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基于柱芳烃的光响应主–客体超分子体系研究进展
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Abstract:
柱芳烃是一类具有独特对称性和柱状空腔结构的新型人工合成大环分子，可通过简单的化学方法对其端基进行功能化修饰，目前已发展成为一类重要的大环基元分子用于构筑各种刺激响应的功能超分子组装材料。光是一种清洁、非侵入性和时空可控的外部刺激，具有光刺激响应特性的主–客体作用超分子体系受到广泛关注。文章总结了近年来在基于柱芳烃的光响应主–客体超分子组装体系和功能材料方面的重要研究进展，系统阐述了目前报道的光响应柱芳烃主–客体超分子组装体系的主要构筑策略和代表性应用。
Pillar[n]arenes are a class of artificial synthetic macrocyclic molecules featuring unique symmetrical and pillar-shaped cavity structures, as well as facile functionalization by chemically modifying their end groups. These features have conferred pillar[n]arenes to be of fundamental importance as macrocyclic building blocks for the construction of copious stimuli-responsive functional supramolecular assembly systems and materials. Light represents a clean and noninvasive external stimulus with unique spatiotemporal controllability, which has attracted considerable attention to the development of photoresponsive host-guest supramolecular systems. This review mainly summarizes the recent progress on photoresponsive pillar[n]arene-based host-guest supramolecular assembly systems and functional materials, with systematical elaboration and perspectives on their construction strategies and applications of currently reported photoresponsive pillar[n]arene-based host-guest supramolecular assembly systems and materials.
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