|
|
Material Sciences 2025
镁铝水滑石的制备及其应用研究进展
|
Abstract:
水滑石类化合物的研究已经历了多年的发展，其结构和性能得到了深入的研究和了解，其中镁铝水滑石作为一种具有层状结构的材料，其独特的结构和阴离子的可交换性，以及碱性、热稳定性等性能，使其成为在催化、水资源净化、大气治理等方面有巨大潜力的新材料。镁铝水滑石可以通过共沉淀法、水热合成法、溶胶–凝胶法、离子交换法、尿素水解法、焙烧还原法等多种方法合成，着重介绍了共沉淀法和水热合成法并分析它们各自的优点，同时重点综述了其在催化方面的应用。镁铝水滑石作为一种多功能材料，在多个领域都有广泛应用，并且随着研究和市场的发展，其应用前景和市场潜力仍然在不断扩大。
The research of hydrotalcite compounds has experienced many years of development, and its structure and properties have been deeply studied and understood, among which magnesium aluminum hydrotalcite as a material with a layered structure, its unique structure and anionic exchangability, as well as alkaline, thermal stability and other properties, make it become a new material with great potential in catalysis, water purification, atmospheric governance and other aspects. Magnesium aluminum hydrotalcite can be synthesized by coprecipitation, hydrothermal synthesis, sol-gel method, ion exchange method, urea hydrolysis method, roasting reduction method, etc. The advantages of coprecipitation method and hydrothermal synthesis method are introduced, and their applications in catalysis are reviewed. As a multifunctional material, magnesium aluminum hydrotalcite has been widely used in many fields, and with the development of research and market, its application prospect and market potential are still expanding.
| [1] | 路绍琰, 田欣霞, 骆碧君, 等. 水滑石的改性研究概况及发展趋势[J]. 盐科学与化工, 2023, 52(7): 13-17. |
| [2] | 宋国君, 孙良栋, 李培耀, 等. 水滑石的合成、改性及其在功能复合材料中的应用[J]. 材料导报, 2008, 22(1): 53-57. |
| [3] | Hameed, A., Batool, M., Liu, Z., Nadeem, M.A. and Jin, R. (2022) Layered Double Hydroxide-Derived Nanomaterials for Efficient Electrocatalytic Water Splitting: Recent Progress and Future Perspective. ACS Energy Letters, 7, 3311-3328. https://doi.org/10.1021/acsenergylett.2c01362 |
| [4] | Wu, Y., Liu, X., Lei, Y., Qiu, Y., Wang, M. and Wang, H. (2017) Synthesis and Characterization of 12-Tungstophosphoric Acid Intercalated Layered Double Hydroxides and Their Application as Esterification Catalysts for Deacidification of Crude Oil. Applied Clay Science, 150, 34-41. https://doi.org/10.1016/j.clay.2017.09.007 |
| [5] | Smoláková, L., Frolich, K., Kocík, J., Kikhtyanin, O. and Čapek, L. (2017) Surface Properties of Hydrotalcite-Based Zn(Mg)Al Oxides and Their Catalytic Activity in Aldol Condensation of Furfural with Acetone. Industrial & Engineering Chemistry Research, 56, 4638-4648. https://doi.org/10.1021/acs.iecr.6b04927 |
| [6] | 黄洁莹, 乔建江. 硼砂改性镁铝水滑石的制备及阻燃应用[J]. 塑料工业, 2022, 50(12): 133-139. |
| [7] | 张客厅. 插层水滑石的合成及其在催化转化领域的应用[D]: [硕士学位论文]. 郑州: 郑州大学, 2017. |
| [8] | 杨杨. 镍铁水滑石/碳复合材料的制备及其电催化性能研究[D]: [硕士学位论文]. 长春: 吉林大学, 2023. |
| [9] | Yang, Z., Ren, X., Zhang, H., Su, D. and Rong, Z. (2024) CuMgAl Catalyzed Dimethyl 1, 4-Cyclohexane Dicarboxylate to 1, 4-Cyclohexane Dimethanol under Relatively Mild Conditions. Catalysis Letters, 154, 4502-4510. https://doi.org/10.1007/s10562-024-04632-y |
| [10] | 朱清, 李成胜, 周建成. 镁铝水滑石的共沉淀法制备及表征[J]. 化工时刊, 2017, 31(4): 1-3, 17. |
| [11] | 张明浩, 胡盛, 胡卫兵. 反应条件对镁铝水滑石制备和吸附性能的影响[J]. 非金属矿, 2019, 42(5): 87-90. |
| [12] | 李志新. 铝镁锆类水滑石催化合成异佛尔酮[D]: [硕士学位论文]. 齐齐哈尔: 齐齐哈尔大学, 2013. |
| [13] | Zhang, J., Hou, A., Li, J., Lian, D., Zhang, M. and Wang, Z. (2022) Enhanced Corrosion and Wear Resistance of LA43M Magnesium-Lithium Alloy with Magnesium-Aluminum Layered Double Hydroxide Coating. Journal of Materials Engineering and Performance, 32, 3550-3562. https://doi.org/10.1007/s11665-022-07361-8 |
| [14] | 谢晖, 矫庆泽, 段雪. 镁铝型水滑石水热合成[J]. 应用化学, 2001, 18(1): 70-72. |
| [15] | 袁东, 周良芹. 锌镁铝类水滑石的制备与表征研究[J]. 硅酸盐通报, 2016, 35(3): 748-752, 757. |
| [16] | Paredes, S.P., Fetter, G., Bosch, P. and Bulbulian, S. (2006) Sol-Gel Synthesis of Hydrotalcite—Like Compounds. Journal of Materials Science, 41, 3377-3382. https://doi.org/10.1007/s10853-005-5347-4 |
| [17] | Mora, M., López, M.I., Jiménez-Sanchidrián, C. and Ruiz, J.R. (2010) MIR and NIR Spectroscopy of Sol-Gel Hydrotalcites with Various Trivalent Cations. Journal of Sol-Gel Science and Technology, 55, 59-65. https://doi.org/10.1007/s10971-010-2213-x |
| [18] | Amiri, S. and Rahimi, A. (2016) Hybrid Nanocomposite Coating by Sol-Gel Method: A Review. Iranian Polymer Journal, 25, 559-577. https://doi.org/10.1007/s13726-016-0440-x |
| [19] | 汪港, 范展华, 邹煦, 等. 尿素水热生长法合成不同形貌镁铝水滑石及其对活性红染料的吸附性能[J]. 天津师范大学学报(自然科学版), 2021, 41(3): 17-23. |
| [20] | 祝春蕾, 王海林, 孙春宝. 脱硫类水滑石衍生复合氧化物不同方法的制备与表征[J]. 环境科学, 2014, 35(5): 2010-2017. |
| [21] | 李美娜. 原位镁铝水滑石的制备及其催化废水中尿素水解的研究[D]: [硕士学位论文]. 太原: 太原理工大学, 2016. |
| [22] | 张琳. 镁铝水滑石的制备及其焙烧产物在水泥净浆中固化氯离子性能研究[D]: [硕士学位论文]. 衡阳: 南华大学, 2019. |
| [23] | Yang, Z., Fischer, H., Cerezo, J., Mol, J.M.C. and Polder, R. (2015) Modified Hydrotalcites for Improved Corrosion Protection of Reinforcing Steel in Concrete—Preparation, Characterization, and Assessment in Alkaline Chloride Solution. Materials and Corrosion, 67, 721-738. https://doi.org/10.1002/maco.201508618 |
| [24] | 杜小旺. 水镁石基镁铝水滑石合成研究[D]: [硕士学位论文]. 大连: 大连理工大学, 2020. |
| [25] | 刘齐鲁. 水滑石的制备和应用综述[J]. 中国非金属矿工业导刊, 2017(2): 9-11. |
| [26] | Cai, Z., Bu, X., Wang, P., Ho, J.C., Yang, J. and Wang, X. (2019) Recent Advances in Layered Double Hydroxide Electrocatalysts for the Oxygen Evolution Reaction. Journal of Materials Chemistry A, 7, 5069-5089. https://doi.org/10.1039/c8ta11273h |
| [27] | 扈彬, 刘温霞, 张洁. 催化技术及前景分析[J]．华东纸业, 2014, 45(3): 42-45. |
| [28] | Sun, J., Fan, H., Nan, B. and Ai, S. (2014) Fe3O4@LDH@Ag/Ag3PO4 Submicrosphere as a Magnetically Separable Visible-Light Photocatalyst. Separation and Purification Technology, 130, 84-90. https://doi.org/10.1016/j.seppur.2014.04.007 |
| [29] | He, W., Wang, R., Zhang, L., Zhu, J., Xiang, X. and Li, F. (2015) Enhanced Photoelectrochemical Water Oxidation on a BiVo4 Photoanode Modified with Multi-Functional Layered Double Hydroxide Nanowalls. Journal of Materials Chemistry A, 3, 17977-17982. https://doi.org/10.1039/c5ta04105h |
| [30] | 李旭. 水滑石类层状化合物的制备、微分析及应用研究[D]: [硕士学位论文]. 保定: 河北大学, 2015. |
| [31] | 刘永红, 王全红, 王宁, 等. TiO2/ACF光催化反应器在多种染料废水中的脱色应用[J]. 西安工程大学学报, 2021, 35(5): 1-6. |
| [32] | Han, N., Ding, P., He, L., Li, Y. and Li, Y. (2019) Promises of Main Group Metal-Based Nanostructured Materials for Electrochemical CO2 Reduction to Formate. Advanced Energy Materials, 10, Article ID: 1902338. https://doi.org/10.1002/aenm.201902338 |
| [33] | 徐书群, 叶利民. 醛/酮羟醛缩合反应效率提升方法探讨[J]. 山东化工, 2021, 50(4): 169-170. |
| [34] | 邱俊, 周晶. 新型改性分子筛FSM-16催化对硝基苯甲醛与丙酮的Aldol缩合反应[J]. 化学试剂, 2016, 38(7): 621-624. |
| [35] | 何沁阳, 张越, 赵铭鑫, 等. 重构水滑石催化丙酮与苯甲醛的羟醛反应[J]. 实验技术与管理, 2018, 35(4): 73-78. |
| [36] | 吴丽丽, 安华良, 梁宁, 等. 羟醛缩合反应中酸碱双功能催化剂的研究进展[J]. 化学通报, 2014, 77(2): 109-114. |
| [37] | Kikhtyanin, O., Tišler, Z., Velvarská, R. and Kubička, D. (2017) Reconstructed Mg-Al Hydrotalcites Prepared by Using Different Rehydration and Drying Time: Physico-Chemical Properties and Catalytic Performance in Aldol Condensation. Applied Catalysis A: General, 536, 85-96. https://doi.org/10.1016/j.apcata.2017.02.020 |
| [38] | 纪月红. 水污染分析及水环境保护措施探究[J]. 皮革制作与环保科技, 2024, 5(3): 36-38. |
| [39] | 吴国强. 改性水滑石的制备及其对盐酸四环素的吸附研究[D]: [硕士学位论文]. 合肥: 安徽建筑大学, 2024. |
| [40] | 邓林. 镁铝水滑石基复合材料吸附去除水中铬(Ⅵ)、磷酸盐的研究[D]: [博士学位论文]. 长沙: 湖南大学, 2017. |
| [41] | 张启彦. TiO2-GO/LDHs复合材料光催化降解VOCs的研究[D]: [硕士学位论文]. 济南: 山东大学, 2020. |
| [42] | 张骄佼, 田森林, 周键. 镁铝水滑石的合成与应用研究进展[J]. 材料导报, 2013, 27(7): 144-148. |
| [43] | Xu, X., Jiang, L., Lü, Z., Song, J. and Li, Z. (2012) Influence of the Pore Structure of Ce/MgAl Hydrotalcite-Derived Mixed Oxides on Its SO X Pick-Up Capacity. Chinese Science Bulletin, 58, 1670-1674. https://doi.org/10.1007/s11434-012-5552-x |
