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Material Sciences 2023
高镁含量的铝基合金粉末的水反应活性研究
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Abstract:
使用高温气雾化法制备了Al-40Mg、Al-37Mg-3Li与Al-37Mg-3Eu (wt.%)三种合金燃料粉末,用XRD和SEM表征其物相组成和表面形貌,并研究了Al-40Mg、Al-37Mg-3Li与Al-37Mg-3Eu三种合金燃料粉末在高压反应釜中的水反应性能。结果表明,单质Al粉的产氢效率仅为80.17%,而Al-40Mg、Al-37Mg-3Li、Al-37Mg-3Eu的产氢效率分别提升至93.69%、94.32%和94.63%。此外,还表征了三种合金燃料粉末水反应产物的物相组成和微观形貌。
Al-40Mg, Al-37Mg-3Li and Al-37Mg-3Eu (wt.%) alloy fuel powders were prepared by high tempera-ture gas atomization method, and their phase compositions and surface morphology were charac-terized by XRD and SEM. The water reaction properties of Al-40Mg, Al-37Mg-3Li and Al-37Mg-3Eu alloy fuel powders in high pressure reactor were studied. The results showed that the hydrogen production efficiency of elemental Al powder was only 80.17%, while the hydrogen production effi-ciency of Al-40Mg, Al-37Mg-3Li and Al-37Mg-3Eu increased to 93.69%, 94.32% and 94.63%, re-spectively. In addition, the phase composition and morphology of the water reaction products of three kinds of alloy fuel powder were characterized.
[1] | Elitzur, S., Rosenband, V. and Gany, A. (2014) Study of Hydrogen Production and Storage Based on Aluminum-Water Reaction. International Journal of Hydrogen Energy, 39, 6328-6334. https://doi.org/10.1016/j.ijhydene.2014.02.037 |
[2] | Yavor, Y., et al. (2013) Enhanced Hydrogen Generation from Aluminum-Water Reactions. International Journal of Hydrogen Energy, 38, 14992-15002. https://doi.org/10.1016/j.ijhydene.2013.09.070 |
[3] | Chen, X., et al. (2013) Hydrogen Generation by Splitting Wa-ter with Al-Li Alloys. International Journal of Energy Research, 37, 1624-1634. https://doi.org/10.1002/er.2978 |
[4] | Chen, X., et al. (2013) Research of Hydrogen Generation by the Reaction of Al-Based Materials with Water. Journal of Power Sources, 222, 188-195. https://doi.org/10.1016/j.jpowsour.2012.08.078 |
[5] | Wang, H.Z., et al. (2009) A Review on Hydrogen Production Using Aluminum and Aluminum Alloys. Renewable and Sustainable Energy Reviews, 13, 845-853. https://doi.org/10.1016/j.rser.2008.02.009 |
[6] | Soler, L., et al. (2007) Aluminum and Aluminum Alloys as Sources of Hydrogen for Fuel Cell Applications. Journal of Power Sources, 169, 144-149. https://doi.org/10.1016/j.jpowsour.2007.01.080 |
[7] | Shkolnikov, E.I., Zhuk, A.Z. and Vlaskin, M.S. (2011) Alu-minum as Energy Carrier: Feasibility Analysis and Current Technologies Overview. Renewable and Sustainable Energy Reviews, 15, 4611-4623.
https://doi.org/10.1016/j.rser.2011.07.091 |
[8] | Martínez-Salazar, A.L., et al. (2020) Hydrogen Generation by Alu-minum Alloy Corrosion in Aqueous Acid Solutions Promoted by Nanometal: Kinetics Study. Renewable Energy, 146, 2517-2523.
https://doi.org/10.1016/j.renene.2019.08.103 |
[9] | Wollmark, S. and Yavor, Y. (2019) Burning Rates of Nanoalu-minum-Water Solid Propellants at Various Pressures. Journal of Propulsion and Power, 35, 173-181. https://doi.org/10.2514/1.B37098 |
[10] | Bergthorson, J.M., et al. (2017) Metal-Water Combustion for Clean Propul-sion and Power Generation. Applied Energy, 186, 13-27. https://doi.org/10.1016/j.apenergy.2016.10.033 |
[11] | Huang, H.T., et al. (2013) Analysis of the Aluminum Reaction Efficiency in a Hydro-Reactive Fuel Propellant Used for a Water Ramjet. Combustion, Explosion, and Shock Waves, 49, 541-547.
https://doi.org/10.1134/S0010508213050055 |
[12] | Ingenito, A. and Bruno, C. (2004) Using Aluminum for Space Propulsion. Journal of Propulsion and Power, 20, 1056-1063.
https://doi.org/10.2514/1.5132 |
[13] | Deng, Z.-Y., et al. (2010) Effect of Different Modification Agents on Hydro-gen-Generation by the Reaction of Al with Water. International Journal of Hydrogen Energy, 35, 9561-9568. https://doi.org/10.1016/j.ijhydene.2010.07.027 |
[14] | Schoenitz, M., Chen, C.-M. and Dreizin, E.L. (2009) Oxidation of Aluminum Particles in the Presence of Water. The Journal of Physical Chemistry B, 113, 5136-5140. https://doi.org/10.1021/jp807801m |
[15] | Risha, G.A., et al. (2006) Combustion of Aluminum Particles with Steam and Liquid Water. 44th AIAA Aerospace Sciences Meeting, Reno, 9-12 January 2006, 14007-14014. |
[16] | Dupiano, P., Stamatis, D. and Dreizin, E.L. (2011) Hydrogen Production by Reacting Water with Mechanically Milled Composite Aluminum-Metal Oxide Powders. International Journal of Hydrogen Energy, 36, 4781-4791.
https://doi.org/10.1016/j.ijhydene.2011.01.062 |
[17] | Wan, J., et al. (2012) Reaction Characteristics of Nano-Aluminum and Water by In-Situ Investigation. Materials Chemistry and Physics, 136, 466-471. https://doi.org/10.1016/j.matchemphys.2012.07.012 |
[18] | Yavor, Y., et al. (2015) Comparative Reactivity of Indus-trial Metal Powders with Water for Hydrogen Production. International Journal of Hydrogen Energy, 40, 1026-1036. https://doi.org/10.1016/j.ijhydene.2014.11.075 |
[19] | Meng, A., et al. (2023) Hydrogen Production Performance of an Al-Ga-In-Sn Quaternary Alloy. Materials Today Sustainability, 21, Article ID: 100284. https://doi.org/10.1016/j.mtsust.2022.100284 |
[20] | Aleksandrov, Y.A., Tsyganova, E.I. and Pisarev, A.L. (2003) Reaction of Aluminum with Dilute Aqueous NaOH Solutions. Russian Journal of General Chemistry, 73, 729-734. https://doi.org/10.1023/A:1026114331597 |
[21] | Huang, X.-N., et al. (2012) Hydrogen Generation from Hydroly-sis of Aluminum/Graphite Composites with a Core-Shell Structure. International Journal of Hydrogen Energy, 37, 7457-7463.
https://doi.org/10.1016/j.ijhydene.2012.01.126 |
[22] | Deng, Z.-Y., et al. (2005) Modification of Al Particle Surfaces by Gamma-Al2O3 and Its Effect on the Corrosion Behavior of Al. Journal of the American Ceramic Society, 88, 977-979. https://doi.org/10.1111/j.1551-2916.2005.00154.x |
[23] | Fan, M., Xu, F. and Sun, L. (2007) Studies on Hydrogen Generation Characteristics of Hydrolysis of the Ball Milling Al-Based Materials in Pure Water. International Journal of Hydrogen Energy, 32, 2809-2815.
https://doi.org/10.1016/j.ijhydene.2006.12.020 |
[24] | Xiao, F., Yang, R. and Liu, Z. (2022) Active Aluminum Com-posites and Their Hydrogen Generation via Hydrolysis Reaction: A Review. International Journal of Hydrogen Energy, 47, 365-386.
https://doi.org/10.1016/j.ijhydene.2021.09.241 |
[25] | Uda, M., et al. (2012) Hydrogen Generation from Water Using Mg Nanopowder Produced by Arc Plasma Method. Science and Technology of Advanced Materials, 13, Article ID: 025009.
https://doi.org/10.1088/1468-6996/13/2/025009 |
[26] | Liu, Y., et al. (2013) Hydrogen Generation from the Hydrol-ysis of Mg Powder Ball-Milled with AlCl3. Energy, 53, 147-152. https://doi.org/10.1016/j.energy.2013.01.073 |
[27] | Zou, M.-S., et al. (2011) The Preparation of Mg-Based Hy-dro-Reactive Materials and Their Reactive Properties in Seawater. International Journal of Hydrogen Energy, 36, 6478-6483. https://doi.org/10.1016/j.ijhydene.2011.02.108 |
[28] | Ouyang, L.Z., et al. (2009) Production of Hydro-gen via Hydrolysis of Hydrides in Mg-La System. International Journal of Hydrogen Energy, 34, 9671-9676. https://doi.org/10.1016/j.ijhydene.2009.09.068 |
[29] | Grosjean, M., et al. (2006) Hydrogen Production via Hydroly-sis Reaction from Ball-Milled Mg-Based Materials. International Journal of Hydrogen Energy, 31, 109-119. https://doi.org/10.1016/j.ijhydene.2005.01.001 |
[30] | Miller, T.F. and Herr, J.D. (2004) Green Rocket Propulsion by Reaction of Al and Mg Powders and Water. 40th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, Fort Lauderdale, 11-14 July 2004, 1.
https://doi.org/10.2514/6.2004-4037 |
[31] | Zou, M.-S., et al. (2012) Preparation and Characterization of Hy-dro-Reactive Mg-Al Mechanical Alloy Materials for Hydrogen Production in Seawater. Journal of Power Sources, 219, 60-64.
https://doi.org/10.1016/j.jpowsour.2012.07.008 |
[32] | Kozin, L.F., et al. (2011) Kinetics and Mechanism of Interac-tion of Aluminum and Magnesium of Al-Mg-Bi Ternary System with Water. Protection of Metals and Physical Chemis-try of Surfaces, 47, 171-180.
https://doi.org/10.1134/S2070205111020110 |
[33] | Yang, W., et al. (2015) Experimental Study on the Effect of Low Melting Point Metal Additives on Hydrogen Production in the Aluminum-Water Reaction. Energy, 88, 537-543. https://doi.org/10.1016/j.energy.2015.05.069 |