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纤维素气凝胶的研究进展及应用
Research Progress and Applications of Cellulose Aerogels

DOI: 10.12677/aac.2025.152017, PP. 172-178

Keywords: 纤维素,气凝胶,干燥,应用
Cellulose
, Aerogel, Drying, Applications

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Abstract:

气凝胶凭借其独特的三维网络结构,作为目前已知世界上密度最低且微观尺度极小的固体材料,在材料科学及相关领域引发了广泛关注。纤维素气凝胶无疑是与可持续发展理念相契合的新型材料,它不仅具备高孔隙率和大比表面积等优异特性,还具有可被微生物降解以及与多种物质良好兼容等优势。文章介绍了制作纤体素凝胶的方法,常压干燥,冷冻干燥,超临界干燥等特征论述。在应用上,对纤素气凝胶所展现的广阔前景进行了探索,并展望了它的发展前景。
Aerogels, with their unique three-dimensional network structure, have attracted widespread attention in materials science and related fields as the lowest density solid materials known in the world with extremely small microscopic scales. Cellulose aerogels are undoubtedly a new type of material that aligns with the concept of sustainable development; they not only possess excellent characteristics such as high porosity and large specific surface area but also have advantages such as biodegradability and good compatibility with various substances. This article introduces methods for producing cellulose aerogels, discussing features such as ambient pressure drying, freeze-drying, and supercritical drying. In terms of applications, it explores the broad prospects demonstrated by cellulose aerogels and anticipates their future development.to the Hans standard, which illustrates all the formats.

References

[1]  Kistler, S.S. (1931) Coherent Expanded Aerogels and Jellies. Nature, 127, 741.
https://doi.org/10.1038/127741a0
[2]  Cheng, H., Gu, B., Pennefather, M.P., Nguyen, T.X., Phan-Thien, N. and Duong, H.M. (2017) Cotton Aerogels and Cotton-Cellulose Aerogels from Environmental Waste for Oil Spillage Cleanup. Materials & Design, 130, 452-458.
https://doi.org/10.1016/j.matdes.2017.05.082
[3]  马书荣, 米勤勇, 余坚, 等. 基于纤维素的气凝胶材料[J]. 化学进展, 2014, 26(5): 796-809.
[4]  Qi, H., Liu, J., Gao, S. and Mäder, E. (2013) Multifunctional Films Composed of Carbon Nanotubes and Cellulose Regenerated from Alkaline-Urea Solution. J. Mater. Chem. A, 1, 2161-2168.
https://doi.org/10.1039/c2ta00882c
[5]  Zaborowska, M., Bodin, A., Bäckdahl, H., Popp, J., Goldstein, A. and Gatenholm, P. (2010) Microporous Bacterial Cellulose as a Potential Scaffold for Bone Regeneration. Acta Biomaterialia, 6, 2540-2547.
https://doi.org/10.1016/j.actbio.2010.01.004
[6]  Zhao, J., Lu, C., He, X., Zhang, X., Zhang, W. and Zhang, X. (2015) Polyethylenimine-Grafted Cellulose Nanofibril Aerogels as Versatile Vehicles for Drug Delivery. ACS Applied Materials & Interfaces, 7, 2607-2615.
https://doi.org/10.1021/am507601m
[7]  Heath, L. and Thielemans, W. (2010) Cellulose Nanowhisker Aerogels. Green Chemistry, 12, 1448-1453.
https://doi.org/10.1039/c0gc00035c
[8]  付哲, 苑兴洲, 韩乔, 等. 纤维素气凝胶的制备及其应用进展[J]. 石油化工高等学校学报, 2024, 37(1): 52-58.
[9]  刘昌宇, 孙永祥, 张成俊, 等. 二氧化硅气凝胶制备条件对热导率的影响[J]. 热科学与技术, 2022, 21(3): 221-226.
[10]  王美娟, 慕道炎, 侯海波, 等. 二氧化硅气凝胶的制备及应用研究进展[J]. 四川化工, 2024, 27(6): 5-9.
[11]  Bisson, A., Rigacci, A., Lecomte, D., Rodier, E. and Achard, P. (2003) Drying of Silica Gels to Obtain Aerogels: Phenomenology and Basic Techniques. Drying Technology, 21, 593-628.
https://doi.org/10.1081/drt-120019055
[12]  Aravind, P.R., Shajesh, P., Soraru, G.D. and Warrier, K.G.K. (2010) Ambient Pressure Drying: A Successful Approach for the Preparation of Silica and Silica Based Mixed Oxide Aerogels. Journal of Sol-Gel Science and Technology, 54, 105-117.
https://doi.org/10.1007/s10971-010-2164-2
[13]  Zhao, X., Chen, L., Su, P., Xiao, L., Zhao, H., Fu, T., et al. (2024) 4-Hydroxybenzenesulfonic Acid Triggers Rapid Preparation of Phenolic Aerogel Composites by Ambient Pressure Drying. Chemical Engineering Journal, 479, Article 147856.
https://doi.org/10.1016/j.cej.2023.147856
[14]  Shao, G., Hanaor, D.A.H., Wang, J., Kober, D., Li, S., Wang, X., et al. (2020) Polymer-Derived SiOC Integrated with a Graphene Aerogel as a Highly Stable Li-Ion Battery Anode. ACS Applied Materials & Interfaces, 12, 46045-46056.
https://doi.org/10.1021/acsami.0c12376
[15]  Barachini, S., Trombi, L., Danti, S., D’Alessandro, D., Battolla, B., Legitimo, A., et al. (2009) Morpho-Functional Characterization of Human Mesenchymal Stem Cells from Umbilical Cord Blood for Potential Uses in Regenerative Medicine. Stem Cells and Development, 18, 293-306.
https://doi.org/10.1089/scd.2008.0017
[16]  Zhang, X., Zhao, X., Xue, T., Yang, F., Fan, W. and Liu, T. (2020) Bidirectional Anisotropic Polyimide/Bacterial Cellulose Aerogels by Freeze-Drying for Super-Thermal Insulation. Chemical Engineering Journal, 385, Article 123963.
https://doi.org/10.1016/j.cej.2019.123963
[17]  Wan, J., Zhang, J., Yu, J. and Zhang, J. (2017) Cellulose Aerogel Membranes with a Tunable Nanoporous Network as a Matrix of Gel Polymer Electrolytes for Safer Lithium-Ion Batteries. ACS Applied Materials & Interfaces, 9, 24591-24599.
https://doi.org/10.1021/acsami.7b06271
[18]  Li, Y., Jiang, H., Han, B. and Zhang, Y. (2019) Drying of Cellulose Nanocrystal Gel Beads Using Supercritical Carbon Dioxide. Journal of Chemical Technology & Biotechnology, 94, 1651-1659.
https://doi.org/10.1002/jctb.5936
[19]  Matsuyama, K., Morotomi, K., Inoue, S., Nakashima, M., Nakashima, H., Okuyama, T., et al. (2019) Antibacterial and Antifungal Properties of Ag Nanoparticle-Loaded Cellulose Nanofiber Aerogels Prepared by Supercritical CO2 Drying. The Journal of Supercritical Fluids, 143, 1-7.
https://doi.org/10.1016/j.supflu.2018.08.008
[20]  Laitinen, O. and Liimatainen, H. (2024) Gelatin-Reinforced Cellulose Nanofiber Composite Cryogels for Effective Separation of Small Particulate Matter in Air. Materials & Design, 238, Article 112654.
https://doi.org/10.1016/j.matdes.2024.112654
[21]  Xu, M., Bao, W., Xu, S., Wang, X. and Sun, R. (2015) Porous Cellulose Aerogels with High Mechanical Performance and Their Absorption Behaviors. BioResources, 11, 8-20.
https://doi.org/10.15376/biores.11.1.8-20
[22]  Yifan, S., and Jing, S. (2022) Preparation and Adsorption Abilities of Biomass Carbon Aerogel Derived from Sweet Potato. Journal of Liaoning University of Petroleum & Chemical Technology, 42, 8-14.
https://doi.org/10.3969/j.issn.1672-6952.2022.02.002
[23]  Zhu, J., Wang, X., He, L. and Huang, X. (2023) Preparation and Oil Absorption Performance Evaluation of Superhydrophobic Biomass Composite Aerogels. Oilfield Chemistry, 40, 143-148.
https://doi.org/10.19346/j.cnki.1000-4092.2023.01.023
[24]  Mulyadi, A., Zhang, Z. and Deng, Y. (2016) Fluorine-Free Oil Absorbents Made from Cellulose Nanofibril Aerogels. ACS Applied Materials & Interfaces, 8, 2732-2740.
https://doi.org/10.1021/acsami.5b10985
[25]  Wang, X., Meng, R., Zhao, S., Jing, Z., Jin, Y., Zhang, J., et al. (2024) Efficient Adsorption of Radioactive Iodine by Covalent Organic Framework/chitosan Aerogel. International Journal of Biological Macromolecules, 260, Article 129690.
https://doi.org/10.1016/j.ijbiomac.2024.129690
[26]  Cao, J., Zhao, Y., Xu, Y., Zhang, Y., Zhang, B. and Peng, H. (2018) Sticky-Note Supercapacitors. Journal of Materials Chemistry A, 6, 3355-3360.
https://doi.org/10.1039/c7ta10756k
[27]  Huang, Y., Zeng, Y., Yu, M., Liu, P., Tong, Y., Cheng, F., et al. (2017) Recent Smart Methods for Achieving High‐energy Asymmetric Supercapacitors. Small Methods, 2, Article ID: 1700230.
https://doi.org/10.1002/smtd.201700230
[28]  Gao, K., Shao, Z., Wang, X., Zhang, Y., Wang, W. and Wang, F. (2013) Cellulose Nanofibers/Multi-Walled Carbon Nanotube Nanohybrid Aerogel for All-Solid-State Flexible Supercapacitors. RSC Advances, 3, 15058-15064.
https://doi.org/10.1039/c3ra42050g
[29]  Benito-González, I., López-Rubio, A., Gómez-Mascaraque, L.G. and Martínez-Sanz, M. (2020) PLA Coating Improves the Performance of Renewable Adsorbent Pads Based on Cellulosic Aerogels from Aquatic Waste Biomass. Chemical Engineering Journal, 390, Article 124607.
https://doi.org/10.1016/j.cej.2020.124607
[30]  Ye, S., He, S., Su, C., Jiang, L., Wen, Y., Zhu, Z., et al. (2018) Morphological, Release and Antibacterial Performances of Amoxicillin-Loaded Cellulose Aerogels. Molecules, 23, Article 2082.
https://doi.org/10.3390/molecules23082082

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