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棉秆催化热解差异研究及预测
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Abstract:
本文旨在探究脱硫灰为催化剂下,棉秆、纤维素和木质素热解过程中不同混合比例与热解产物间的关系,为棉秆的高效利用和可持续发展提供部分理论支持。本文通过t检验,发现脱硫灰对棉秆中纤维素和木质素生成的热解产物均有不同促进。同时使用配对样本T检验对脱硫灰与纤维素和木质素两种组合得到的热解产物与热解气进行差异性分析。发现在相同混合比例下,纤维素与木质素的热解产物和热解气大多数都具有显著性差异。通过建立多项式回归拟合,用于研究混合比例对脱硫灰/纤维素热解的影响,模型系数表明混合比例对热解产物产率及热解气体产量有较大影响。此外,本文还采用灰色预测对不同混合比例下脱硫灰/棉秆的热解产物的产率进行了预测。
The purpose of this paper is to explore the relationship between different mixing ratios and pyrolysis products in the pyrolysis process of cotton stalk, cellulose and lignin with desulfurized fly ash as catalyst, and to provide some theoretical support for the efficient utilization and sustainable development of cotton stalk. In this paper, through t test, it was found that the desulfurized fly ash had different promotion effects on the pyrolysis products of cellulose and lignin in cotton stalk. At the same time, the paired sample T test was used to analyze the difference between the pyrolysis products and pyrolysis gas obtained by the combination of desulfurized fly ash and cellulose and lignin. It was found that most of the pyrolysis products and pyrolysis gases of cellulose and lignin had significant differences at the same mixing ratio. By establishing polynomial regression fitting, the influence of mixing ratio on the pyrolysis of desulfurization DFA/CE was studied. The model coefficients showed that the mixing ratio had a great influence on the yield of pyrolysis products and the yield of pyrolysis gas. In addition, the yield of pyrolysis products of desulfurization DFA/CS stalk under different mixing ratios was predicted by grey prediction.
[1] | 白志刚, 刘帅, 胡启星, 等. 棉花秸秆利用的主要途径及存在的问题[J]. 棉花科学, 2021, 43(5): 11-15. |
[2] | 刘郁珏, 张涵斌, 张歆然. 秸秆热解∙燃烧特性及动力学研究[J]. 安徽农业科学, 2019, 47(4): 12-17, 21. |
[3] | 周岭, 周福君, 蒋恩臣, 等. 棉秆不同组分热解特性及动力学[J]. 农业工程学报, 2009, 25(8): 220-225. |
[4] | 曹新新, 沈伯雄. 棉秆催化热解的热重分析[J]. 南开大学学报(自然科学版), 2009, 42(5): 25-31. |
[5] | 别尔德汗·瓦提汗, 亚力昆江∙吐尔逊, 迪丽努尔∙塔力甫, 等. 载镍橄榄石催化剂对棉秆热解的影响[J]. 可再生能源, 2018, 36(7): 969-976. |
[6] | 邓聚龙. 灰色理论基础[M]. 武汉: 华中科技大学出版社, 2002. |
[7] | 杜启, 唐初阳, 安新元, 等. 基于模型化合物的脱硫灰催化提质生物质热解气研究[J]. 可再生能源, 2023, 41(6): 711-716. |
[8] | 陈明强, 齐雪宜, 王君, 等. 棉秆催化热解特性及动力学建模研究[J]. 燃料化学学报, 2011, 39(8): 585-589. |
[9] | 牛璐瑶, 葛炬. 基于灰色预测模型的河南省多式联运货运量预测研究[J]. 物流科技, 2024, 47(17): 88-91. |
[10] | 杨瑛, 郑文轩. 棉秆热解特性的分析[J]. 湖北农业科学, 2014, 53(16): 3915-3917. |
[11] | 付迁, 徐圆圆, 闫永波, 等. 污泥棉花秆共热解特性的响应面优化分析[J]. 燃烧科学与技术, 2023, 29(6): 699-705. |