Dilution and attenuation factor (DAF) has a major influence on soil-to-groundwater screening level calculation for protection of contaminant migration from soil into groundwater at solid waste management units (SWMUs). Risk assessment guidance prepared by U.S. Environmental Protection Agency for site investigation and remediation suggests a default DAF of 20. If the base assumptions included in the default DAF are recognized to be not representative of site conditions at a SWMU, calculation of site-specific DAF is recommended when sufficient data are collected to justify using a different DAF value for development of soil screening levels. Commonly used methods of calculating DAF include analytical and numerical simulations that often require too many parameters to be obtained in practice. This paper proposes a probability method to develop site-specific DAF. The approach uses data that are readily available through field reconnaissance and site-specific investigation. A case study is presented in which the probability method was applied to an actual SWMU, and the calculated DAF is compared with that calculated from a dilution method. The probability-based DAF is 67 at 90% probability percentile, which is comparable to the dilution-based DAF of 76. Based on the calculated site-specific DAFs, SSLs could be developed for the contaminants of potential concern and used for evaluation of migration pathways from a contamination source through soil to groundwater.
References
[1]
Allison, G. B., Gee, G. W., & Tyler, S. W. (1994). Vadose-Zone Techniques for Estimating Groundwater Recharge in Arid and Semiarid Regions. SoilScienceSocietyofAmericaJournal,58, 6-14. https://doi.org/10.2136/sssaj1994.03615995005800010002x
[2]
American Petroleum Institute (1996). Estimation of Infiltration and Recharge for Environmental Site Assessment, Stephens & Associates. API Publication.
[3]
American Society for Testing and Materials (ASTM) (2022). Standard Guide for Risk-Based Corrective Action, ASTM E2081-22.
[4]
Connor, J. A., Bowers, R. L., Paquette, S. M., & Newell, C. J. (1997). Soil Attenuation Models (SAM) for Derivation of Risk-Based Soil Remediation Standards. GSI Environmental Inc.
[5]
Dassi, L. (2010). Use of Chloride Mass Balance and Tritium Data for Estimation of Groundwater Recharge and Renewal Rate in an Unconfined Aquifer from North Africa: A Case Study from Tunisia. EnvironmentalEarthSciences,60, 861-871. https://doi.org/10.1007/s12665-009-0223-1
[6]
Enfield, C. G., Carsel, R. F., Cohen, S. Z., Phan, T., & Walters, D. M. (1982). Approximating Pollutant Transport to Ground Water. Groundwater,20, 711-722. https://doi.org/10.1111/j.1745-6584.1982.tb01391.x
[7]
ESTCP (2022). Using Real-Time Remote Sensors to Reduce the Cost of Long-Term Monitoring and Remediation Performance Monitoring at PFAS Vadose Source Zones. Environmental Certification and Technology Demonstration Program Project ER22-7381.
[8]
Gelhar, L. W., Welty, C., & Rehfeldt, K. R. (1992). A Critical Review of Data on Field-Scale Dispersion in Aquifers. WaterResourcesResearch,28, 1955-1974. https://doi.org/10.1029/92wr00607
[9]
Gradient Corporation (2013). National Human Health Risk Evaluation for Hydraulic Fracturing Fluid Additives. Halliburton Energy Services, Inc.
[10]
Henry, D. W., Zakikhani, M., Theel, H. J., Lorentz, W. P., Harrelson, D. W., & Khan, M. S. (2016). Development of Soil Screening Levels and Site-Specific Dilution Attenuation Factors for the Fort Wingate Depot Activity. The US Army Engineer Research and Development Center (ERDC), ERDC TR-16-DRAFT.
[11]
Javandel, I., Doughty, C., & Tsang, C. (1984). Groundwater Transport: Handbook of Mathematical Models. American Geophysical Union. https://doi.org/10.1029/wm010
[12]
Newell, C. J., Stockwell, E. B., Alanis, J., Adamson, D. T., Walker, K. L., & Anderson, R. H. (2022). Determining Groundwater Recharge for Quantifying PFAS Mass Discharge from Unsaturated Source Zones. VadoseZoneJournal,22, e20262. https://doi.org/10.1002/vzj2.20262
[13]
Phillips, F. M. (1994). Environmental Tracers for Water Movement in Desert Soils of the American Southwest. SoilScienceSocietyofAmericaJournal,58, 15-24. https://doi.org/10.2136/sssaj1994.03615995005800010003x
[14]
Texas Commission on Environmental Quality (2022). Texas Risk Reduction Program Rule. Texas Risk Reduction Program. https://www.tceq.texas.gov/remediation/trrp/trrprule.html
USEPA (2023). Report on the Environment: Ground Water. https://www.epa.gov/report-environment/ground-water
[17]
Van Genuchten, M. T. (1980). A Closed-Form Equation for Predicting the Hydraulic Conductivity of Unsaturated Soils. Soil Science Society of America Journal, 44, 892-898. https://doi.org/10.2136/sssaj1980.03615995004400050002x
[18]
Wood, W. W. (1999). Use and Misuse of the Chloride-Mass Balance Method in Estimating Ground Water Recharge. Groundwater,37, 2-3. https://doi.org/10.1111/j.1745-6584.1999.tb00949.x