Rare earth elements are indispensable raw materials for advanced aero-engines, special optical materials, and high-performance electronic products. With the development of the social economy, the global demand for rare earth resources is increasing, and rare earths have become a key metal for the development of new industries and frontier technologies that are highly valued both at home and abroad. Ion-adsorbed rare earth ores are an important source of rare earths, so the efficient green leaching of ion-adsorbed rare earths is important. Researchers found that the selection of an efficient green leaching agent for ion-adsorbed rare earths is based on the zeta potential of tailing clay minerals in addition to leaching efficiency, and both zeta potential and leaching ion concentration are related to mineral acidity and alkalinity, and the pH of tailing water suspension is a direct indicator of environmental water quality requirements. Therefore, the efficiency of the leaching process is closely integrated with the environmental evaluation, and the characteristics and correlation of the changes in zeta potential, pH, conductivity and pollutant concentration of the pulp of clay mineral content during the leaching process of ore leaching and tailings aqueous electrolyte solution leaching are studied by evaluating the leaching system, and a set of correlation leaching efficiency and environmental impact evaluation method is established based on the results of the above analysis, which is of scientific development of ion adsorption rare earth resources. It has important theoretical significance and practical application value.
References
[1]
Kunhikrishnan, A., et al. (2022) Rare Earth Elements (REE) for the Removal and Recovery of Phosphorus: A Review. Chemosphere, 286, Article 131661. https://doi.org/10.1016/j.chemosphere.2021.131661
[2]
Sun, Y.-Y. (2016) Mechanism of Adsorption, Migration and Desorption of Rare Earth Ions on the Surface of Clay Minerals. Master’s Thesis, Nanchang University, Nanchang.
[3]
Yang, L.F. (2018) Efficient Leaching of Ion-Adsorbed Rare Earths by Aluminum Sulfate. Master’s Thesis, Nanchang University, Nanchang.
[4]
Xiao, Y.F., Gao, G.H., Huang, L., et al. (2018) A Discussion on the Leaching Process of the Ion-Adsorption Type Rare Earth Ore with the Electrical Double Layer Model. Minerals Engineering, 120, 35-43. https://doi.org/10.1016/j.mineng.2018.02.015
[5]
Tian, J., Yin, J., Chen, K., et al. (2010) Optimisation of Mass Transfer in Column Elution of Rare Earths from Low Grade Weathered Crust Elution-Deposited Rare Earth Ore. Hydrometallurgy, 103, 211-214. https://doi.org/10.1016/j.hydromet.2010.04.003
[6]
Xu, Q.H., Yang, L.F., Zhang, L., et al. (2018) Classification and High Efficient Leaching of Ion Adsorption Rare Earth Based on Its pH Dependence. Chinese Journal of Inorganic Chemistry, 34, 112-121.
[7]
Li, Y.X. (2014) Ion Adsorption Rare Earth Resources and Green Extraction. Chemical Industry Press, Beijing, 13-15.
[8]
You, J.F. and Xing, L.Y. (2014) Application of Short-Wave Infrared (SWIR) Spectroscopy in Quantitative Estimation of Clay Mineral Contents. IOP Conference Series: Earth and Environmental Science. 17, Article 012256. https://doi.org/10.1088/1755-1315/17/1/012256
[9]
Tyler, G. (2004) Rare Earth Elements in Soil and Plant Systems: A Review. Plant and Soil, 267, 191-206. https://doi.org/10.1007/s11104-005-4888-2
[10]
Xiao, Y., Chen, Y.Y., Feng, Z.Y., et al. (2015) Leaching Characteristics of Ion-Adsorption Type Rare Earths Ore with Magnesium Sulfate. Transactions of Nonferrous Metals Society of China, 25, 3784-3790. https://doi.org/10.1016/S1003-6326(15)64022-5
[11]
Yang, L.F., Li, C.C., Wang, D.S., et al. (2018) Leaching Ion Adsorption Rare Earth by Aluminum Sulfate for Increasing Efficiency and Lowering the Environmental Impact. Journal of Rare Earths, 37, 429-436. https://doi.org/10.1016/j.jre.2018.08.012
[12]
Xu, Q.H., Yang, L.F., Wang, D.S., et al. (2018) Evaluating the Fractionation of Ion-Adsorption Rare Earths for in-situ Leaching and Metallogenic Mechanism. Journal of Rare Earths, 36, 1333-1341. https://doi.org/10.1016/j.jre.2018.05.009