in cosmetic preparations, wetting agents and antistatic agents, dispersants, corrosion inhibitors, etc. Finding amides with nonionic foaming qualities in the presence of diethanolamines containing fatty acids extracted from horse fat is the aim of the study. In accordance with the reaction mechanism, amidation was performed using 400 grams of horse fatty acid (1.5 mol), 157.6 grams of diethanolamine (1.5 mol), and 3% of the Al2O3 catalyst (i.e., 12 grams) in relation to the total mass of fatty acid. The study’s Horse DEA surfactant’s HLB values were contrasted with those of other DEAs. As a local alternative to the popular Coconut DEA product for shampoo products, the Horse DEA developed in this scientific work has good solubility in oily environments with a DEA value of less than 10.

References

[1]  Rakhmanov, S.Y., Khamidovа, M.O., Rakhimov, D.P., Sukor, R. and Kenjaev, N.T. (2025) Separation of Fatty Acids from Horse Fat and Their Analysis. Chemistry and Chemical Engineering, 2025, Article 6.
[2]  Adewuyi, A., Oderinde, R.A., Rao, B.V.S.K. and Prasad, R.B.N. (2011) Synthesis of Alkanolamide: A Nonionic Surfactant from the Oil of Gliricidia sepium. Journal of Surfactants and Detergents, 15, 89-96.
https://doi.org/10.1007/s11743-011-1285-0
[3]  Ahmad, M.U. (2017) Zhirnyye kislaty: khimiya, sintez i primeneniye [Fatty Acids: Chemistry, Synthesis, and Applications]. AOCS Press, 617 p.
[4]  Ruzibayev, A.T., Salijonova, S.D., Rakhimov, D.P., Akbarov, M.M., Gaipova, S.S., Khakimova, Z.A., et al. (2025) Developing a Healthier Chocolate Spread: Using Persimmons to Reduce Sugar Content. BIO Web of Conferences, 173, Article ID: 04008.
https://doi.org/10.1051/bioconf/202517304008
[5]  Bondarenko, V., Dzhusenov, A. and Nursultan, A. (2015) Issledovaniye svoystv zhidkostey glusheniya skvazhin [Research of Properties of Well-Killing Fluids]. Journal of the Industrial Technology and Engineering, 15, 49-55.
[6]  Boshui, C., Nan, Z., Jiang, W., Jiu, W., Jianhua, F. and Kai, L. (2013) Enhanced Biodegradability and Lubricity of Mineral Lubricating Oil by Fatty Acidic Diethanolamide Borates. Green Chemistry, 15, 738-743.
https://doi.org/10.1039/c3gc36774f
[7]  Butler, R.N., O’Regan, C.B. and Moynihan, P. (1978) Reactions of Fatty Acids with Amines. Part 2. Sequential Thermal Reactions of Stearic (Octadecanoic) Acid with Some 1, 2-and 1, 3-Aminoalcohols and Bis-Amines. Journal of the Chemical Society, Perkin Transactions 1, No. 4, 373-377.
https://doi.org/10.1039/p19780000373
[8]  Dardir, M.M., Ibrahime, S., Soliman, M., Desouky, S.D. and Hafiz, A.A. (2014) Preparation and Evaluation of Some Esteramides as Synthetic Based Drilling Fluids. Egyptian Journal of Petroleum, 23, 35-43.
https://doi.org/10.1016/j.ejpe.2014.02.006
[9]  Rakhimov, D., Fayzullayeva, N., Shomaksudova, K., Kenjayev, N., Hakimova, Z., Rakhmanov, S., et al. (2024) A Bibliometric Review of Vegetable Oils and Modified Fats Studied in Scientific Bases around the World. BIO Web of Conferences, 93, Article ID: 02005.
https://doi.org/10.1051/bioconf/20249302005
[10]  Folmer, B.M., Holmberg, K., Klingskog, E.G. and Bergström, K. (2001) Fatty Amide Ethoxylates: Synthesis and Self-Assembly. Journal of Surfactants and Detergents, 4, 175-183.
https://doi.org/10.1007/s11743-001-0172-6
[11]  Kamalakar, K., Satyavani, T., Mohini, Y., Prasad, R.B.N. and Karuna, M.S.L. (2013) Synthesis of Thumba, Castor and Sal Fatty Ethanolamide-Based Anionic Surfactants. Journal of Surfactants and Detergents, 17, 637-645.
https://doi.org/10.1007/s11743-013-1500-2
[12]  Kumar, D., Kim, S.M. and Ali, A. (2016) Solvent-free One Step Aminolysis and Alcoholysis of Low-Quality Triglycerides Using Sodium Modified Cao Nanoparticles as a Solid Catalyst. RSC Advances, 6, 55800-55808.
https://doi.org/10.1039/c6ra13446g
[13]  Mardashov, D.V. and Rogachev, M.K. (2014) Well Killing and Stimulation at Oil Well Servicing with Hydrophobic Emulsion Compositions. Journal of Life Sciences, 11, 286-288.
https://www.elibrary.ru/item.asp?id=24957626
[14]  Piispanen, P.S., Hedman, B. and Norin, T. (2002) Synthesis and Characterization of Dehydroabietic Acid Derivatives Suitable for Surfactant Synthesis. Journal of Surfactants and Detergents, 5, 165-168.
https://doi.org/10.1007/s11743-002-0217-x
[15]  Sagnella, S.M., Conn, C.E., Krodkiewska, I. and Drummond, C.J. (2011) Nonionic Diethanolamide Amphiphiles with Unsaturated C18 Hydrocarbon Chains: Thermotropic and Lyotropic Liquid Crystalline Phase Behavior. Physical Chemistry Chemical Physics, 13, 13370-13381.
https://doi.org/10.1039/c1cp21808e
[16]  Fayzullaev, A., Ruzibaev, A., Ilkhamdjanov, P., Saidvaliev, S., Gaipova, S., Salijonova, S., Octavio, C.G., Usmanova, F.Z. and Rakhimov, D. (2025) Bibliometric Analysis of Articles on Scopus Database on Pumpkin Seed, Published on the Period 1990-2024. The Annual International Conference on Food Science & Nutrition, Oxford, 21-22 August 2025, 17.
[17]  Wang, X., Han, Z., Chen, Y., Jin, Q. and Wang, X. (2015) Scalable Synthesis of Oleoyl Ethanolamide by Chemical Amidation in a Mixed Solvent. Journal of the American Oil Chemists’ Society, 93, 125-131.
https://doi.org/10.1007/s11746-015-2749-6
[18]  Feng, R., Pu, D., Zhou, Y., Chen, J., Kou, J., Jiang, X. and Guo, Y. (2015) Effect of Compositions of the Mixed Alkanolamide on Oil/Water Dynamic Interfacial Tensions. Chemical Industry and Engineering Progress, 34, 2955.
[19]  Yanovsky, V.A., Andropov, M.O., Fakhrislamova, R.S., Churkin, R.A., Minaev, K.M. and Yanovskaya, E.A. (2018) The Effect of Duration of Amidation of Fatty Acids with Diethanolamine on the Surfactant Properties. Journal of Surfactants and Detergents, 22, 641-654.
https://doi.org/10.1002/jsde.12235
[20]  Kroll, H. and Nadeau, H. (1957) The Chemistry of Lauric Acid-Diethanolamine Condensation Products. Journal of the American Oil Chemists’ Society, 34, 323-326.
https://doi.org/10.1007/bf02638836

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133