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Mine Engineering 2025
表面活性剂在矿物浸出中的强化作用:原理、应用与展望
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Abstract:
随着矿产资源的日益枯竭,如何提高矿物的浸出效率成为矿业领域中的关键问题。表面活性剂作为一种具有特殊分子结构的物质,通过降低溶液表面张力、改善矿石的润湿性、促进固液界面反应等多种方式,有效地增强矿物浸出效果。本文综述了表面活性剂在矿物浸出中的作用机制,包括其对矿石表面润湿性的改善、化学反应的促进、以及离子扩散与传质的影响。此外,本文还探讨了表面活性剂在不同矿物(如铜矿、磷钾伴生矿、低品位锰矿等)中的应用实例,展示了不同类型表面活性剂对矿物浸出效率的提升作用。最后,讨论了表面活性剂强化矿物浸出的影响因素,如表面活性剂种类、矿石性质及浸出条件等,为矿业高效、绿色、可持续发展提供了理论支持和技术参考。
As mineral resources continue to deplete, enhancing the leaching efficiency of minerals has become a critical issue in the mining industry. Surfactants, with their unique molecular structures, effectively enhance mineral leaching through various mechanisms, including reducing solution surface tension, improving ore wettability, and facilitating solid-liquid interface reactions. This review explores the mechanisms by which surfactants influence mineral leaching, such as enhancing ore surface wettability, promoting chemical reactions, and influencing ion diffusion and mass transfer. Furthermore, the paper discusses the application of surfactants in the leaching of different minerals, such as copper ores, phosphorite-potash associated ores, and low-grade manganese ores, highlighting the role of various surfactant types in improving leaching efficiency. Finally, the review examines factors affecting surfactant-enhanced mineral leaching, including surfactant type, ore properties, and leaching conditions, providing theoretical insights and technical references for the efficient, green, and sustainable development of the mining industry.
[1] | 周有勤. 金的地质冶金学及其应用[J]. 黄金科学技术, 2013(5): 76-80. |
[2] | 田庆华, 王浩, 辛云涛, 郭学益. 难处理金矿预处理方法研究现状[J]. 有色金属科学与工程, 2017, 8(2): 83-89. |
[3] | 宛鹤, 何廷树, 谢建宏, 刘思伟. 磁化处理技术在矿物加工中的应用[J]. 黄金, 2011, 32(1): 53-55. |
[4] | 刘佳奇, 霍冀川, 雷永林, 等. 发泡剂及泡沫混凝土的研究进展[J]. 化学工业与工程, 2010, 27(1): 73-78. |
[5] | Kralova, I. and Sjöblom, J. (2009) Surfactants Used in Food Industry: A Review. Journal of Dispersion Science and Technology, 30, 1363-1383. https://doi.org/10.1080/01932690902735561 |
[6] | Mohr, A., Pozo Vila, T., Korth, H., Rehage, H. and Sustmann, R. (2008) Hydrophobic n‐Diazeniumdiolates and the Aqueous Interface of Sodium Dodecyl Sulfate (SDS) Micelles. ChemPhysChem, 9, 2397-2405. https://doi.org/10.1002/cphc.200800399 |
[7] | Gonçalves, R.A., Holmberg, K. and Lindman, B. (2023) Cationic Surfactants: A Review. Journal of Molecular Liquids, 375, Article ID: 121335. https://doi.org/10.1016/j.molliq.2023.121335 |
[8] | 纪卿, 云喜玲. 表面活性剂的分类、性能及其应用原理[J]. 集宁师专学报, 2003, 25(4): 58-59. |
[9] | de Guertechin, L.O. (2001) Classification of Surfactants. In: Knowlton, J. and Pearce, S., Eds., Handbook of Cosmetic Science and Technology, Elsevier Science, 14-22. |
[10] | 赵前飞, 杨洪英, 佟琳琳. 典型脉石矿物表面CN-吸附规律及润湿性研究[J]. 黄金科学技术, 2023, 31(2): 340-348. |
[11] | 赵濉, 陈兴锋, 张磊, 严峰, 张路. 含聚醚基团阴离子表面活性剂对PMMA表面润湿性的影响[J]. 天津工业大学学报, 2024, 43(3): 32-39, 49. |
[12] | Ai, C., Sun, P., Wu, A., Chen, X. and Liu, C. (2019) Accelerating Leaching of Copper Ore with Surfactant and the Analysis of Reaction Kinetics. International Journal of Minerals, Metallurgy, and Materials, 26, 274-281. https://doi.org/10.1007/s12613-019-1735-7 |
[13] | Zhou, J., Liu, C., Ma, J., Qin, Y., Wu, Z., Yang, L., et al. (2018) Intensification of Potassium Leaching from Phosphorus-Potassium Associated Ore with Lauryl Alcohol. Separation and Purification Technology, 191, 1-7. https://doi.org/10.1016/j.seppur.2017.09.007 |
[14] | Zeng, X., Shu, J., Chen, M., Wang, J., He, D., Wei, Y., et al. (2022) A Cost-Effective Method for Enhancing Manganese Leaching from Rhodochrosite Caused by Surfactant-Regulated Crystal Growth of CaSO4∙2H2O. Hydrometallurgy, 211, Article ID: 105870. https://doi.org/10.1016/j.hydromet.2022.105870 |
[15] | 王一雍, 张廷安, 陈霞, 鲍丽. 添加剂对一水硬铝石矿增溶溶出过程的影响[J]. 矿冶工程, 2007(1): 57-60. |
[16] | Wang, L., Yin, S. and Wu, A. (2021) Ore Agglomeration Behavior and Its Key Controlling Factors in Heap Leaching of Low-Grade Copper Minerals. Journal of Cleaner Production, 279, Article ID: 123705. https://doi.org/10.1016/j.jclepro.2020.123705 |
[17] | 宋广君, 寻克刚. 石灰在黄金选厂的作用及应用[J]. 黄金科学技术, 2004(1): 19-23. |
[18] | 李孟婷, 郑星群, 李莉, 魏子栋. 碱性介质中氢氧化和析氢反应机理研究现状[J]. 物理化学学报, 2021, 37(9): 21-37. |
[19] | Judge, W.D. and Azimi, G. (2020) Recent Progress in Impurity Removal during Rare Earth Element Processing: A Review. Hydrometallurgy, 196, Article ID: 105435. https://doi.org/10.1016/j.hydromet.2020.105435 |
[20] | 李洪枚, 柯家骏. 细菌浸出含镍硫化矿的研究进展[J]. 矿产综合利用, 1999(5): 28-33. |
[21] | 李诗浩, 马强, 王龙, 等. 黄铁矿浮选活化机理研究进展[J]. 矿产综合利用, 2023(2): 124-130, 140. |
[22] | 童格, 顾帼华, 王艳红, 黄娇, 巫銮东. 闪锌矿微生物浸出过程溶解动力学研究进展[J] .有色金属工程, 2022, 12(6): 75-82. |
[23] | 张瑞洋, 卢涛, 孙春宝, 寇珏, 魏德洲. 表面活性剂吐温20对胶硫钼矿生物浸出的促进机理[J]. 工程科学学报, 2018, 40(7): 793-799. |
[24] | 周桂英, 阮仁满, 温建康, 武彪. 紫金山铜矿浸出过程黄铁矿的氧化行为[J]. 北京科技大学学报, 2008(1): 11-15. |
[25] | Li, J., Kawashima, N., Kaplun, K., Absolon, V.J. and Gerson, A.R. (2010) Chalcopyrite Leaching: The Rate Controlling Factors. Geochimica et Cosmochimica Acta, 74, 2881-2893. https://doi.org/10.1016/j.gca.2010.02.029 |
[26] | 邱天, 言兰, 王福增, 谢鸿, 税妍, 张涛, 姜峰. 材料去除过程中Rehbinder效应的研究进展[J]. 中国表面工程, 2024, 37(1): 59-74. |
[27] | 于耕, 宗平. GILS组合进场策略研究[J]. 科学技术与工程, 2016, 16(11): 1-2. |
[28] | Saldaña, M., Jeldres, M., Galleguillos Madrid, F.M., Gallegos, S., Salazar, I., Robles, P., et al. (2023) Bioleaching Modeling—A Review. Materials, 16, Article 3812. https://doi.org/10.3390/ma16103812 |
[29] | Cisternas, L., Lucay, F. and Botero, Y. (2019) Trends in Modeling, Design, and Optimization of Multiphase Systems in Minerals Processing. Minerals, 10, Article 22. https://doi.org/10.3390/min10010022 |
[30] | 孙建孟, 王克文, 李伟. 测井饱和度解释模型发展及分析[J]. 石油勘探与开发, 2008(1): 101-107. |