Oil and gas industries generate a significant amount of water during the
production. The composition of this water varies with the geologic age, depth, and
geochemistry of the region along with the chemicals added during the process. Geochemistry of
formation water is used for aquifer identification, pollution problems, water
compatibility studies, corrosion monitoring, water-quality control, water
flooding, exploration, and to diagnose wellbore integrity issues. The current
study investigates the spatial and temporal variation of produced water
geochemistry from one of the largest conventional oil field, Ghawar field, Saudi Arabia. Produced
water from different wellheads were collected and analyzed for different
geochemical characteristics. Sixteen wells from ABQQ, nineteen wells from ANDR
and twenty wells from SDGM area were selected for the current study. Sampling
and analysis were performed as per the standard procedures. Results indicated
that the pH of the sample varied from 6.0 to 7.4, and Electrical conductivity
from 94200 to 102690 μS/cm. The spatial variation of major cations and anions
were also recorded and represented by graphical plots. Metal analysis indicated the highest concentration for boron, which is 20.5mg/L at
ABQQ area, whereas all other metals are very low in concentration. Temporal
variation of a single well at SDGM area indicated drastic change in the ionic
concentration, whereas the geochemistry remains same as indicated by Tickler
plot. The water type of the respective area was studied by tickler plots, which
indicated same source of formation water in different wells at ABQQ, ANDR and
SDGM areas. The ionic concentration is also used to predict corrosion and
scaling issues. By Langelier Saturation Index (LSI) and Ryznar Stability Index
(RSI), the sample from all the wells showed
higher scaling potential. The study concludes that the water type in different
areas
References
[1]
Ahmadun, F.-R., Pendashteh, A., Abdullah, L. C., Biak, D. R. A., Madaeni, S. S., & Abidin, Z. Z. (2009). Review of Technologies for Oil and Gas Produced Water Treatment. Journal of Hazardous Materials, 170, 530-551. https://doi.org/10.1016/j.jhazmat.2009.05.044
[2]
Alfarhan, A. A., & Duane, M. J. (2011) Geochemistry and Modification of Oilfield Brines in Surface Pits in Northern Kuwait. Arabian Journal of Geosciences, 5, 1055-1068. https://doi.org/10.1007/s12517-011-0297-4
[3]
Al-Ghouti, M. A., Kaabi, M. A., Ashfaq, M. Y., & Da’na, D. A. (2019). Produced Water Characteristics, Treatment and Reuse: A Review. Journal of Water Process Engineering, 28, 222-239. https://doi.org/10.1016/j.jwpe.2019.02.001
[4]
Birkle, P., Jenden, P. D., & Al-Dubaisi J. M. (2013). Origin of Formation Water from the Unayzah and Khuff Petroleum Reservoirs, Saudi Arabia. Procedia Earth and Planetary Science, 7, 77-80. https://doi.org/10.1016/j.proeps.2013.03.214
[5]
Carrigan, J. (1993). Environmental Isotope Geochemistry of Groundwater from FRWN-801, UQAB-801 and SHYB-801 (12 p). Saudi Aramco, Geochemistry Unit, Report HSD-125/93. Saudi Aramco, Geochemistry Unit.
[6]
Collins, A. G. (1975). Geochemistry of Oilfield Waters (496 p). Elsevier.
[7]
Dickhout, J. M., Moreno, J., Biesheuvel, P. M., Boels, L., Lammertink, R. G. H., & de Vos, W. M. (2017). Produced Water Treatment by Membranes: A Review from a Colloidal Perspective. Journal of Colloid Interface Science, 487, 523-534. https://doi.org/10.1016/j.jcis.2016.10.013
[8]
Johnson, B. M., Kanagy L. E., Rodgers J. H., & Castle J. W. (2008). Feasibility of a Pilot Scale Hybrid Constructed Wetland Treatment System for Simulated Natural Gas Storage Produced Waters. Environmental Geosciences, 15, 91-104. https://doi.org/10.1306/eg.06220707004
[9]
Nasir, U., Saeed, M. A., & Yousif, M. (2021). Environmental Impact Assessment of Heavy Metals in Surface Disposed Drilling Waste. Journal of Geoscience and Environment Protection, 9, 227-238. https://doi.org/10.4236/gep.2021.99012
[10]
Neff, J. M. (1987). Biological Effects of Drilling Fluids, Drill Cuttings and Produced Waters. In D. F. Boesch, & N. N. Rabalais (Eds.), Long-Term Effects of Offshore Oil and Gas Development (pp. 469-538). Elsevier Applied Science Publishers.
[11]
Neff, J., Lee, K., & DeBlois, E. M. (2011). Produced Water: Overview of Composition, Fates, and Effects. In K. Lee, & J. Neff (Eds.), Produced Water (pp. 3-54). Springer. https://doi.org/10.1007/978-1-4614-0046-2_1
[12]
Pillard, D. A., Tietge, J. E. & Evans, J. M. (1996). Estimating the Acute Toxicity of Produced Waters to Marine Organisms Using Predictive Toxicity Models. In M. Reed, & S. Johnsen (Eds.), Produced Water 2. Environmental Science Research (Vol. 52, pp. 49-60). Springer. https://doi.org/10.1007/978-1-4613-0379-4_6
[13]
Saner, S., Khattab, H., & Perincek, D. (2005). Surface Expressions of the Ghawar Structure, Saudi Arabia. Marine and Petroleum Geology, 22, 657-670. https://doi.org/10.1016/j.marpetgeo.2004.12.006
[14]
Tibbetts, P. J. C., Buchanan, I. T., Gawel, L. J., & Large, R. (1992). A Comprehensive Determination of Produced Water Composition. In J. P. Ray, & F. R. Engelhardt (Eds.), Produced Water. Environmental Science Research (Vol. 46, pp. 97-112). Springer. https://doi.org/10.1007/978-1-4615-2902-6_9
[15]
Udeagbara, S. G., Isehunwa, S. O., Okereke, N. U., & Oguamah I. U. (2020). Treatment of Produced Water from Niger Delta Oil Fields Using Simultaneous Mixture of Local Materials. Journal of Petroleum Exploration and Production, 11, 289-302. https://doi.org/10.1007/s13202-020-01017-w