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Feasibility Analysis of the Sintering Flue Gas Oxidation Method for Denitrification Technology Route

DOI: 10.4236/msce.2024.126002, PP. 12-23

Keywords: Sintering, Air Pollution, Denitration by Oxidation

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Abstract:

With the vigorous development of China’s iron and steel industry and the introduction of ultra-low emission policies, the emission of pollutants such as SO2 and NOx has received unprecedented attention. At present, the commonly used denitrification methods include selective catalytic reduction (SCR), active coke, etc. As a newly developed denitrification technology, oxidation denitrification is not widely used, and the technical level is mixed, and there might be problems such as yellow smoke, secondary pollution and ozone escape in the practical application. In this paper, problems existing in the denitrification process of sintering flue gas oxidation are analyzed, and a 320 m2 sintering machine is taken as an example. Comparing the denitrification technology of sintering industry, it could be seen that the denitrification technology route of oxidation method has low pollution, low cost and high comprehensive environmental benefits, and has greatly potential development.

References

[1]  Cheng, T., Zhou, X., Yang, L., Sun, Z. and Wu, H. (2020) Emission Characteristics of Soluble Ions in Fine Particulates in Limestone-Gypsum Wet Flue Gas Desulfurization System. Energy & Fuels, 34, 3836-3842.
https://doi.org/10.1021/acs.energyfuels.9b04512
[2]  Shen, Z., Guo, S., Kang, W., Zeng, K., Yin, M., Tian, J., et al. (2012) Kinetics and Mechanism of Sulfite Oxidation in the Magnesium-Based Wet Flue Gas Desulfurization Process. Industrial & Engineering Chemistry Research, 51, 4192-4198.
https://doi.org/10.1021/ie300163v
[3]  Bao, J., Yang, L., Sun, W., Geng, J., Yan, J. and Shen, X. (2011) Removal of Fine Particles by Heterogeneous Condensation in the Double-Alkali Desulfurization Process. Chemical Engineering and Processing: Process Intensification, 50, 828-835.
https://doi.org/10.1016/j.cep.2011.05.008
[4]  Skalska, K., Miller, J.S. and Ledakowicz, S. (2012) Intensification of Nox Absorption Process by Means of Ozone Injection into Exhaust Gas Stream. Chemical Engineering and Processing: Process Intensification, 61, 69-74.
https://doi.org/10.1016/j.cep.2012.06.007
[5]  Zhang, Y., Zheng, Y., Wang, X. and Lu, X. (2015) Preparation of Mn-FeOx/CNTs Catalysts by Redox Co-Precipitation and Application in Low-Temperature NO Reduction with Nh3. Catalysis Communications, 62, 57-61.
https://doi.org/10.1016/j.catcom.2014.12.023
[6]  Zhang, L., Zhang, D., Zhang, J., Cai, S., Fang, C., Huang, L., et al. (2013) Design of meso-TIO2@MnOx-CeOx/CNTs with a Core-Shell Structure as Denox Catalysts: Promotion of Activity, Stability and So2-Tolerance. Nanoscale, 5, 9821-9829.
https://doi.org/10.1039/c3nr03150k
[7]  Guo, J., Li, Y., Xiong, J. and Zhu, T. (2020) Coupling Mechanism of Activated Carbon Mixed with Dust for Flue Gas Desulfurization and Denitrification. Journal of Environmental Sciences, 98, 205-214.
https://doi.org/10.1016/j.jes.2020.06.002
[8]  Wang, Y., Jin, S., Li, J., Zhou, J., Zhang, L., Wang, J., et al. (2017) Investigation of the Fine Structure Around the Copper Site in Copper/zinc Superoxide Dismutase by XANES Combined with ab initio Calculations. Radiation Physics and Chemistry, 137, 88-92.
https://doi.org/10.1016/j.radphyschem.2016.03.003
[9]  Jia, J., Cheng, S., Yao, S., Xu, T., Zhang, T., Ma, Y., et al. (2018) Emission Characteristics and Chemical Components of Size-Segregated Particulate Matter in Iron and Steel Industry. Atmospheric Environment, 182, 115-127.
https://doi.org/10.1016/j.atmosenv.2018.03.051
[10]  Mele, M. and Magazzino, C. (2020) A Machine Learning Analysis of the Relationship among Iron and Steel Industries, Air Pollution, and Economic Growth in China. Journal of Cleaner Production, 277, Article ID: 123293.
https://doi.org/10.1016/j.jclepro.2020.123293
[11]  Bo, X., Li, Z., Qu, J., Cai, B., Zhou, B., Sun, L., et al. (2020) The Spatial-Temporal Pattern of Sintered Flue Gas Emissions in Iron and Steel Enterprises of China. Journal of Cleaner Production, 266, Article ID: 121667.
https://doi.org/10.1016/j.jclepro.2020.121667
[12]  Zhang, X., Gao, S., Fu, Q., Han, D., Chen, X., Fu, S., et al. (2020) Impact of VOCs Emission from Iron and Steel Industry on Regional O3 and PM2.5 Pollutions. Environmental Science and Pollution Research, 27, 28853-28866.
https://doi.org/10.1007/s11356-020-09218-w
[13]  Zou, Y., Wang, Y., Liu, X., Zhu, T., Tian, M. and Cai, M. (2020) Simultaneous Removal of NOx and SO2 Using Two-Stage O3 Oxidation Combined with Ca(OH)2 Absorption. Korean Journal of Chemical Engineering, 37, 1907-1914.
https://doi.org/10.1007/s11814-020-0597-z
[14]  Liu, F., Cai, M., Liu, X., Zhu, T. and Zou, Y. (2021) O3 Oxidation Combined with Semi-Dry Method for Simultaneous Desulfurization and Denitrification of Sintering/Pelletizing Flue Gas. Journal of Environmental Sciences, 104, 253-263.
https://doi.org/10.1016/j.jes.2020.11.021
[15]  Cai, M., Liu, X., Zhu, T., Zou, Y., Tao, W. and Tian, M. (2020) Simultaneous Removal of SO2 and No Using a Spray Dryer Absorption (SDA) Method Combined with O3 Oxidation for Sintering/Pelleting Flue Gas. Journal of Environmental Sciences, 96, 64-71.
https://doi.org/10.1016/j.jes.2020.04.018
[16]  Zhang, W., Wu, S. and Hu, Z. (2020) Analysis of Operational Parameters Affecting Denitrification Rate of Sintering Flue Gas in Cross-Flow Activated Coke Purification Facility. Journal of Iron and Steel Research International, 27, 887-897.
https://doi.org/10.1007/s42243-020-00440-x
[17]  Wu, Z., Chen, Z., Wang, H., Liu, H. and Wei, Z. (2023) Arsenic Removal in Flue Gas through Anaerobic Denitrification and Sulfate Reduction Cocoupled Arsenic Oxidation. Chemosphere, 337, Article ID: 139350.
https://doi.org/10.1016/j.chemosphere.2023.139350
[18]  Ma, L., Duan, X., Wu, J., Li, J., Peng, L., Wang, L., et al. (2022) Simultaneous Desulfurization and Denitrification of Flue Gas Enabled by Hydrojet Cyclone. Journal of Cleaner Production, 377, Article ID: 134205.
https://doi.org/10.1016/j.jclepro.2022.134205
[19]  Shen, Z., Xing, X., Wang, S., Zheng, Z. and Lv, M. (2023) Low Temperature Co Oxidation from Sintering Flue Gas on CuO-CeO2/AC-Fe Catalyst. Catalysis Today, 423, Article ID: 113988.
https://doi.org/10.1016/j.cattod.2022.12.019
[20]  Han, Z., Zou, T., Wang, J., Dong, J., Deng, Y. and Pan, X. (2020) A Novel Method for Simultaneous Removal of NO and SO2 from Marine Exhaust Gas via In-Site Combination of Ozone Oxidation and Wet Scrubbing Absorption. Journal of Marine Science Engineering, 8, 943-964.
https://doi.org/10.3390/jmse8110943
[21]  Liu, S., Liu, Z., Zhu, H., Wang, Z., Guo, J., Zhang, X., et al. (2023) The Roles of Red Mud as Desulfurization and Denitrification in Flue Gas: A Review. Journal of Environmental Chemical Engineering, 11, Article ID: 109770.
https://doi.org/10.1016/j.jece.2023.109770
[22]  Zou, Y., Liu, X., Zhu, T., Tian, M., Cai, M., Zhao, Z., et al. (2019) Simultaneous Removal of NOx and SO2 by Mgo Combined with O3 Oxidation: The Influencing Factors and O3 Consumption Distributions. ACS Omega, 4, 21091-21099.
https://doi.org/10.1021/acsomega.9b02502
[23]  Li, B., Wu, H., Liu, X., Zhu, T., Liu, F. and Zhao, X. (2020) Simultaneous Removal of SO2 and No Using a Novel Method with Red Mud as Absorbent Combined with O3 Oxidation. Journal of Hazardous Materials, 392, Article ID: 122270.
https://doi.org/10.1016/j.jhazmat.2020.122270
[24]  Gao, F., Tang, X., Yi, H., Zhao, S., Li, C., Li, J., et al. (2017) A Review on Selective Catalytic Reduction of NOx by NH3 over Mn-Based Catalysts at Low Temperatures: Catalysts, Mechanisms, Kinetics and DFT Calculations. Catalysts, 7, Article 199.
https://doi.org/10.3390/catal7070199
[25]  Johansson, J., Heijnesson Hultén, A., Ajdari, S., Nilsson, P., Samuelsson, M., et al. (2018) Gas-Phase Chemistry of the NO-SO2-CLO2 System Applied to Flue Gas Cleaning. Industrial & Engineering Chemistry Research, 57, 14347-14354.
https://doi.org/10.1021/acs.iecr.8b03067
[26]  Han, Z., Lan, T., Han, Z., Yang, S., Dong, J., Sun, D., et al. (2019) Simultaneous Removal of NO and SO2 from Exhaust Gas by Cyclic Scrubbing and Online Supplementing pH-Buffered Naclo2 Solution. Energy & Fuels, 33, 6591-6599.
https://doi.org/10.1021/acs.energyfuels.9b01106
[27]  Hao, R., Mao, X., Qian, Z., Zhao, Y., Wang, L., Yuan, B., et al. (2019) Simultaneous Removal of SO2 and NO Using a Novel Method of Ultraviolet Irradiating Chlorite-Ammonia Complex. Environmental Science & Technology, 53, 9014-9023.
https://doi.org/10.1021/acs.est.8b06950
[28]  Sun, Y., Fan, W., Zhu, T. and Hong, X. (2017) Effect of Cao on NOx Reduction by Selective Non-Catalytic Reduction under Variable Gas Compositions in a Simulated Cement Precalciner Atmosphere. International Journal of Environmental Research and Public Health, 14, Article 1474.
https://doi.org/10.3390/ijerph14121474

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