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基于大环分子主–客体相互作用的超分子聚合物网络研究进展
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Abstract:
高分子链间通过非共价交联作用能够形成超分子聚合物网络(SPNs)，这类材料具有动态可逆性、刺激响应性、自愈性和形状记忆等优点，目前已在高分子科学、超分子化学、自适应材料和生物医学材料等诸多领域取得广泛应用。基于大环主体的主客体相互作用是构筑超分子聚合物网络的一类重要非共价驱动力，本文按照大环主体的种类介绍了不同类型主–客体作用交联的超分子聚合物网络的构筑策略，以及它们的刺激响应组装行为和功能调控相关研究进展。同时，讨论了该领域面临的问题和挑战，为发展其他新颖超分子聚合物网络材料提供参考。
The noncovalent crosslinking of polymer chains can lead to the formation of supramolecular poly-mer networks (SPNs) featuring with unique dynamic, stimuli-responsive, self-healing and shape memory etc, which have enabled widespread applications in polymer science, supramolecular chemistry, adaptive materials as well as biomedical materials. The macrocyclic host based host-guest interactions are an important class of non covalent driving force for constructing SPNs. This review mainly summarize the representative construction strategies for SPNs crosslinked by different host-guest interactions according to the types of macrocyclic hosts, as well as the research progress related to their stimuli-responsive assembly behavior and functional regulation. Mean-while, the challenges and perspectives will be discussed to provide valuable references for the de-velopment of other novel SPNs materials.
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