|
|
Mine Engineering 2024
页岩气藏中CO2与CH4竞争吸附的机理分析与技术展望
|
Abstract:
页岩气作为一种重要的非常规天然气资源，在全球能源结构中占据越来越重要的地位。在页岩气的开发过程中，气体在页岩中的吸附行为对气藏评估和开发方案的制定至关重要。本文综述了页岩气藏中二氧化碳与甲烷的竞争吸附机理、影响因素、实验研究进展、数值模拟方法及其实际应用，并对未来研究方向进行了展望。
Shale gas, as an important unconventional natural gas resource, occupies an increasingly important position in the global energy mix. During the development of shale gas, the adsorption behaviour of the gas in shale is crucial for the assessment of the reservoir and the formulation of the development plan. This paper reviews the competitive adsorption mechanism of carbon dioxide and methane in shale gas reservoirs, the influencing factors, the progress of experimental research, numerical simulation methods and their practical applications, and gives an outlook on the future research direction.
| [1] | Zhou, W., Zhang, Z., Wang, H., et al. (2019) Molecular Investigation of CO2/CH4 Competitive Adsorption and Confinement in Realistic Shale Kerogen. Nanomaterials, 9, 1646. https://doi.org/10.3390/nano9121646 |
| [2] | Chareonsuppanimit, P., Mohammad, S.A., Robinson, R.L. and Gasem, K.A.M. (2012) High-Pressure Adsorption of Gases on Shales: Measurements and Modeling. International Journal of Coal Geology, 95, 34-46. https://doi.org/10.1016/j.coal.2012.02.005 |
| [3] | Sun, H., Sun, W., Zhao, H., Sun, Y., Zhang, D., Qi, X., et al. (2016) Adsorption Properties of CH4 and CO2 in Quartz Nanopores Studied by Molecular Simulation. RSC Advances, 6, 32770-32778. https://doi.org/10.1039/c6ra05083b |
| [4] | Cancino, L.R., Lei, Y. and Xue, Q. (2017) Adsorption of Gases in Shales: Thermodynamic Analysis and Competitive Behavior. |
| [5] | 李毅, 张可霓, 王笑雨. 页岩气开发中吸附-解吸过程的影响及CO2驱替页岩气的模拟研究[J]. 北京师范大学学报(自然科学版), 2015, 51(4): 399-403. |
| [6] | Wang, H., Huang, J., Zhan, S., Zhang, M. and Cai, J. (2024) Study on CO2 and CH4 Competitive Adsorption in Shale Organic and Clay Porous Media from Molecular-to Pore-Scale Simulation. SPE Journal, 29, 3265-3276. https://doi.org/10.2118/219478-pa |
| [7] | Chen, Z., Zhang, B., Tian, J. and Jiang, X. (2021) Insights into Competitive Adsorption of CO2 and CH4 in Shale Reservoirs from Molecular Simulation. |
| [8] | Qin, C., Jiang, Y., Zhou, J., Song, X., Liu, Z., Li, D., et al. (2021) Effect of Supercritical CO2 Extraction on CO2/CH4 Competitive Adsorption in Yanchang Shale. Chemical Engineering Journal, 412, Article ID: 128701. https://doi.org/10.1016/j.cej.2021.128701 |
| [9] | 孙宝江, 张彦龙, 杜庆杰. CO2在页岩中的吸附解吸性能评价[J]. 化工学报, 2015, 66(6): 2118-2122. |
| [10] | Cai, J., Yu, Q. and Hu, X. (2015) Thermogravimetric Analysis of Gas Adsorption in Shale: Effects of Temperature and Pressure. |
| [11] | Zhan, S., Zhang, M. and Cai, J. (2024) Competitive Adsorption Phenomenon in Shale Gas Displacement Processes. SPE Journal, 29, 3265-3276. |
| [12] | Zhang, H., Diao, R., Mostofi, M. and Evans, B. (2019) Monte Carlo Simulation of the Adsorption and Displacement of CH4 by CO2 Injection in Shale Organic Carbon Slit Micropores for CO2 Enhanced Shale Gas Recovery. Energy & Fuels, 34, 150-163. https://doi.org/10.1021/acs.energyfuels.9b03349 |
| [13] | Ma, J., Wang, X., Gao, R., Zeng, F., Huang, C., Tontiwachwuthikul, P., et al. (2015) Enhanced Light Oil Recovery from Tight Formations through CO2 Huff “n” Puff Processes. Fuel, 154, 35-44. https://doi.org/10.1016/j.fuel.2015.03.029 |
| [14] | Zhou, X., Yuan, Q., Peng, X., Zeng, F. and Zhang, L. (2018) A Critical Review of the CO2 Huff “n” Puff Process for Enhanced Heavy Oil Recovery. Fuel, 215, 813-824. https://doi.org/10.1016/j.fuel.2017.11.092 |
| [15] | 陈敏, 张雷, 张砚. 注CO2提高页岩气采收率技术可行性分析[J]. 化学工程与装备, 2017, 46(4): 118-119. |
