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Material Sciences 2024
苯胺辅助层状MoO3用于构建高性能锌离子电池的研究
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Abstract:
采用水热法将苯胺(PANI)插入MoO3层间，PANI的插层促进了MoO3的电荷储存，增强了导电性，同时减弱了Zn2+与MoO3主体之间的静电相互作用，加速Zn2+的传输。鉴于这些特性，PANI-MoO3//Zn电池在1 A？g？1电流条件下表现出超高的比容量352 mAh？g？1，具有卓越的倍率性能在当电流密度从1 A？g？1增加到10 A？g？1时，PANI-MoO3电极仍然保持着133 mAh？g？1的放电比容量(保持率为40%)，而MoO3电极仅有72 mAh？g？1的放电比容量(保持率为29%)。此外，还具备出色的循环性能，经过1000次循环后，PANI-MoO3//Zn电池的容量保持率比MoO3//Zn电池提高了132%。
The PANI was inserted between the MoO3 layers using a hydrothermal method, and the insertion of PANI promoted the charge storage of MoO3 and enhanced the electrical conductivity, while attenuating the electrostatic interactions between Zn2+ and the main body of MoO3 and accelerating the transport of Zn2+. In view of these properties, the PANI-MoO3//Zn battery exhibits an ultra-high specific capacity of 352 mAh？g？1 at a current of 1 A？g？1, with excellent multiplicative performance at when the current density is increased from 1 A？g？1 to 10 A？g？1 When the current density is increased from 1 A？g？1 to 10 A？g？1, the PANI-MoO3 electrode still maintains a discharge specific capacity of 133 mAh？g？1 (40% retention), while the MoO3 electrode has a discharge specific capacity of only 72 mAh？g？1 (29% retention). In addition, there is excellent cycling performance, with the PANI-MoO3//Zn battery showing a 132% improvement in capacity retention over the MoO3//Zn battery after 1000 cycles.
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