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The Contradictions between the Total-Entropy and the Gibbs Energy When Applied to the Evolving Path and State of Equilibrium of Thermodynamically-Reversible Chemical Reactions

DOI: 10.4236/jhepgc.2025.111011, PP. 120-137

Keywords: Total-Entropy, Gibbs Energy, Evolving Path, Equilibrium, Contradictory Prescriptions for Thermodynamically Reversible Chemical Reactions

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Abstract:

This paper, an addendum to “Dialectical Thermodynamics’ solution to the conceptual imbroglio that is the reversible path”, this journal, 10, 775-799, was written in response to the requests of several readers to provide further evidence of the said “imbroglio”. The evidence here presented relates to the incompatibility existing between the total-entropy and the Gibbs energy prescriptions for the reversible path. The previously published proof of the negentropic nature of the transformation of heat into work is here included to validate out conclusions about the Gibbs energy perspective.

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